Stabilised olefin carbon monoxide copolymer compositions

Abstract

Polymer compositions which comprise (a) a major amount of a polymer of carbon monoxide and at least one olefin and (b) a minor amount of a pseudoboehmite are stabilised against degradation in melt processing. The polymer is suitably a polyketone.

We claim: 
     
       1. A polymer composition which comprises (a) a major amount of a polymer of carbon monoxide and at least one olefin and (b) a minor amount of a pseudoboehmite.Iadd., and providing that an aliphatic amine is not present in the composition.Iaddend.. 
     
     
       2. A polymer composition as claimed in claim 1 wherein the polymer of carbon monoxide and at least one olefin is a polyketone. 
     
     
       3. A polymer composition as claimed in claim 2 wherein the polyketone is a terpolymer of carbon monoxide, ethylene and propylene. 
     
     
       4. A polymer composition as claimed in claim 1 wherein the pseudoboehmite has a crystallite size of less than 200 Å. 
     
     
       5. A polymer composition as claimed in claim 4 wherein the pseudoboehmite has a crystallite size of less than 150 Å. 
     
     
       6. A polymer composition as claimed in claim 5 wherein the pseudoboehmite has a crystallite size in the range 20-120 Å. 
     
     
       7. A polymer composition as claimed in claim 1 wherein the pseudoboehmite has a surface area greater than 120 m 2  g -1 . 
     
     
       8. A polymer composition as claimed in claim 7 wherein the pseudoboehmite has a surface area in the range 150-400 m 2  g -1 . 
     
     
       9. A polymer composition as claimed in claim 1 wherein the amount of pseudoboehmite is in the range 0.1 to 10 parts per hundred parts of the total composition. 
     
     
       10. A polymer composition as claimed in claim 9 wherein the pseudoboehmite is present in the composition in the range 1.0 to 2.0 parts per hundred parts of the total composition. .Iadd. 
     
     
       11.  A polymer composition consisting essentially of (a) a major amount of a polymer of carbon monoxide and at least one olefin and (b) a melt processing stabilizer in the form of a minor amount of pseudoboehmite and optionally (c) antioxidants, blowing agents, UV stabilizer, fire retardants, mold release agents, lubricants, processing agents and fillers..Iaddend.