Polyetheresteramides and compositions of antistatic polymers containing the same

Abstract

The present invention relates to polyetheresteramides (B) containing polyamide blocks comprising dicarboxylic acid sulphonates either as polyamide-block chain limiters or combined with a diamine as one of the constituent monomers of the polyamide block, and the containing polyether blocks consisting essentially of alkylene oxide units. The invention also relates to polyetheresteramides (B) containing polyamide blocks of the polyamide oligomer type of low molecular mass or of the copolyamide type which comprise dicarboxylic acid sulphonates and containing polyether blocks which are adducts of alkylene oxide with an aromatic diol. The invention also relates to antistatic or breathable polymer compositions comprising a thermoplastic polymer (A) and at least one of the above polyetheresteramides (B).

1. Polyetheresteramides (B) containing polyamide blocks comprising condensing dicarboxylic acid sulphonates either as chain limiters for the polyamide block or with a diamine as one of the constituent monomers of the polyamide block wherein a polyamide sequence comprises oligomers made by condensing one or more α,ω-aminocarboxylic acids and/or of one or more lactams containing from 6 to 12 carbon atoms in the presence of a dicarboxylic acid sulphonate and optionally of a dicarboxylic acid containing from 4 to 12 carbon atoms, and the oligomers are of molecular mass  Mn  between 400 and 900, and containing polyether blocks consisting essentially of alkylene oxide units. 
     
     
       2. Polyetheresteramides (B) according to  claim 1 , in which the polyamide sequences result from the condensation of at least one α,ω-aminocarboxylic acid (or a lactam), at least one diamine and at least one dicarboxylic acid, and such that the chain limiter can be an excess of the dicarboxylic acid or another dicarboxylic acid, all or some of the chain limiter being replaced with a dicarboxylic acid sulphonate. 
     
     
       3. Polyetheresteramides (B) according to  claim 2 , in which the amount of dicarboxylic acid sulphonate is greater than the amount required as chain limiter and replaces all or some of the dicarboxylic acids used in combination with the diamine to constitute the polyamide block. 
     
     
       4. Polyetheresteramides (B) containing (i) polyamide blocks of the polyamide oligomer type of molecular masses  Mn  between 400 and 900 or of the copolyamide type, these polyamide blocks comprising condensing dicarboxylic acid sulphonates and containing (ii) polyether blocks which are adducts of alkylene oxide with an aromatic diol. 
     
     
       5. Antistatic or breathable polymer compositions comprising a thermoplastic polymer (A) and at least one polyetheresteramide (B) according claim  1    13 . 
     
     
       6. Compositions according to  claim 5 , in which the thermoplastic polymer (A) is chosen from polyolefins, polyamides, fluorinated polymers, saturated polyesters, polycarbonate, styrene resins, PMMA, thermoplastic polyurethanes (TPU), PVC, copolymers of ethylene and of vinyl acetate (EVA), copolymers of ethylene and of an alkyl(meth)acrylate, ABS, SAN, polyacetal and polyketones. 
     
     
       7. Anistatic or breathable polymer compositions comprising a thermoplastic polymer (A) and at least one polyetheresteramide (B) according to  claim 2 . 
     
     
       8. Antistatic or breathable polymer compositions comprising a thermoplastic polymer (A) and at least one polyetheresteramide (B) according to  claim 3 . 
     
     
       9. Antistatic or breathable polymer compositions comprising a thermoplastic polymer (A) and at least one polyetheresteramide (B) according to  claim 4 . 
     
     
       10. Compositions according to  claim 7 , in which the thermoplastic polymer (A) is chosen from polyolefins, polyamides, fluorinated polymers, saturated polyesters, polycarbonate, styrene resins, PMMA, thermoplastic polyurethanes (TPU), PVC, copolymers of ethylene and of vinyl acetate (EVA), copolymers of ethylene and of an alkyl(meth)acrylate, ABS, SAN, polyacetal and polyketones. 
     
     
       11. Compositions according to  claim 8 , in which the thermoplastic polymer (A) is chosen from polyolefins, polyamides, fluorinated polymers, saturated polyesters, polycarbonate, styrene resins, PMMA, thermoplastic polyurethanes (TPU), PVC, copolymers of ethylene and of vinyl acetate (EVA), copolymers of ethylene and of an alkyl(meth)acrylate, ABS, SAN, polyacetal and polyketones. 
     
     
       12. Compositions according to  claim 9 , in which the thermoplastic polymer (A) is chosen from polyolefins, polyamides, fluorinated polymers, saturated polyesters, polycarbonate, styrene resins, PMMA, thermoplastic polyurethanes (TPU), PVC, copolymers of ethylene and of vinyl acetate (EVA), copolymers of ethylene and of an alkyl(meth)acrylate, ABS, SAN, polyacetal and polyketones. 
     
     
       13. Polyetheresteramides ( B )  containing  ( i )  polyamide blocks of the polyamide oligomer type, these polyamide blocks comprising ammonium or alkali metal salts of dicarboxylic acid sulphonates condensed with at least one diamine and at least one lactam or an α,ω - amino - carboxylic acid, and containing  ( ii )  polyether blocks which are adducts of alkylene oxide with an aromatic diol.   
     
     
       14. Polyetheresteramides ( B )  containing  ( i )  polyamide blocks of the polyamide oligomer type having a molecular mass  Mn  between  400  and  900 , these polyamide blocks comprising ammonium or alkali metal salts of dicarboxylic acid sulphonates condensed with at least one diamine and at least one lactam or an α,ω - aminocarboxylic acid, and containing  ( ii )  polyether blocks which are adducts of alkylene oxide with an aromatic diol.