Impact-resistant polyamide composition

Abstract

A moldable composition, which comprises polyamide incorporated with at least one polymer selected from the group consisting of hydrogenated block copolymer and ethylene-containing polymer, and with a specified modified block copolymer each in a specified ratio and amount, having excellent impact resistance and good balance of properties among stiffness, heat resistance and weld zone strength, as well as good moldability and excellent appearance of molded articles which have utility in a wide field of application including automobile parts, electric appliance parts and electronic parts.

What is claimed is: .[.1. A polyamide composition which comprises (a) 60 to 90% by weight of polyamide, (b) 2 to 36% by weight of at least one polymer selected from the group consisting of (i) a hydrogenated block copolymer comprising a vinyl aromatic polymer block A and an olefin polymer block B, the degree of unsaturation of said block B not exceeding 20%, and (ii) an ethylene-containing polymer, and (c) 2 to 36% by weight of a modified block copolymer formed by bonding a molecular unit containing a carboxylic acid group or its derivative group to a hydrogenated block copolymer, which is the same as defined above, the amount of said molecular unit containing a carboxylic acid group or its derivative group bonded to the modified block copolymer of (c), expressed in terms of x parts by weight per 100 parts by weight of the hydrogenated block copolymer before modification, and the compounding ratio of said modified block copolymer of (c) to the sum of the weight of the modified block copolymer of (c) and the weight of the at least one polymer of (b), expressed in terms of y, being within the range specified by the expression 
     
        according to claim 1 wherein (c) is 3 to 30% by weight..]..[.7.  The polyamide composition according to claim 1 wherein the carboxylic acid group or its derivative group of (c) is derived from maleic anhydride..]..[.8. The polyamide composition according to claim 1 wherein the modification amount of said modified block copolymer is 0.15 to 1.8 parts by weight per 100 parts by weight of the hydrogenated block copolymer before modification..]..[.9. The polyamide composition according to claim 1 wherein the compounding ratio y of said modified block copolymer is 0.15 to 0.85..]..[.10. The polyamide composition according to claim 1 wherein the relation between the compounding ratio y of said modified block polymer and the modifiction amount x of the same polymer is 
     
     
        expressed by the expression y≧x+0.6..]..Iadd.11.  A polyamide composition which comprises (a) 60 to 90% by weight of polyamide, (b) 2 to 36% by weight of a hydrogenated block copolymer comprising a vinyl aromatic polymer block A and an olefin polymer block B, the degree of unsaturation of said block B not exceeding 20%, and (c) 2 to 36% by weight of a modified block copolymer formed by bonding a molecular unit containing a carboxylic acid group or its derivative group to a hydrogenated block copolymer, which is the same as defined above, the amount of said molecular unit containing a carboxylic acid group or its derivative croup bonded to the modified block copolymer of (c), expressed in terms of x parts by weight per 100 parts by weight of the hydrogenated block copolymer before modification, and the compounding ratio of said modified block copolymer of (c) to the sum of the weight of the modified block copolymer of (c) and the weight of the polymer of (b), expressed in terms of y, being within the range specified by the expression   0.1≦x≦1.1,       0.1≦y≦0.9, and       y≧-x+0.5. .Iaddend..Iadd.12. The polyamide composition according to claim 11 wherein the amount of said polyamide is 65 to 85% by weight. .Iaddend..Iadd.13. The polyamide composition according to claim 11 wherein said polyamide is nylon 6 or nylon 66. .Iaddend..Iadd.14. The polyamide composition according to claim 11 wherein (b) is 3 to 30% by weight. .Iaddend..Iadd.15. The polyamide composition according to claim 11 wherein     
     
     
        (c) is 3 to 30% by weight. .Iaddend..Iadd.16.  The polyamide composition according to claim 11 wherein the carboxylic acid group or its derivative group of (c) is derived from maleic anhydride. .Iaddend..Iadd.17. The polyamide composition according to claim 11 wherein the compounding ratio y of said modified block copolymer is 0.15 to 0.85. .Iaddend..Iadd.18. The polyamide composition according to claim 11 wherein the relation between the compounding ratio y of said modified block polymer and the modification amount x of the same polymer is expressed by the expression y≧-x+0.6. .Iaddend..Iadd.19. A polyamide composition which comprises (a) 60 to 90% by weight of polyamide, (b) 2 to 36% by weight of an ethylene-containing polymer, and (c) 2 to 36% by weight of a modified block copolymer formed by bonding a molecular unit containing a carboxylic acid group or its derivative group to a hydrogenated block copolymer, which comprises a vinyl aromatic polymer block A and an olefin polymer block B, the degree of unsaturation of said block B not exceeding 20%, the amount of said molecular unit containing a carboxylic acid group or its derivative group bonded to the modified block copolymer of (c), expressed in terms of x parts by weight per 100 parts by weight of the hydrogenated block copolymer before modification, and the compounding ratio of said modified block copolymer of (c) to the sum of the weight of the modified block copolymer of (c) and the weight of said polymer (b), expressed in terms of y, being within the range specified by the expression   0.1≦x≦2.0,       0.1≦y≦0.9, and       y≧-x+0.5. .Iaddend.     
     
     
       .Iadd.20.  The polyamide composition according to claim 19 wherein the amount of said polyamide is 65 to 85% by weight. .Iaddend..Iadd.21. The polyamide composition according to claim 19 wherein said polyamide is nylon 6 or nylon 66. .Iaddend..Iadd.22. The polyamide composition according to claim 19 wherein (b) is 3 to 30% by weight. .Iaddend..Iadd.23. The polyamide composition according to claim 19 wherein the ethylene-containing polymer (b) is an ethylene-α-olefin copolymer. .Iaddend..Iadd.24. The polyamide composition according to claim 
     
     
        19 wherein (c) is 3 to 30% by weight. .Iaddend..Iadd.25.  The polyamide composition according to claim 19 wherein the carboxylic acid group or its derivative group of (c) is derived from maleic anhydride. .Iaddend..Iadd.26. The polyamide composition according to claim 19 wherein the modification amount x of said modified block copolymer is 0.15 to 1.8 parts by weight per 100 parts by weight of the hydrogenated block copolymer before modification. .Iaddend..Iadd.27. The polyamide composition according to claim 19 wherein the compounding ratio y of said modified block copolymer is 0.15 to 0.85. .Iaddend..Iadd.28. The polyamide composition according to claim 19 wherein the relation between the compounding ratio y of said modified block polymer and the modification amount x of the same polymer is expressed by the expression y≧-x+0.6. .Iaddend.