Transparent hologram seal

Abstract

A hologram forming layer, transparent evaporated layer, colored layer, adhesion anchor layer, and adhesive layer are sequentially laminated on the under surface of a base member. The laminated body is used as a seal by the presence of the adhesive layer. It is preferable for the base member to have adequate rigidity (flexibility, tensile strength) and surface flatness. The hologram forming layer has a relief type hologram image. The transparent evaporated layer is a multi-layered ceramic layer constructed by alternately laminating high-refractive index layers and low-refractive index layers and the thickness thereof is preferably set to 1 μm or less. In the transparent evaporated layer, the color of visible light in predetermined wavelength range is changed according to the viewing angle when it is transmitted therethrough or reflected therefrom.

What is claimed is:  
     
       1. A laminate body comprising: 
       a reflective base member; and  
       a transparent layer formed on a portion of said base member such that a pattern is formed by contrast between the portion having the transparent layer formed thereon and a remainder portion, the transparent layer having a laminated structure of first and second ceramic materials having different refractive indices, the first and second ceramic materials being laminated by an evaporation method,  
       the transparent layer selectively absorbing incident light rays such that a peak wavelength of absorption is shifted in an amount which depends on an angle of incidence of incident light rays,  
       the selective absorption causing light emitted from the laminated body to have a color which varies depending on the angle of incidence of incident light rays, the color variation being detectable by an optical instrument.  
     
     
       2. The laminated body according to  claim 1 , wherein said first ceramic material is selected from the group consisting of magnesium oxide, silicon dioxide, magnesium fluoride, calcium fluoride, cerium fluoride, aluminum fluoride, and aluminum oxide and said second ceramic material is selected from the group consisting of titanium dioxide, zirconium dioxide, zinc sulfide, zinc oxide, indium oxide, cerium dioxide and tantalum oxide. 
     
     
       3. The laminated body according to  claim 1 , further comprising a thin film layer formed on said evaporated layer and formed of an element of one of groups III to VI or formed of an oxide, carbide, nitride, or boride of an element of one of groups III to VI. 
     
     
       4. The laminated body according to  claim 1 , further comprising a protection layer, which serves as an outer resistant member for said laminated body and is formed of diamond-like carbon, silicon carbide or boron carbide. 
     
     
       5. The laminated body according to  claim 1 , wherein said reflective base member reflects substantially all of the light incident thereon. 
     
     
       6. A laminated body comprising: 
       a reflective base member; and  
       a transparent layer formed on said base member and having a laminated structure of first and second ceramic materials having different refractive indices, a first portion of the transparent layer having a different number of layers in the laminated structure than a second portion of the transparent layer such that a pattern is formed by contrast between the first and second portions, the first and second ceramic materials being laminated by an evaporation method,  
       the transparent layer selectively absorbing incident light rays such that a peak wavelength of absorption is shifted in an amount which depends on an angle of incidence of incident light rays,  
       the selective absorption causing light emitted from the laminated body to have a color which varies depending on the angle of incidence of incident light rays, the color variation being detectable by an optical instrument.  
     
     
       7. The laminated body according to  claim 6 , wherein said first ceramic material is selected from the group consisting of magnesium oxide, silicon dioxide, magnesium fluoride, calcium fluoride, cerium fluoride, aluminum fluoride, and aluminum oxide and said second ceramic material is selected from the group consisting of titanium dioxide, zirconium dioxide, zinc sulfide, zinc oxide, indium oxide, cerium dioxide and tantalum oxide. 
     
     
       8. The laminated body according to  claim 6 , further comprising a thin film layer formed on said evaporated layer and formed of an element of one of groups III to VI or formed of an oxide, carbide, nitride, or boride of an element of one of groups III to VI. 
     
     
       9. The laminated body according to  claim 6 , further comprising a protection layer, which serves as an outer resistant member for said laminated body and is formed of diamond-like carbon, silicon carbide or boron carbide. 
     
     
       10. The laminated body according to  claim 6 , wherein said reflective base member reflects substantially all of the light incident thereon. 
     
     
       11. A laminated body comprising: 
       a reflective base member; and  
       a transparent layer formed on said base member and having a laminated structure of first and second ceramic materials having different refractive indices, a first portion of the transparent layer having a thickness different than a thickness of a second portion of the transparent layer such that a pattern is formed by contrast between the first and second portions, the first and second ceramic materials being laminated by an evaporation method,  
       the transparent layer selectively absorbing incident light rays such that a peak wavelength of absorption is shifted in an amount which depends on an angle of incidence of incident light rays,  
       the selective absorption causing light emitted from the laminated body to have a color which varies depending on the angle of incidence of incident light rays, the color variation being detectable by an optical instrument.  
     
     
       12. The laminated body according to  claim 11 , wherein said first ceramic material is selected from the group consisting of magnesium oxide, silicon dioxide, magnesium fluoride, calcium fluoride, cerium fluoride, aluminum fluoride, and aluminum oxide and said second ceramic material is selected from the group consisting of titanium dioxide, zirconium dioxide, zinc sulfide, zinc oxide, indium oxide, cerium dioxide and tantalum oxide. 
     
     
       13. The laminated body according to  claim 11 , further comprising a thin film layer formed on said evaporated layer and formed of an element of one of groups III to VI or formed of an oxide, carbide, nitride, or boride of an element of one of groups III to VI. 
     
     
       14. The laminated body according to  claim 11 , further comprising a protection layer, which serves as an outer resistant member for said laminated body and is formed of diamond-like carbon, silicon carbide or boron carbide. 
     
     
       15. The laminated body according to  claim 11 , wherein said reflective base member reflects substantially all of the light incident thereon. 
     
     
       16. A laminated body comprising: 
       
         base member;  
       
       
         hologram layer formed on said base member;  
       
       
         a transparent evaporated layer formed on said hologram layer and constructed by a laminated structure of first and second ceramic materials having different refractive indices, a first portion of the transparent layer having a different number of layers in the laminated structure than a second portion of the transparent layer such that a pattern is formed by contrast between the first and second portions, the first and second ceramic materials being laminated by an evaporation method; and  
       
       
         an adhesive layer formed on said transparent evaporated layer;  
       
       
         the transparent layer selectively absorbing incident light rays such that a peak wavelength of absorption is shifted in an amount which depends on an angle of incidence light rays,  
       
       
         the selective absorption causing light emitted from the laminated body to have a color which varies depending on the angle of incidence of incident light rays, the color variation being detectable by an optical instrument. 
       
     
     
       17. The laminated body according to  claim 16 , wherein said first ceramic material is one selected from a group consisting of magnesium oxide, silicon dioxide, magnesium fluoride, calcium fluoride, cerium fluoride, aluminum fluoride, and aluminum oxide and said second ceramic material is one selected from a group consisting of titanium dioxide, zirconium dioxide, zinc sulfide, zinc oxide, indium oxide, cerium dioxide and tantalum oxide. 
     
     
       18. The laminated body according to  claim 16 , further comprising a thin film layer formed on said evaporated layer and formed of an element of III to VI group, the oxide, carbide, nitride, or boride thereof. 
     
     
       19. The laminated body according to  claim 16 , further comprising a protection layer on top surface of said body and formed of diamond- like carbon, silicon carbide or boron carbide.   
     
     
       20. A laminating body comprising: 
       
         base member;  
       
       
         a separating layer formed on said base member;  
       
       
         a hologram layer formed on said separating layer;  
       
       
         a transparent evaporated layer formed on said hologram layer and constructed by a laminated structure of first and second ceramic materials having different refractive indices, a first portion of the transparent layer having a different number of layers in the laminated structure than a second portion of the transparent layer such that a pattern is formed by contrast between the first and second portions, the first and second ceramic materials being laminated by an evaporation method; and  
       
       
         an adhesive layer formed on said transparent evaporated layer;  
       
       
         the transparent layer selectively absorbing incident light rays such that a peak wavelength of absorption is shifted in an amount which depends on an angle of incidence light rays,  
       
       
         the selective absorption causing light emitted from the laminated body to have a color which varies depending on the angle of incidence of incident light rays, the color variation being detectable by an optical instrument. 
       
     
     
       21. The laminated body according to  claim 20 , wherein said first ceramic material is one selected from a group consisting of magnesium oxide, silicone dioxide, magnesium fluoride, calcium fluoride, cerium fluoride, aluminum fluoride, and aluminum oxide and said second ceramic material is one selected from a group consisting of titanium dioxide, zirconium dioxide, zinc sulfide, zinc oxide, indium oxide, cerium dioxide and tantalum oxide. 
     
     
       22. The laminated body according to  claim 20 , further comprising a thin film layer formed on said evaporated layer and formed of an element of III to VI group, the oxide, carbide, nitride, or boride thereof. 
     
     
       23. The laminated body according to  claim 20 , further comprising a protection layer on top surface of said body and formed of diamond- like carbon, silicon carbide or boron carbide.   
     
     
       24. The laminated body according to  claim 20 , in which one of said adhesion layer and said separating layer is formed in a pattern form. 
     
     
       25. A laminated body comprising: 
       
         base member;  
       
       
         hologram layer formed on said base member;  
       
       
         transparent evaporated layer formed on said hologram layer and constructed by a laminated structure of first and second ceramic materials having different refractive indices, a first portion of the transparent layer having a different number of layers in the laminated structure than a second portion of the transparent layer such that a pattern is formed by contrast between the first and second portions, the first and second ceramic materials being laminated by an evaporation method;  
       
       
         a separating layer formed on said transparent evaporated layer; and  
       
       
         an adhesive layer formed on said separating layer,  
       
       
         the transparent layer selectively absorbing incident light rays such that a peak wavelength of absorption is shifted in an amount which depends on an angle of incidence light rays,  
       
       
         the selective absorption causing light emitted from the laminated body to have a color which varies depending on the angle of incidence of incident light rays, the color variation being detectable by an optical instrument. 
       
     
     
       26. The laminated body according to  claim 25 , wherein said first ceramic material is one selected from a group consisting of magnesium oxide, silicon dioxide, magnesium fluoride, calcium fluoride, cerium fluoride, aluminum fluoride, and aluminum oxide and said second ceramic material is one selected from a group consisting of titanium dioxide, zirconium dioxide, zinc sulfide, zinc oxide, indium oxide, cerium dioxide and tantalum oxide. 
     
     
       27. The laminated body according to  claim 25 , further comprising a thin film layer formed on said evaporated layer and formed of an element of III to VI group, the oxide, carbide, nitride, or boride thereof. 
     
     
       28. The laminated body according to  claim 25 , further comprising a protection layer on top surface of said body and formed of diamond- like carbon, silicon carbide or boron carbide.   
     
     
       29. The laminated body according to  claim 25 , in which one of said adhesion layer and said separating layer is formed in a pattern form. 
     
     
       30. A laminated body comprising: 
       
         base member;  
       
       
         transparent evaporated layer formed on said base member and constructed by a laminated structure of first and second ceramic materials having different refractive indices, a first portion of the transparent layer having a different number of layers in the laminated structure than a second portion of the transparent layer such that a pattern is formed by contrast between the first and second portions, the first and second ceramic materials being laminated by an evaporation method; and  
       
       
         a print layer formed on said transparent evaporated layer and having a predetermined printed pattern,  
       
       
         the transparent layer selectively absorbing incident light rays such that a peak wavelength of absorption is shifted in an amount which depends on an angle of incidence light rays,  
       
       
         the selective absorption causing light emitted from the laminated body to have a color which varies depending on the angle of incidence of incident light rays, the color variation being detectable by an optical instrument. 
       
     
     
       31. The laminated body according to  claim 30 , wherein said first ceramic material is one selected from a group consisting of magnesium oxide, silicon dioxide, magnesium fluoride, calcium fluoride, cerium fluoride, aluminum fluoride, and aluminum oxide and said second ceramic material is one selected from a group consisting of titanium dioxide, zirconium dioxide, zinc sulfide, zinc oxide, indium oxide, cerium dioxide and tantalum oxide. 
     
     
       32. The laminated body according to  claim 30 , further comprising a thin film layer formed on said evaporated layer and formed of an element of III to VI group, the oxide, carbide, nitride, or boride thereof. 
     
     
       33. The laminated body according to  claim 30 , further comprising a protection layer on top surface of said body and formed of diamond- like carbon, silicon carbide or boron carbide.   
     
     
       34. The laminated body according to  claim 30 , in which said print layer is formed in a pattern form having a color which is the same as or similar to the color of said transparent evaporated layer viewed from a specific direction. 
     
     
       35. A laminated body comprising: 
       
         reflective base member; and  
       
       
         transparent evaporated layer formed on said base member and constructed by a laminated structure of first and second ceramic materials having different refractive indices, a first portion of the transparent layer having a different number of layers in the laminated structure than a second portion of the transparent layer such that a pattern if formed by contrast between the first and second portions, the first and second ceramic materials being laminated by an evaporation method,  
       
       
         the transparent layer selectively absorbing incident layer rays such that a peak wavelength of absorption is shifted in an amount which depends on an angle of incidence light rays,  
       
       
         the selective absorption causing light emitted from the laminated body to have a color which varies depending on the angle of incidence of incident light rays, the color variation being detectable by an optical instrument. 
       
     
     
       36. The laminated body according to  claim 35 , wherein said first ceramic material is one selected from a group consisting of magnesium oxide, silicon dioxide, magnesium fluoride, calcium fluoride, cerium fluoride, aluminum fluoride, and aluminum oxide and said second ceramic material is one selected from a group consisting of titanium dioxide, zirconium dioxide, zinc sulfide, zinc oxide, indium oxide, cerium dioxide and tantalum oxide. 
     
     
       37. The laminated body according to  claim 35 , further comprising a thin film layer formed on said evaporated layer and formed of an element of III to VI group, the oxide, carbide, nitride, or boride thereof. 
     
     
       38. The laminated body according to  claim 35 , further comprising a protection layer on top surface of said body and formed of diamond- like carbon, silicon carbide or boron carbide.   
     
     
       39. The laminated body according to  claim 35 , in which said base member is one selected from a group consisting of gold, aluminum, chrome and nickel. 
     
     
       40. A laminated body comprising: 
       
         a base member;  
       
       
         a print layer formed on said base member and having a predetermined printed pattern; and  
       
       
         a transparent evaporated layer formed on said print layer and constructed by a laminated structure of first and second ceramic materials having different refractive indices, a first portion of the transparent layer having a different number of layers in the laminated structure than a second portion of the transparent layer such that a pattern is formed by contrast between the first and second portions, the first and second ceramic materials being laminated by an evaporation method,  
       
       
         the transparent layer selectively absorbing incident light rays such that a peak wavelength of absorption is shifted in an amount which depends on an angle of incidence light rays,  
       
       
         the selective absorption causing light emitted from the laminated body to have a color which varies depending on the angle of incidence of incident light rays, the color variation being detectable by an optical instrument. 
       
     
     
       41. The laminated body according to  claim 40 , wherein said first ceramic material is one selected from a group consisting of magnesium oxide, silicon dioxide, magnesium fluoride, calcium fluoride, cerium fluoride, aluminum fluoride, and aluminum oxide and said second ceramic material is one selected from a group consisting of titanium dioxide, zirconium dioxide, zinc sulfide, zinc oxide, indium oxide, cerium dioxide and tantalum oxide. 
     
     
       42. The laminated body according to  claim 40 , further comprising a thin film layer formed on said evaporated layer and formed of an element of III to VI group, the oxide, carbide, nitride, or boride thereof. 
     
     
       43. The laminated body according to  claim 40 , further comprising a protection layer on top surface of said body and formed of diamond- like carbon, silicon carbide or boron carbide.   
     
     
       44. A laminated body comprising: 
       
         base member;  
       
       
         hologram layer formed on said base member;  
       
       
         a transparent evaporated layer formed on said hologram layer and constructed by a laminated structure of first and second ceramic materials having different refractive indices, a first portion of the transparent layer having a thickness different from a thickness of a second portion of the transparent layer such that a pattern is formed by contrast between the first and second portions, the first and second ceramic materials being laminated by an evaporation method; and  
       
       
         an adhesive layer formed on said transparent evaporated layer,  
       
       
         the transparent layer selectively absorbing incident light rays such that a peak wavelength of absorption is shifted in an amount which depends on an angle of incidence light rays,  
       
       
         the selective absorption causing light emitted from the laminated body to have a color which varies depending on the angle of incidence of incident light rays, the color variation being detectable by an optical instrument. 
       
     
     
       45. The laminated body according to  claim 44 , wherein said first ceramic material is one selected from a group consisting of magnesium oxide, silicon dioxide, magnesium fluoride, calcium fluoride, cerium fluoride, aluminum fluoride, and aluminum oxide and said second ceramic material is one selected from a group consisting of titanium dioxide, zirconium dioxide, zinc sulfide, zinc oxide, indium oxide, cerium dioxide and tantalum oxide. 
     
     
       46. The laminated body according to  claim 44 , further comprising a thin film layer formed on said evaporated layer and formed of an element of III to VI group, the oxide, carbide, nitride, or boride thereof. 
     
     
       47. The laminated body according to  claim 44 , further comprising a protection layer on top surface of said body and formed of diamond- like carbon, silicon carbide or boron carbide.   
     
     
       48. A laminated body comprising: 
       
         base member;  
       
       
         a separating layer formed on said base member;  
       
       
         a hologram layer formed on said separating layer;  
       
       
         a transparent evaporated layer formed on said hologram layer and constructed by a laminated structure of first and second ceramic materials having different refractive indices, a first portion of the transparent layer having a thickness different from a thickness of a second portion of the transparent layer such that a pattern is formed by contrast between the first and second portions, the first and second ceramic materials being laminated by an evaporation method; and  
       
       
         an adhesive layer formed on said transparent evaporated layer,  
       
       
         the transparent layer selectively absorbing incident light rays such that a peak wavelength of absorption is shifted in an amount which depends on an angle of incidence light rays,  
       
       
         the selective absorption causing light emitted from the laminated body to have a color which varies depending on the angle of incidence of incident light rays, the color variation being detectable by an optical instrument. 
       
     
     
       49. The laminated body according to  claim 48 , wherein said first ceramic material is one selected from a group consisting of magnesium oxide, silicon dioxide, magnesium fluoride, calcium fluoride, cerium fluoride, aluminum fluoride, and aluminum oxide and said second ceramic material is one selected from a group consisting of titanium dioxide, zirconium dioxide, zinc sulfide, zinc oxide, indium oxide, cerium dioxide and tantalum oxide. 
     
     
       50. The laminated body according to  claim 48 , further comprising a thin film layer formed on said evaporated layer and formed of an element of III to VI group, the oxide, carbide, nitride, or boride thereof. 
     
     
       51. The laminated body according to  claim 48 , further comprising a protection layer on top surface of said body and formed of diamond- like carbon, silicon carbide or boron carbide.   
     
     
       52. The laminated body according to  claim 48 , in which one of said adhesion layer and said separating layer is formed in a pattern form. 
     
     
       53. A laminated body comprising: 
       
         base member;  
       
       
         hologram layer formed on said base member;  
       
       
         transparent evaporated layer formed on said hologram layer and constructed by a laminated structure of first and second ceramic materials having different refractive indices, a first portion of the transparent layer having a thickness different from a thickness of a second portion of the transparent layer such that a pattern is formed by contrast between the first and second portions, the first and second ceramic materials being laminated by an evaporation method;  
       
       
         a separating layer formed on said transparent evaporated layer; and  
       
       
         an adhesive layer formed on said separating layer,  
       
       
         the transparent layer selectively absorbing incident light rays such that a peak wavelength of absorption is shifted in an amount which depends on an angle of incidence light rays,  
       
       
         the selective absorption causing light emitted from the laminated body to have a color which varies depending on the angle of incidence of incident light rays, the color variation being detectable by an optical instrument. 
       
     
     
       54. The laminated body according to  claim 53 , wherein said first ceramic material is one selected from a group consisting of magnesium oxide, silicon dioxide, magnesium fluoride, calcium fluoride, cerium fluoride, aluminum fluoride, and aluminum oxide and said second ceramic material is one selected from a group consisting of titanium dioxide, zirconium dioxide, zinc sulfide, zinc oxide, indium oxide, cerium dioxide and tantalum oxide. 
     
     
       55. The laminated body according to  claim 53 , further comprising a thin film layer formed on said evaporated layer and formed of an element of III to VI group, the oxide, carbide, nitride, or boride thereof. 
     
     
       56. The laminated body according to  claim 53 , further comprising a protection layer on top surface of said body and formed of diamond- like carbon, silicon carbide or boron carbide.   
     
     
       57. The laminated body according to  claim 53 , in which one of said adhesion layer and said separating layer is formed in a pattern form. 
     
     
       58. A laminated body comprising: 
       
         base member;  
       
       
         transparent evaporated layer formed on said base member and constructed by a laminated structure of first and second ceramic materials having different refractive indices, a first portion of the transparent layer having a thickness different from a thickness of a second portion of the transparent layer such that a pattern is formed by contrast between the first and second portions, the first and second ceramic materials being laminated by an evaporation method; and  
       
       
         a print layer formed on said transparent evaporated layer and having a predetermined printed pattern,  
       
       
         the transparent layer selectively absorbing incident light rays such that a peak wavelength of absorption is shifted in an amount which depends on an angle of incidence light rays,  
       
       
         the selective absorption causing light emitted from the laminated body to have a color which varies depending on the angle of incidence of incident light rays, the color variation being detectable by an optical instrument. 
       
     
     
       59. The laminated body according to  claim 58 , wherein said first ceramic material is one selected from a group consisting of magnesium oxide, silicon dioxide, magnesium fluoride, calcium fluoride, cerium fluoride, aluminum fluoride, and aluminum oxide and said second ceramic material is one selected from a group consisting of titanium dioxide, zirconium dioxide, zinc sulfide, zinc oxide, indium oxide, cerium dioxide and tantalum oxide. 
     
     
       60. The laminated body according to  claim 58 , further comprising a thin film layer formed on said evaporated layer and formed of an element of III to VI group, the oxide, carbide, nitride, or boride thereof. 
     
     
       61. The laminated body according to  claim 58 , further comprising a protection layer on top surface of said body and formed of diamond- like carbon, silicon carbide or boron carbide.   
     
     
       62. The laminated body according to  claim 58 , in which said print layer is formed in a pattern form having a color which is the same as or similar to the color of said transparent evaporated layer viewed from a specific direction. 
     
     
       63. A laminated body comprising: 
       
         reflective base member; and  
       
       
         transparent evaporated layer formed on said base member and constructed by a laminated structure of first and second ceramic materials having different refractive indices, a first portion of the transparent layer having a thickness different from a thickness of a second portion of the transparent layer such that a pattern is formed by contrast between the first and second portions, the first and second ceramic materials being laminated by an evaporation method,  
       
       
         the transparent layer selectively absorbing incident light rays such that a peak wavelength of absorption is shifted in an amount which depends on an angle of incidence light rays,  
       
       
         the selective absorption causing light emitted from the laminated body to have a color which varies depending on the angle of incidence of incident light rays, the color variation being detectable by an optical instrument. 
       
     
     
       64. The laminated body according to  claim 63 , wherein said first ceramic material is one selected from a group consisting of magnesium oxide, silicon dioxide, magnesium fluoride, calcium fluoride, cerium fluoride, aluminum fluoride, and aluminum oxide and said second ceramic material is one selected from a group consisting of titanium dioxide, zirconium dioxide, zinc sulfide, zinc oxide, indium oxide, cerium dioxide and tantalum oxide. 
     
     
       65. The laminated body according to  claim 63 , further comprising a thin film layer formed on said evaporated layer and formed of an element of III to VI group, the oxide, carbide, nitride, or boride thereof. 
     
     
       66. The laminated body according to  claim 63 , further comprising a protection layer on top surface of said body and formed of diamond- like carbon, silicon carbide or boron carbide.   
     
     
       67. The laminated body according to  claim 63 , in which said base member is one selected from a group consisting of gold, aluminum, chrome and nickel. 
     
     
       68. A laminated body comprising: 
       
         a base member;  
       
       
         a print layer formed on said base member and having a predetermined printed pattern; and  
       
       
         a transparent evaporated layer formed on said print layer and constructed by a laminated structure of first and second ceramic materials having different refractive indices, a first portion of the transparent layer having a thickness different from a thickness of a second portion of the transparent layer such that a pattern is formed by contrast between the first and second portions, the first and second ceramic materials being laminated by an evaporation method,  
       
       
         the transparent layer selectively absorbing incident light rays such that a peak wavelength of absorption is shifted in an amount which depends on an angle of incidence light rays,  
       
       
         the selective absorption causing light emitted from the laminated body to have a color which varies depending on the angle of incidence of incident light rays, the color variation being detectable by an optical instrument. 
       
     
     
       69. The laminated body according to  claim 68 , wherein said first ceramic material is one selected from a group consisting of magnesium oxide, silicon dioxide, magnesium fluoride, calcium fluoride, cerium fluoride, aluminum fluoride, and aluminum oxide and said second ceramic material is one selected from a group consisting of titanium dioxide, zirconium dioxide, zinc sulfide, zinc oxide, indium oxide, cerium dioxide and tantalum oxide. 
     
     
       70. The laminated body according to  claim 69 , further comprising a thin film layer formed on said evaporated layer and formed of an element of III to VI group, the oxide, carbide, nitride, or boride thereof. 
     
     
       71. The laminated body according to  claim 70 , further comprising a protection layer on top surface of said body and formed of diamond- like carbon, silicon carbide or boron carbide.