Pigment-dispersed color-filter composition comprising an alkali-soluble block copolymer as a binder

Abstract

The present invention provides a pigment dispersed color-filter composition containing a binder polymer such as an alkali-soluble block copolymer; a radiation-sensitive compound; and a pigment. The pigment-dispersed color-filter composition which further contains an organic medium, or an organic medium and a carboxylic acid is also provided.

What is claimed is:  
     
       1. A pigment-dispersed color-filter composition comprising an admixture of: 
       (A) an alkali-soluble block copolymer composed of a block having an acid group and a block having no acid group;  
       (B) a radiation-sensitive compound,  
       (C) a pigment,  
       (D) an organic medium, and  
       (E) an aliphatic or aromatic dicarboxylic acid having a molecular weight of 1,000 or less.  
     
     
       2. The composition of claim  1 , wherein the radiation-sensitive compound (B) is selected from the group consisting of a polymerization initiator which generates radicals under irradiation with radiation and is selected from a carbonium compound, an azo compound, an azide compound, an organic sulfur compound, a peroxide compound and a trihalomethane compound, and a photo-crosslinking agent having at least two functional groups which generate carbene or nitrene under irradiation with radiation. 
     
     
       3. The composition of claim  1 , wherein the organic medium (D) is selected from the group consisting of ethyl lactate, methyl 3-methoxypropionate, ethyl 3-ethoxypropionate, ethyl 2-ethoxypropionate, methylcellosolve acetate, ethylcellosolve acetate, diethylene glycol dimethyl ether, diethylene glycol diethyl ether and propylene glycol monomethyl ether acetate. 
     
     
       4. The composition of claim  1 , wherein the organic medium is present in an amount of at least 50% by wt. of the composition. 
     
     
       5. The composition of claim  1 , wherein the aliphatic or aromatic dicarboxylic acid is selected from the group consisting of malonic acid, citraconic acid, itaconic acid, mesaconic acid, fumaric acid and phthalic acid. 
     
     
       6. The composition of claim  1 , wherein the alkali-soluble block copolymer is a copolymer derived from benzyl methacrylate, methacrylic acid and polystyrene macromonomer, or a copolymer derived from methyl methacrylate, methacrylic acid and polystyrene macromonomer. 
     
     
       7. A pigment- dispersed color - filter composition comprising an admixture of:    
       ( A )  an alkali - soluble block copolymer composed of a block having an acid group and a block having no acid group;    
       ( B )  a radiation - sensitive composition comprising  1 . )  a polymerization initiator selected from the group consisting of a carbonium compound, an azide compound, an organic sulfur compound, a peroxide compound and a trihalomethane compound and  2 . )  a compound containing polyvalent unsaturated double bonds and is polymerized under irradiation with radiation;    
       ( C )  a pigment;    
       ( D )  an organic medium; and    
       ( E )  an aliphatic or aromatic dicarboxylic acid having a molecular weight of  1 , 000  or less.   
     
     
       8. The composition of claim  7 , wherein the organic medium ( D )  is selected from the group consisting of ethyl lactate, methyl  3   - methoxypropionate, ethyl  3   - ethoxypropionate, ethyl  2   - ethoxypropionate, methyl - cellosolve acetate, ethylcellosolve acetate, diethylene glycol dimethyl ether, diethylene glycol diethyl ether and propylene glycol monomethyl ether acetate.   
     
     
       9. The composition of claim  7 , wherein the organic medium is present in an amount of at least  50 %  by weight of the composition.   
     
     
       10. The composition of claim  7 , wherein the aliphatic or aromatic dicarboxylic acid is selected from the group consisting of malonic acid, citraconic acid, itaconic acid, mesaconic acid, fumaric acid and phthalic acid. 
     
     
       11. The composition of claim  7 , wherein the alkali soluble block copolymer is a copolymer derived from benzyl methacrylate, methacrylic acid and polystyrene macromonomer, or a copolymer derived from methyl methacrylate, methacrylic acid and polystyrene macromonomer.