Block copolymer of polyalkylene and halogenated polystyrene

Abstract

A block copolymer of polyalkylene and halogenated polystyrene comprises the formula: S'--A--(A--S').sub.m in which m is 0, 1, 3 or 4, A is a saturated polyalkylene, and S' is a nuclear brominated polystyrene having from about 0.5 to about 5 bromines per styrene unit. The polystyrene blocks are substantially free of halogen other than bromine and chlorine, and the polyalkylene is substantially free of halogen. The compositions retain the elastomeric properties of the non-halogenated form of the compounds while having significantly reduced flammability.

What is claimed is: 
     
       1. A block copolymer of polyalkylene and halogenated polystyrene which comprises:   S'--A--(A--S').sub.m     in which m is 0, 1, 2, 3, or 4, A is a saturated polyalkylene, and S' is a nuclear halogenated polystyrene having from about 0.5 to about 5 bromines per styrene unit .Iadd.and further including chlorine.Iaddend..   
     
     
       2. The block copolymer of claim 1 in which A is substantially free of halogen. 
     
     
       3. The block copolymer of claim 1 in which S' is substantially free of nuclear halogen other than bromine and chlorine. 
     
     
       4. The block copolymer of claim 3 in which A is substantially free of halogen. 
     
     
       5. The block copolymer of claim 1 in which S' has from about 1 to 2 bromines per styrene unit. 
     
     
       6. The block copolymer of claim 5 in which A is substantially free of halogen. 
     
     
       7. The block copolymer of claim 5 in which S' is substantially free of nuclear halogen other than bromine and chlorine. 
     
     
       8. The block copolymer of claim 7 in which A is substantially free of halogen. 
     
     
       9. The block copolymer of claim 5 in which S' further includes up to about 1 nuclear chlorine per styrene unit. 
     
     
       10. The block copolymer of claim 9 in which at least about 70% of the nuclear halogens in the styrene units are bromines. 
     
     
       11. The block copolymer of claim 9 in which S' is substantially free of nuclear halogen other than bromine and chlorine. 
     
     
       12. The block copolymer of claim 9 in which A is substantially free of halogen. 
     
     
       13. The block copolymer of claim 1 in which S' .[.further includes.]. .Iadd.contains .Iaddend.up to about 1.5 nuclear chlorines per styrene unit. 
     
     
       14. The block copolymer of claim 13 in which at least about 70% of the nuclear halogens in the styrene units are bromines. 
     
     
       15. The block copolymer of claim 14 in which at least about 85% of the nuclear halogens in the styrene units are bromines. 
     
     
       16. The block copolymer of claim 14 in which at least about 90% of the nuclear halogens in the styrene units are bromines. 
     
     
       17. The block copolymer of claim 13 in which A is substantially free of halogen. 
     
     
       18. The block copolymer of claim 13 in which S' is substantially free of nuclear halogen other than bromine and chlorine. 
     
     
       19. The block copolymer of claim 18 in which A is substantially free of halogen. 
     
     
       20. The block copolymer of claim 1 in which A comprises a saturated polyalkylene block selected from the group consisting of polyethylene, polypropylene, poly(ethylene-propylene), polybutylene, poly(ethylene-butylene) and combinations thereof. 
     
     
       21. A block copolymer of polyalkylene and halogenated polystyrene consisting essentially of:   S'--A--(A--S').sub.m     in which m is 0, 1, 2, 3, or 4, A is a saturated polyalkylene, and S' is a nuclear halogenated polystyrene having from about 0.5 to about 5 bromines per styrene unit .Iadd.and further including chlorine.Iaddend..   
     
     
       22. The block copolymer of claim 21 in which A is substantially free of halogen. 
     
     
       23. The block copolymer of claim 21 in which S' is substantially free of nuclear halogen other than bromine and chlorine. 
     
     
       24. The block copolymer of claim 21 in which S' has from about 1 to about 2 bromines per styrene unit. 
     
     
       25. The block copolymer of claim 21 in which A comprises a saturated polyalkylene block selected from the group consisting of polyethylene, polypropylene, poly(ethylene-propylene), polybutylene, poly(ethylene-butylene) and combinations thereof. 
     
     
       26. The block copolymer of claim 21 in which S' .[.further includes.]. .Iadd.contains .Iaddend. up to about 1.5 nuclear chlorines per styrene unit. 
     
     
       27. The block copolymer of claim 26 in which A is substantially free of halogen. 
     
     
       28. The block copolymer of claim 26 in which at least about 70% of the nuclear halogens are bromines. 
     
     
       29. The block copolymer of claim 26 in which S' is substantially free of nuclear halogen other than bromine and chlorine. 
     
     
       30. A block copolymer of polyalkylene and halogenated polystyrene which comprises:   S'--A--(A--S').sub.m     in which m is 0, 1, 2, 3, or 4, A is a saturated polyalkylene, and S' is a halogenated polystyrene which .Iadd.contains both chlorine and bromine and .Iaddend.comprises: ##STR2## wherein n is an integer, x=0.5 to 5.0 times n, and y .[.=0.]. .Iadd.is up .Iaddend.to 1.5 times n.   
     
     
       31. The block copolymer of claim 30 in which A is substantially free of halogen. 
     
     
       32. The block copolymer of claim 30 in which S' is substantially free of nuclear halogen other than bromine and chlorine. 
     
     
       33. The block copolymer of claim 30 in which S' has from about 1 to about 2 bromines per styrene unit. 
     
     
       34. The block copolymer of claim 30 in which A comprises a saturated polyalkylene block selected from the group consisting of polyethylene, polypropylene, poly(ethylene-propylene), polybutylene, poly(ethylene-butylene) and combinations thereof.