Flame resistant polycarbonate/abs moulding compounds resistant to stress cracking

Abstract

Flame resistant, thermoplastic molding compounds containing A) 40 to 98 parts by weight of an aromatic polycarbonate, B) 3 to 50 parts by weight of a vinyl copolymer, C) 0.5 to 40 parts by weight of a graft polymer, D) 0.5 to 20 parts by weight of a mixture of D.1) 10 to 90 wt. %, related to D) , of a monophosphorus compound of the formula (I) ##STR1## D.2) 90 to 10 wt. %, related to D), of an oligomeric phosphorus compound of the formula (II) ##STR2## and E) 0.05 to 5 parts by weight of a fluorinated polyolefin with an average particle diameter of 0.05 to 1000 μm, a density of 1.2 to 2.3 g/cm 3 and a fluorine content of 65 to 76 wt. %.

We claim: 
     
       1. Flame resistant, thermoplastic moulding compounds containing A) 40 to 98 parts by weight of an aromatic polycarbonate;   B) 3 to 50 parts by weight of a vinyl copolymer prepared from B.1) 50 to 98 parts by weight of styrene, α-methylstyrene, ring-substituted styrenes, C 1  -C 8  alkyl methacrylates, C 1  -C 8  alkyl acrylates or mixtures thereof and   B.2) 50 to 2 parts by weight of acrylonitrile, methacrylonitrile, C 1  -C 8  alkyl methacrylates, C 1  -C 8  alkyl acrylates, maleic anhydride, N-substituted maleimides and mixtures thereof;     C) 0.5 to 40 parts by weight of a graft polymer prepared from C.1) 5 to 95 parts by weight of a mixture of C.1.1) 50 to 95 parts by weight of styrene, α-methylstyrene, halogen or methyl ring-substituted styrene, C 1  -C 8  alkyl methacrylate, C 1  -C 8  alkyl acrylate, or mixtures of these compounds and   C.1.2) 5 to 50 parts by weight of acrylonitrile, methacrylonitrile, C 1  -C 8  alkyl methacrylates, C 1  -C 8  alkyl acrylate, maleic anhydride, C 1  -C 4  alkyl or phenyl N-substituted maleimides or mixtures of these compounds on     C.2) 5 to 95 parts by weight of a polymer with a glass transition temperature of below -10° C.     D) 0.5 to 20 parts by weight of a mixture of D.1) 14 to 40 wt. %, related to D), of a monophosphorus compound of the formula (I) ##STR9## in which R 1 , R 2  and R 3  are independently phenyl, cresyl, cumyl, naphthyl, chlorophenyl, bromophenyl, pentachlorophenyl or pentabromophenyl     n means 1 and D.2) 86 to 60 wt. %, related to D), of an oligomeric phosphorus compound of the formula (II) ##STR10## in which R 4 , R 5 , R 6 , R 7  are independently cresyl, phenyl xylenyl , propylphenyl or butylphenyl, or brominated or chlorinated derivatives thereof,     n means 1,   y has an average value of between 1 and 2, and   x means a residue derived from resorcinol or hydroquinone, and   E) 0.05 to 5 parts by weight of a fluorinated polyolefin with an average particle diameter of 0.05 to 1000 μm, a density of 1.2 to 2.3 g/cm 3  and a fluorine content of 65 to 76 wt. %.   
     
     
       2. Moulding compounds according to claim 1, containing 50 to 95 parts by weight of an aromatic polycarbonate A. 
     
     
       3. Moulding compounds as according to claim 1 containing component D) in amounts of monophosphorus compound D.1) and an oligomeric phosphorus compound D.2) in combined amounts effective to improve stress cracking resistance. 
     
     
       4. Flame resistant thermoplastic moulding compound according to claim 1 containing additives selected from the group consisting of stabilizers, dyes, pigments, lubricants and mold release agents, fillers and reinforcing materials, nucleating agents and antistatic agents. 
     
     
       5. The flame resistant, thermoplastic molding compound of claim 1, wherein in component D.2. each of R 4 , R 5 , R 6  and R 7  are phenyl. 
     
     
       6. A flame resistant thermoplastic molding compound having improved stress resistance, consisting essentially of: A) 40-98 parts by weight of aromatic polycarbonate;   B) 3-50 parts by weight of styrene/acrylonitrile copolymer;   C) 0.5 to 40 parts by weight of a graft polymer of styrene and acrylonitrile on particulate, crosslinked polybutadiene rubber;   D) 0.5 to 20 parts by weight of a mixture of: D.1.) 14 to 40%, based on D), of triphenyl phosphate;   D.2.) 86 to 60%, based on D), of m-phenylene-bis(diphenylphosphate); and     E) 0.05 to 5 parts by weight of tetrafluoroethylene polymer.   
     
     
       7. The molding compound of claim 6 containing 50 to 95 parts of A), 5 to 40 parts of B), 2 to 12 parts of C), 2 to 15 parts of D), and 0.1 to 0.5 parts of E). 
     
     
       8. The molding compound of claim 7, containing 67 parts of A), 10 parts of B), 7.5 parts of C), and 3.5 parts of E). 
     
     
       9. Flame resistant, thermoplastic moulding compounds containing A) 40 to 98 parts by weight of an aromatic polycarbonate;   B) 3 to 50 parts by weight of a vinyl copolymer prepared from B.1) 50 to 98 parts by weight of styrene, α-methylstyrene, ring-substituted styrenes, C 1  -C 8  alkyl methacrylates, C 1  -C 8  alkyl acrylates or mixtures thereof and   B.2) 50 to 2 parts by weight of acrylonitrile, methacrylonitrile, C 1  -C 8  alkyl methacrylates, C 1  -C 8  alkyl acrylates, maleic anhydride, N-substituted maleimides and mixtures thereof;     C) 0.5 to 40 parts by weight of a graft polymer prepared from C.1) 5 to 95 parts by weight of a mixture of C.1.1.) 50 to 95 parts by weight of styrene, α-methylstyrene, halogen or methyl ring-substituted styrene, C 1  -C 8  alkyl methacrylate C 1  -C 8  alkyl acrylate, or mixtures of these compounds and   C.1.2.) 5 to 50 parts by weight of acrylonitrile, methacrylonitrile, C 1  -C 8  alkyl methacrylates C 1  -C 8  alkyl acrylate, maleic anhydride, C 1  -C 4  alkyl or phenyl N-substituted maleimides or mixtures of these compounds on     C.2) 5 to 95 parts by weight of a polymer with a glass transition temperature of below -10° C.     D) 0.5 to 20 parts by weight of a mixture of D.1) 10 to 90 wt. %, related to D), of a monophosphorus compound of the formula (I) ##STR11## in which R 1 , R 2  and R 3  mutually independently mean optionally halogenated C 1  -C 8  alkyl, C 6  -C 20  aryl or C 7  -C 12  aralkyl     n means 1 and D.2) 90 to 10 wt. %, related to D), of an oligomeric phosphorus compound of the formula (II) ##STR12## in which R 4 , R 5 , R 6 , R 7  are mutually independently cresyl, phenyl, xylenyl, propylphenyl or butylphenyl, or brominated or chlorinated derivatives thereof     n means 1,   Y means an average value of between 1 and 2, and   X means a residue derived from resorcinol or hydroquinone, and   E) 0.05 to 5 parts by weight of a fluorinated polyolefin with an average particle diameter of 0.05 to 1000 μm, a density of 1.2 to 2.3 g/cm 3  and a fluorine content of 65 to 76 wt. %.   
     
     
       10. The moulding compound of claim 9, wherein component C) is one or more of polybutadiene, butadiene styrene copolymer, acrylate rubber, polyisobutadiene, or polyisoprene. 
     
     
       11. The moulding composition of claim 9, wherein component C) is polybutadiene, butadiene/styrene copolymer, or mixtures thereof. .Iadd. 
     
     
       12.  Flame resistant, thermoplastic moulding compounds containing A) 40 to 98 parts by weight of an aromatic polycarbonate;   B) 3 to 50 parts by weight of a vinyl copolymer prepared from B.1) 50 to 98 parts by weight of styrene, α-methylstyrene, ring-substituted styrenes, C 1  -C 8  alkyl methacrylates, C 1  -C 8  alkyl acrylates or mixtures thereof and   B.2) 50 to 2 parts by weight of acrylonitrile, methacrylonitrile, C 1  -C 8  alkyl methacrylates, C 1  -C 8  alkyl acrylates, maleic anhydride, N-substituted maleimides and mixtures thereof;     C) 0.5 to 40 parts by weight of a graft polymer prepared from C.1) 5 to 95 parts by weight of a mixture of C.1.1) 50 to 95 parts by weight of styrene, α-methylstyrene, halogen or methyl ring-substituted styrene, C 1  -C 8  alkyl methacrylate, C 1  -C 8  alkyl acrylate, or mixtures of these compounds and   C.1.2) 5 to 50 parts by weight of acrylonitrile, methacrylonitrile, C 1  -C 8  alkyl methacrylates, C 1  -C 8  alkyl acrylate, maleic anhydride, C 1  -C 4  alkyl alkyl or phenyl N-substituted maleimides or mixtures of these compounds on     C.2) 5 to 95 parts by weight of a polymer with a glass transition temperature of below -10° C.,     D) 0.5 to 20 parts by weight of a mixture of D.1) 10 to 90 wt. %, related to D), of a monophosphorus compound of the formula (I) ##STR13## in which R 1 , R 2  and R 3  mutually independently mean optionally halogenated C 1  -C 8  alkyl, C 6  -C 20  aryl or C 7  -C 12  aralkyl     n means 1 and D.2) 90 to 10 wt. %, related to D), of an oligomeric phosphorus compound of the formula (II) ##STR14## in which R 4 , R 5 , R 6 , R 7  are mutually independently cresyl, phenyl, xylenyl, propylphenyl or butylphenyl, or brominated or chlorinated derivatives thereof     n means 1,   y means an average value between 1 and 2, and   x means a residue derived from bisphenol A, rescorcinol or hydroquinone, and   E) 0.05 to 5 parts by weight of a fluorinated polyolefin with an average particle diameter of 0.05 to 1000 μm, a density of 1.2 to 2.3 g/cm 3  and a fluorine content of 65 to 76 wt. %..Iaddend..Iadd.   
     
     
       13.  Flame resistant, thermoplastic moulding compounds containing A) 40 to 98 parts by weight of an aromatic polycarbonate;   B) 3 to 50 parts by weight of a vinyl copolymer prepared from B.1) 50 to 98 parts by weight of styrene, α-methylstyrene, ring-substituted styrenes, C 1  -C 8  alkyl methacrylates, C 1  -C 8  alkyl acrylates or mixtures thereof and   B.2) 50 to 2 parts by weight of acrylonitrile, methacrylonitrile, C 1  -C 8  alkyl methacrylates, C 1  -C 8  alkyl acrylates, maleic anhydride, N-substituted maleimides and mixtures thereof;     C) 0.5 to 40 parts by weight of a graft polymer prepared from C.1) 5 to 95 parts by weight of a mixture of C.1.1) 50 to 95 parts by weight of styrene, α-methylstyrene, halogen or methyl ring-substituted styrene, C 1  -C 8  alkyl methacrylate, C 1  -C 8  alkyl acrylate, or mixtures of these compounds and   C.1.2) 5 to 50 parts by weight of acrylonitrile, methacrylonitrile, C 1  -C 8  alkyl methacrylates, C 1  -C 8  alkyl acrylate, maleic anhydride, C 1  -C 4  alkyl or phenyl N-substituted maleimides or mixtures of these compounds on     C.2) 5 to 95 parts by weight of a polymer with a glass transition temperature of below -10° C.,     D) 0.5 to 20 parts by weight of a mixture of D.1) 14 to 40 wt. %, related to D), of a monophosphorus compound of the formula (I) ##STR15## in which R 1 , R 2  and R 3  are independently phenyl, cresyl, cumyl, naphthyl, chlorophenyl, bromophenyl, pentachlorophenyl or pentabromophenyl     n means 1 and D.2) 86 to 60 wt. %, related to D), of an oligomeric phosphorus compound of the formula (II) ##STR16## in which R 4 , R 5 , R 6 , R 7  are independently cresyl, phenyl, xylenyl, propylphenyl or butylphenyl, or brominated or chlorinated derivatives thereof,     n means 1,   y has an average value between 1 and 2, and   x means a residue derived from bisphenol A, rescorcinol or hydroquinone, and   E) 0.05 to 5 parts by weight of a fluorinated polyolefin with an average particle diameter of 0.05 to 1000 μm, a density of 1.2 to 2.3 g/cm 3  and a fluorine content of 65 to 76 wt. %..Iaddend.