Chiral optical polymer based information storage material

Abstract

An optical information storage material which can reversibly store said information comprising a polymeric material with a dependence of optical activity on temperature characterized in that the optical activity is substantially invariant at temperatures below Tg of said polymer, and variant at a temperatures at or near or above the Tg.

What is claimed is:  
     
       1. An optical information storage material which can reversibly store said information comprising a chiral polymeric material with a dependence of optical activity on temperature characterized in that the optical activity is substantially invariant at temperatures below Tg of said polymer, and variant at temperatures at or near or above the Tg. 
     
     
       2. The optical information storage material of  claim 1  where the polymeric material is a blend of two polymers and the composition of the blend is adjusted to alter the Tg. 
     
     
       3. The optical information storage material of  claim 1  wherein the polymeric material is a UV transparent blend of two polymers. 
     
     
       4. The optical information storage material of  claim 1  wherein the polymer material is a polyisocyanate. 
     
     
       5. The optical information storage material of  claim 1  wherein the polymer material is a styrene-carbon monoxide copolymer. 
     
     
       6. The optical information storage material of  claim 1 , wherein the polymer material is a binapthyl labelled methacrylic acid polymer and the optical information storage is irreversible. 
     
     
       7. The optical information storage material of  claim 1 , wherein the polymer material is any polymer material with a temperature dependent optical activity. 
     
     
       8. A method for reversibly storing optical information is disclosed, comprising supplying a polymeric material with a dependence of optical activity on temperature characterized in that the optical activity is substantially invariant at temperatures below Tg of said polymer, and variant at a  temperatures at or near the Tg, exposing said material to light wherein the absorption of light induces a temperature change in the polymer and develops in said polymer a preselected optical activity, followed by quenching below Tg wherein the preselected optical activity becomes stored. 
     
     
       9. An optical information storage material which can irreversibly store said information comprising a chiral polymeric material with a dependence of optical activity on temperature characterized in that the optical activity is substantially invariant at temperatures below Tg of said polymer.  
     
     
       10. The optical information storage material of  claim 9 , wherein the polymer material is a binaphthyl labeled methacrylic acid polymer and the optical information storage is irreversible.