Polymer mixture having aromatic polycarbonate styrene I containing copolymer and/or graft polymer and a flame-retardant, articles formed therefrom

Abstract

The invention relates to a polymer mixture which comprises an aromatic polycarbonate, a styrene-containing copolymer and/or a styrene-containing graft polymer and a flame-retardant. It has been found that the use of a certain type of flame-retardants, namely oligomeric phosphates leads to a polymer mixture having improved properties. In particular to a polymer mixture having a good combination of flame retardancy, non-juicing characteristics of the flame retardant, good plastifying effect and good heat resistance.

. .We claim.!. .Iadd.What is claimed is.Iaddend.: . . 
     
       1.  A polymer mixture which comprises an aromatic polycarbonate (A), a styrene-containing copolymer and/or styrene-containing graft copolymer (B) and a phosphate based flame-retardant (C), characterized in that the polymer mixture comprises as flame-retardant an oligomeric phosphate or a blend of oligomeric phosphates with the following formula I: ##STR3## wherein R 1 , R 2 , R 3 , and R 4 , each represent an aryl or an alkaryl group chosen independently of each other with the proviso that none of R 1 , R 2 , R 3  and R 4  are xylyl and wherein X is an arylene group, m 1 , m 2 , m 3 , and m 4 , each independently of each other are 0 or 1 and wherein n=1,2,3,4 or 5 or wherein, in case of a blend of phosphates, n has an average value of 1 to 5..!.. . 
     
     
       2.  A polymer mixture as claimed in claim 1 characterized in that the polymer mixture comprises an oligomeric phosphate of formula 1 or a blend of such phosphates wherein the (average) value of n is greater than 1 but smaller than 3..!.. .3. A polymer mixture as claimed in claim 1, characterized in that the polymer mixture comprises an oligomeric phosphate of formula 1, or a blend of such phosphates wherein the (average) value of n is equal to or greater than 1, but equal to or 
     
     
        smaller than 2..!.4. A polymer mixture . .as claimed in claim 1, characterized in that the polymer comprises an oligomeric phosphate of formula 1, or a blend of such phosphates,.!. .Iadd.which comprises an aromatic polycarbonate (A), a styrene-containing copolymer and/or styrene-containing graft copolymer (B) and a phosphate based flame-retardant (C), characterized in that the polymer mixture comprises as flame-retardant a blend of oligomeric phosphates with the following formula I: ##STR4## .Iaddend.wherein m 1 , m 2 , m 3  and m 4  are all equal to 1, R 1 , R 2 , R 3  and R 4  all represent a phenyl group, X represents a phenylene group and n has an (average) value of . .1,2-1.7.!. 
     
     
        .Iadd.1.2-1.7.Iaddend.. 5. A polymer mixture according to claim . .1.!. .Iadd.4.Iaddend., characterized in that the mixture comprises 5-95% by weight of constituent A and 95-5% by weight of constituent B, calculated 
     
     
        with respect to the sum of the quantities of A and B. 6. A polymer mixture according to claim . .1.!. .Iadd.4.Iaddend., characterized in that the mixture comprises as constituent B a graft copolymer built up from a rubber backbone upon which have been grafted styrene, alphamethylstyrene, a styrene substituted with one or more halogen atoms or with organic groups in its aromatic nucleus, methylmethacrylate or a blend thereof and acrylonitrile, methacrylonitrile, methylmethacrylate, maleic anhydride, N-substituted . .maleinimide.!. .Iadd.maleimide .Iaddend.or a blend 
     
     
        thereof. 7. A polymer mixture according to claim . .1 characterised.!. .Iadd.4 characterized .Iaddend.in that the mixture comprises as constituent B a copolymer of styrene, alpha-methylstyrene, a styrene substituted with one or more halogen atoms or with organic groups in its aromatic nucleus, methylmethacrylate or a blend thereof and acrylonitrile, methacrylonitrile, methylmethacrylate, maleic anhydride, N-substituted 
     
     
        . .maleinimid.!. .Iadd.maleimide .Iaddend.or a blend thereof. 8. A polymer mixture according to claim . .1.!. .Iadd.4.Iaddend., characterized in that the mixture comprises as constituent B a graft copolymer built up from a rubber backbone upon which have been grafted styrene, alphamethylstyrene, a styrene substituted with one or more halogen atoms or with organic groups in its aromatic nucleus, methylmethacrylate or a blend thereof and acrylonitrile, methacrylonitrile, methylmethacrylate, maleic anhydride, N-substituted . .maleinimide.!. .Iadd.maleimide .Iaddend.or a blend thereof and a copolymer of styrene, alphamethylstyrene, a styrene substituted with one or more halogen atoms or with organic groups in its aromatic nucleus, methylmethacrylate or a blend thereof and acrylonitrile, methacrylonitrile, methylmethacrylate, maleic anhydride, N-substituted 
     
     
        . .maleinimide.!. .Iadd.maleimide .Iaddend.or a blend thereof. 9. A polymer mixture according to claim . .1.!. .Iadd.4.Iaddend., characterized in that the mixture comprises 1-25 parts by weight of constituent C per 
     
     
        100 part by weight of A+B. 10. A polymer mixture according to claim . .1.!. .Iadd.4.Iaddend., characterized in that the mixture comprises 5-20 
     
     
        parts by weight of constituent C per 100 parts by weight of A+B. 11. A polymer mixture as claimed in claim . .1.!. .Iadd.4.Iaddend., . .characterised.!. .Iadd.characterized .Iaddend.in that the polymer mixture moreover comprises one or more of the following flame retardants (D): a salt having flame-retarding properties for aromatic polycarbonates and/or   a halogen-containing low-molecular weight compound and/or high-molecular weight polymer and/or   a perfluoroalkane polymer and/or   
     
     
       a metal compound active as a synergist. 12. A polymer mixture as claimed in claim . .1.!. .Iadd.4.Iaddend., characterized in that the polymer mixture comprises the oligomeric phosphate (C) in combination with a salt having 
     
     
        flame-retarding properties for aromatic polycarbonate. 13. A polymer mixture as claimed in claim . .1.!. .Iadd.4.Iaddend., . .characterised.!. .Iadd.characterized .Iaddend.in that the polymer mixture moreover 
     
     
        comprises a perfluoroalkane polymer. 14. Articles formed from the polymer mixture as claimed in claim . .1.!. .Iadd.4.Iaddend.. .Iadd.15. A polymer mixture which comprises an aromatic polycarbonate (A), a styrene-containing copolymer and/or styrene-containing graft copolymer (B) and a phosphate based flame-retardant (C), characterized in that the polymer mixture comprises as flame-retardant a blend of oligomeric phosphates with the following formula I: ##STR5## wherein R 1 , R 2 , R 3  and R 4  each represent an aryl or an alkaryl group chosen independently of each other with the proviso that none of R 1 , R 2 , R 3  and R 4  are xylyl and wherein X is an arylene group, m 1 , m 2 , m 3  and m 4  each independently of each other are 0 or 1 and wherein n has an average value of 1.2-1.7. 
     
     
        .Iaddend..Iadd.16.  A polymer mixture according to claim 15, characterized in that the mixture comprises 5-95% by weight of constituent A and 95-5% by weight of constituent B, calculated with respect to the sum of the quantities of A and B. .Iaddend..Iadd.17. A polymer mixture according to claim 15, characterized in that the mixture comprises as constituent B a graft copolymer built up from a rubber backbone upon which have been grafted styrene, alphamethylstyrene, a styrene substituted with one or more halogen atoms or with organic groups in its aromatic nucleus, methylmethacrylate or a blend thereof and acrylonitrile, methacrylonitrile, methylmethacrylate, maleic anhydride, N-substituted maleimide or a blend thereof. .Iaddend..Iadd.18. A polymer mixture according to claim 15 characterized in that the mixture comprises as constituent B a copolymer of styrene, alpha-methylstyrene, a styrene substituted with one or more halogen atoms or with organic groups in its aromatic nucleus, methylmethacrylate or a blend thereof and acrylonitrile, methacrylonitrile, methylmethacrylate, maleic anhydride, N-substituted maleimide or a blend thereof. .Iaddend..Iadd.19. A polymer mixture according to claim 15, characterized in that the mixture comprises as constituent B a graft copolymer built up from a rubber backbone upon which have been grafted styrene, alphamethylstyrene, a styrene substituted with one or more halogen atoms or with organic groups in its aromatic nucleus, methylmethacrylate or a blend thereof and acrylonitrile, methacrylonitrile, methylmethacrylate, maleic anhydride, N-substituted maleimide or a blend thereof and a copolymer of styrene, alphamethylstyrene, a styrene substituted with one or more halogen atoms or with organic groups in its aromatic nucleus, methylmethacrylate or a blend thereof and acrylonitrile, methacrylonitrile, methylmethacrylate, maleic anhydride, N-substituted maleimide or a blend thereof. 
     
     
        .Iaddend..Iadd.20.  A polymer mixture according to claim 15, characterized in that the mixture comprises 1-25 parts by weight of constituent C per 100 part by weight of A+B. .Iaddend..Iadd.21. A polymer mixture according to claim 15, characterized in that the mixture comprises 5-20 parts by weight of constituent C per 100 parts by weight of A+B. .Iaddend..Iadd.22. A polymer mixture as claimed in claim 15, characterized in that the polymer mixture moreover comprises one or more of the following flame retardants (D): a salt having flame-retarding properties for aromatic polycarbonates and/or   a halogen-containing low-molecular weight compound and/or high-molecular weight polymer and/or   a perfluoroalkane polymer and/or   a metal compound active as a synergist. .Iaddend..Iadd.23. A polymer mixture as claimed in claim 15, characterized in that the polymer mixture comprises the oligomeric phosphate (C) in combination with a salt having   
     
     
        flame-retarding properties for aromatic polycarbonate. .Iaddend..Iadd.24. A polymer mixture as claimed in claim 15, characterized in that the polymer mixture moreover comprises a perfluoroalkane polymer. .Iaddend..Iadd.25. Articles formed from the polymer mixture as claimed in claim 15. .Iaddend.