Thermal dye transfer materials

Abstract

The use of eutectic combinations of a dye and a second compound (which may also be a dye) in a binder has been found to provide benefits to thermal dye transfer materials.

We claim: 
     
       1. A thermal dye transfer element comprising a substrate having on one side thereof a layer of a polymeric binder having a mixture of at least two .Iadd.yellow .Iaddend.dyes therein, said dyes being capable of forming a eutectic composition and at least one pair of said dyes being present within said binder in a ratio which is between 0.25 and 4.0 times the ratio of said pair of dyes in a eutectic point composition, said mixture of dyes comprising at least 20% by weight of said layer and said eutectic composition has a melting point which is at least 5° C. lower than the lowest melting temperature of any of said dyes in said eutectic composition. 
     
     
       2. The element of claim 1 wherein at least one of said dyes is an azo dye. 
     
     
       3. The element of claim 2 wherein at least one of said dyes is an anthraquinone dye. 
     
     
       4. The element of claim 2 wherein said eutectic composition has a melting point which is at least 5° C. lower than the lowest melting temperature of any of said dyes in said eutectic composition. 
     
     
       5. The element of claim 4 wherein at least some portion of each dye which forms said eutectic composition is present within said binder layer as a solid particulate. 
     
     
       6. The element of claim 1 wherein at least one of said dyes is an anthraquinone dye. 
     
     
       7. A thermal dye transfer composition as in claim 1 wherein said pair of dyes has a molar ratio in the range 0.05 to 20.0 at the eutectic point composition. 
     
     
       8. A thermal dye transfer composition as in claim 1 wherein at least one of said dyes is selected from the group consisting of azo dyes, anthraquinone dyes, aminostyryl, azomethine, and disulphone classes, and combinations thereof. 
     
     
       9. The element of claim 1 wherein said mixture of at least two dyes consists of two dyes. 
     
     
       10. A thermal dye transfer element comprising a substrate having on one side thereof a layer of a polymeric binder having a mixture of at least two .Iadd.yellow .Iaddend.dyes therein, said dyes being capable of forming a eutectic composition and at least one pair of said dyes being present within said binder in a ratio which is between 0.25 and 4.0 times the ratio of said pair of dyes in a eutectic point composition, said mixture of dyes comprising at least .[.20%.]. .Iadd.20 to 90% .Iaddend.by weight of said layer, and said eutectic composition has a melting point which is at least 5° C. lower than the lowest melting temperature of any of said dyes in said eutectic composition. 
     
     
       11. A thermal dye transfer element comprising a substrate having on one side thereof a layer of at least two .Iadd.yellow .Iaddend.dyes therein, said dyes being capable of forming a eutectic composition and at least one pair of said dyes being present .[.within said binder.]. in a ratio which is between 0.25 and 4.0 times the ratio of said pair of dyes in a eutectic point composition, and said eutectic composition has a melting point which is at least 5° C. lower than the lowest melting temperature of any of said dyes in said eutectic composition. 
     
     
       12. A thermal dye transfer element comprising a single, self-sustaining layer of a polymeric binder having a mixture of at least two .Iadd.yellow .Iaddend.dyes therein, said dyes being capable of forming a eutectic composition and at least one pair of said dyes being present within said binder in a ratio which is between 0.25 and 4.0 times the ratio of said pair of dyes in a eutectic point composition, said mixture of dyes comprising at least .[.20%.]. .Iadd.20 to 90% .Iaddend.by weight of said layer, and said eutectic composition has a melting point which is at least 5° C. lower than the lowest melting temperature of any of said dyes in said eutectic composition. 
     
     
       13. The element of claim 12 wherein at least one said dyes is an azo dye. 
     
     
       14. The element of claim 13 wherein at least one of said dyes is an anthraquinone dye. 
     
     
       15. The element of claim 14 wherein said eutectic composition has a melting point which is at least 5° C. lower than the lowest melting temperature of any of said dyes in said eutectic composition. 
     
     
       16. The element of claim 15 wherein at least some portion of each dye which forms said eutectic composition is present within said binder layer as a solid particulate. 
     
     
       17. The element of claim 13 wherein said eutectic composition has a melting point which is at least 5° C. lower than the lowest melting temperature of any of said dyes in said eutectic composition. 
     
     
       18. The element of claim 17 wherein at least some portion of each dye which forms said eutectic composition is present within said binder layer as a solid particulate. 
     
     
       19. The element of claim 12 wherein at least one of the said dyes is an anthraquinone dye. 
     
     
       20. The element of claim 19 wherein said eutectic composition has a melting point which is at least 5° C. lower than the lowest melting temperature of any of said dyes in said eutectic composition. 
     
     
       21. The element of claim 20 wherein at least some portion of each dye which forms said eutectic composition is present within said binder layer as a solid particulate. 
     
     
       22. The element of claim 12 wherein at least some portion of each dye which forms said eutectic composition is present within said binder layer as a solid particulate. .Iadd.23. A thermal dye transfer element comprising a substrate having on one side thereof a layer of a polymeric binder having a mixture of at least two magenta dyes therein, said dyes being capable of forming a eutectic composition and at least one pair of said dyes being present within said binder in a ratio which is between 0.25 and 4.0 times the ratio of said pair of dyes in a eutectic point composition, said mixture of dyes comprising at least 20 to 90% by weight of said layer and said eutectic composition having a melting point which is at least 5° C. lower than the lowest melting temperature of any of said dyes in said eutectic composition, wherein at least one of said at least two magenta dyes is a dye selected from the group consisting of a monoazo dye, aminostyryl dye, an azomethine dye, and a disulfone dye. 
     
     
        .Iaddend..Iadd.     The element of claim 23 wherein said eutectic composition has a melting point which is at least 10° C. lower than the lowest melting temperature of any of said dyes in said eutectic composition. .Iaddend..Iadd.25. The element of claim 23 wherein at least some portion of each dye which forms said eutectic composition is present within said binder layer as a solid particulate. .Iaddend..Iadd.26. A thermal dye transfer composition as in claim 1 wherein at least one of said pair of dyes has a molar ratio at the eutectic point composition. 
     
     
        .Iaddend..Iadd.27.  The element of claim 23 wherein in addition to said at least one dye, an azo dye is in said eutectic composition. .Iaddend..Iadd.28. The element of claim 23 wherein in addition to said at least one dye, an anthraquinone dye is in said eutectic composition. 
     
     
        .Iaddend..Iadd.29.  The element of claim 23 wherein in addition to said at least one dye, another dye selected from the group consisting of azo dyes, anthraquinone dyes, aminostyryl dyes, azomethine dyes, and disulfone dyes 
     
     
        is present in said eutectic composition. .Iaddend..Iadd.30.  A thermal dye transfer element comprising a substrate having on one side thereof a layer of a polymeric binder having a mixture of at least two cyan dyes therein, said dyes being capable of forming a eutectic composition and at least one pair of said dyes being present within said binder in a ratio which is between 0.25 an 4.0 times the ratio of said pair of dyes in a eutectic point composition, said mixture of dyes comprising at least 20 to 90% by weight of said layer, and said eutectic composition having a melting point which is at least 5° C. lower than the lowest melting temperature of any of said dyes in said eutectic composition, at least one of said at least two cyan dyes being selected from the group consisting of an azo dye and an azomethine dye. .Iaddend..Iadd.31. A thermal dye transfer element as in claim 30 wherein a second dye present is an anthraquinone dye. .Iaddend.