Substrate treated with a binder comprising positive ions

Abstract

An article for sanitizing a surface with a sanitizing solution while maintaining the concentration level of a sanitizer in the sanitizing solution at an effective concentration level. A substrate that absorbs and holds the sanitizing solution is treated with a sanitizer release polymer composition. The substrate may be a woven, nonwoven, or knit fabric, a foam or sponge, or the like. The sanitizer release polymer composition may include a cationic or nonionic surfactant or binder that is operable to maintain the concentration level of the sanitizer at the effective level during prolonged periods of use.

1. An article for sanitizing a surface utilizing a sanitizing solution that includes a sanitizer comprising positively charged ions at an effective concentration level, said article comprising:
 a substrate that absorbs and holds the sanitizing solution, said substrate having a structure that enables a user to wipe the surface with the substrate, thereby applying the sanitizing solution to the surface; and  
 an adhesive binder that binds together the structure of the substrate, said binder including positively or neutrally charged ions that provide the substrate with a predominantly positive or neutral charge that prevents the substrate from neutralizing the positively charged ions in the sanitizer when the sanitizer is subsequently applied to the substrate, thereby maintaining the concentration level of the sanitizer at the effective level.  An article for sanitizing a surface utilizing a sanitizing solution that includes a sanitizer comprising positively charged ions at an effective concentration level, said article comprising:  
   a plurality of substrate components; and    
   a cationic adhesive binder composition that binds together the substrate components into a substrate that absorbs and holds the sanitizing solution, said cationic binder providing the substrate with a predominantly positive charge that prevents the substrate from neutralizing the positively charged ions in the sanitizer when the sanitizer is subsequently applied to the substrate, thereby maintaining the concentration level of the sanitizer at the effective level.   
 
     
     
       2. The article of  claim 1  wherein the article is further treated with a cationic surfactant applied to the surface of the substrate.  The article of  claim 1  wherein the article is further treated with a cationic surfactant applied to the surface of the substrate. 
     
     
       3. The article of  claim 1  wherein the binder includes the positively or neutrally charged ions in an amount of about  0 . 1  to about  99  weight percent, based on a total weight of the binder.  The article of  claim 2  wherein the cationic surfactant includes positively charged ions in an amount of about  0 . 1  to about  99  weight percent, based on a total weight of the surfactant. 
     
     
       4. The article of  claim 3  wherein the binder includes the positively or neutrally charged ions in an amount of about  0 . 5  to about  50  weight percent, based on a total weight of the binder.  The article of  claim 3  wherein the cationic surfactant includes positively charged ions in an amount of about  0 . 5  to about  50  weight percent, based on a total weight of the surfactant. 
     
     
       5. The article of  claim 4  wherein the binder includes the positively or neutrally charged ions in an amount of about  1  to about  10  weight percent, based on a total weight of the binder.  The article of  claim 4  wherein the cationic surfactant includes positively charged ions in an amount of about  1  to about  10  weight percent, based on a total weight of the surfactant. 
     
     
       6. The article of  claim 2  wherein the cationic surfactant is selected from the group consisting of:
 dieicosyldimethyl ammonium chloride;  
 didocosyldimethyl ammonium chloride;  
 dioctadecyldimethyl ammonium chloride;  
 dioctadecyldimethyl ammonium methosulphate;  
 ditetradecyldimethyl ammonium chloride and naturally occurring mixtures of fatty groups;  
 di(hydrogenated tallow)dimethyl ammonium metho-sulphate;  
 ditallow dimethyl ammonium chloride; and  
 dioleyldimethyl ammonium chloride.  The article of  claim 2  wherein the cationic surfactant is selected from the group consisting of:  
   dieicosyldimethyl ammonium chloride;    
   didocosyldimethyl ammonium chloride;    
   dioctadecyldimethyl ammonium chloride;    
   dioctadecyldimethyl ammonium methosulphate;    
   ditetradecyldimethyl ammonium chloride and naturally occurring mixtures of fatty groups;    
   di(hydrogenated tallow)dimethyl ammonium metho-sulphate;    
   ditallow dimethyl ammonium chloride; and    
   dioleyldimethyl ammonium chloride.   
 
     
     
       7. The article of  claim 2  wherein the article is also treated with a co-surfactant selected from the group consisting of:
 a nonionic surfactant;  
 an anionic surfactant;  
 an amphoteric surfactant;  
 a zwitterionic surfactant; and  
 a semi-polar surfactant.  The article of  claim 2  wherein the article is also treated with a co-surfactant selected from the group consisting of:  
   a nonionic surfactant;    
   an anionic surfactant;    
   an amphoteric surfactant;    
   a zwitterionic surfactant; and    
   a semi-polar surfactant.   
 
     
     
       8. The article of  claim 7  wherein the amphoteric surfactant is selected from the group consisting of:
 derivatives of secondary and tertiary amines;  
 derivatives of quaternary ammonium;  
 quaternary phosphonium; and  
 tertiary sulfonium compounds.  The article of  claim 7  wherein the amphoteric surfactant is selected from the group consisting of:  
   derivatives of secondary and tertiary amines;    
   derivatives of quaternary ammonium;    
   quaternary phosphonium; and    
   tertiary sulfonium compounds.   
 
     
     
       9. The article of  claim 2  wherein the cationic surfactant includes at least one additive agent that provides for improved bonding of the cationic surfactant to the substrate.  The article of  claim 2  wherein the cationic surfactant includes at least one additive agent that provides for improved bonding of the cationic surfactant to the substrate. 
     
     
       10. The article of  claim 1  wherein the binder also includes at least one filler.  The article of  claim 2  wherein the cationic surfactant also includes at least one filler. 
     
     
       11. The article of  claim 2  wherein the article is also treated with at least one nonionic co-surfactant selected from the group consisting of:
 C 6  to C 12  alkylphenol ethoxylates;  
 C 8  to C 20  alkanol alkoxylates;  
 block copolymers of ethylene oxide and propylene oxide;  
 C 4  to C 18  alkyl glucosides; and  
 alkoxylated products obtainable from C 4  to C 18  alkyl glucosides by alkoxylation.  The article of  claim 2  wherein the article is also treated with at least one nonionic co-surfactant selected from the group consisting of:  
   C   6    to C   12    alkylphenol ethoxylates;    
   C   8    to C   20    alkanol alkoxylates;    
   block copolymers of ethylene oxide and propylene oxide;    
   C   4    to C   18    alkyl glucosides; and    
   alkoxylated products obtainable from C   4    to C   18    alkyl glucosides by alkoxylation.   
 
     
     
       12. The article of  claim 1  wherein the article is further treated with a nonionic surfactant applied to the surface of the substrate.  The article of  claim 1  wherein the article is further treated with a nonionic surfactant applied to the surface of the substrate. 
     
     
       13. The article of  claim 12  wherein the nonionic surfactant is selected from the group consisting of:
 C 8  to C 12  alkylphenol ethoxylates;  
 C 8  to C 20  alkanol alkoxylates;  
 block copolymers of ethylene oxide and propylene oxide;  
 C 4  to C 18  alkyl glucosides; and  
 alkoxylated products obtainable from C 4  to C 18  alkyl glucosides by alkoxylation.  The article of  claim 12  wherein the nonionic surfactant is selected from the group consisting of:  
   C   8    to C   12    alkylphenol ethoxylates;    
   C   8    to C   20    alkanol alkoxylates;    
   block copolymers of ethylene oxide and propylene oxide;    
   C   4    to C   18    alkyl glucosides; and    
   alkoxylated products obtainable from C   4    to C   18    alkyl glucosides by alkoxylation.   
 
     
     
       14. The article of  claim 1  wherein the substrate is a nonwoven fabric comprising a multiplicity of strands of material that are bound together by the adhesive binder.  The article of  claim 1  wherein the substrate is a nonwoven fabric comprising a multiplicity of strands of material that are bound together by the adhesive cationic binder. 
     
     
       15. The article of  claim 1  wherein the substrate is selected from the group consisting of woven fabrics, nonwoven fabrics, knit fabrics, and foams.  The article of  claim 1  wherein the substrate is selected from the group consisting of woven fabrics, nonwoven fabrics, knit fabrics, and foams. 
     
     
       16. The article of  claim 15  wherein the article is a sanitizing towel utilized to sanitize one of a plurality of areas in a restaurant.  The article of  claim 15  wherein the article is a sanitizing towel utilized to sanitize one of a plurality of areas in a restaurant. 
     
     
       17. A method of manufacturing a substrate, said substrate being utilized with a sanitizing solution that includes a sanitizer comprising positively charged ions, said method comprising the steps of:
 selecting an adhesive binder comprising predominantly positively or neutrally charged ions; and  
 applying the binder to a plurality of loose strands of material to bind the strands together into a web-like structure forming the substrate;  
 whereby, when the substrate is utilized with the sanitizing solution, the positively or neutrally charged ions in the binder prevent the substrate from neutralizing the positively charged ions in the sanitizer.  A combination for sanitizing a surface, said combination comprising:  
   a liquid sanitizing solution that includes a sanitizer comprising positively charged ions at an effective concentration level; and    
   a substrate that absorbs and holds the sanitizing solution, said substrate comprising:    
   a plurality of substrate components; and    
   a cationic adhesive binder composition that binds together the substrate components to form the substrate, said cationic binder composition providing the substrate with a predominantly positive charge that prevents the substrate from neutralizing the positively charged ions in the sanitizer when the sanitizer is subsequently applied to the substrate, thereby maintaining the concentration level of the positively charged ions in the sanitizer at the effective level.   
 
     
     
       18. The method of  claim 17  wherein the step of selecting a substrate includes selecting a substrate from the group consisting of woven fabrics, nonwoven fabrics, knit fabrics, and foams.  The combination of  claim 17  wherein the sanitizer in the sanitizing solution is a quaternary ammonium compound (QAC)-based sanitizer. 
     
     
       19. The method of  claim 17  further comprising applying a cationic surfactant to the surface of the substrate, said cationic surfactant being selected from the group consisting of:
 dieicosyldimethyl ammonium chloride;  
 didocosyldimethyl ammonium chloride;  
 dioctadecyldimethyl ammonium chloride;  
 dioctadecyldimethyl ammonium methosulphate;  
 ditetradecyldimethyl ammonium chloride and naturally occurring mixtures of fatty groups;  
 di(hydrogenated tallow)dimethyl ammonium metho-sulphate;  
 ditallow dimethyl ammonium chloride; and  
 dioleyldimethyl ammonium chloride.  The combination of  claim 17 , wherein the substrate is further treated with a cationic surfactant applied to the surface of the substrate. 
 
     
     
       20. The method of  claim 19  wherein the step of applying the cationic surfactant to the surface of the substrate includes the steps of:
 mixing a composition in which the cationic surfactant is present in an amount of about  0 . 1  to about  99  weight percent, based on a total weight of the composition; and  
 applying the composition to the substrate.  A method of manufacturing an article for sanitizing surfaces, said article being utilized with a sanitizing solution that includes a sanitizer comprising positively charged ions, said method comprising the steps of:  
   selecting a plurality of substrate components;    
   selecting a cationic adhesive binder composition; and    
   utilizing the cationic adhesive binder composition to bind together the substrate components into a substrate for absorbing and holding the sanitizing solution, said cationic binder composition providing the substrate with a predominantly positive charge;    
   whereby, when the article is subsequently utilized with the sanitizing solution, the positively charged substrate prevents the article from neutralizing the positively charged ions in the sanitizer.   
 
     
     
       21. The method of  claim 20  wherein the step of mixing a composition includes mixing a composition in which the cationic surfactant is present in an amount of about  1  to about  10  weight percent, based on a total weight of the composition. 
     
     
       22. The method of  claim 20  wherein the step of applying the composition to the substrate includes the steps of:
 diluting the composition with an organic solvent; and    dip coating the substrate in the diluted composition.    
     
     
       23. The method of  claim 20  wherein the step of applying the composition to the substrate includes the steps of:
 diluting the composition with an organic solvent; and    spray coating the substrate with the diluted composition.    
     
     
       24. The method of  claim 20  wherein the step of applying the composition to the substrate includes the steps of:
 diluting the composition with an organic solvent; and    foam coating the substrate with the diluted composition.    
     
     
       25. The method of  claim 20  wherein the step of applying the composition to the substrate includes the steps of:
 diluting the composition with water; and    dip coating the substrate in the diluted composition.    
     
     
       26. The method of  claim 20  wherein the step of applying the composition to the substrate includes the steps of:
 diluting the composition with water; and    spray coating the substrate with the diluted composition.    
     
     
       27. The method of  claim 20  wherein the step of applying the composition to the substrate includes the step of:
 diluting the composition with water; and    foam coating the substrate with the diluted composition.    
     
     
       28. The method of  claim 20  further comprising the steps of:
 selecting a nonionic co-surfactant for use with the cationic surfactant in the composition; and    mixing the nonionic co-surfactant with the cationic surfactant to form the composition.    
     
     
       29. The method of  claim 20  further comprising the steps of:
 selecting an additive agent for use with the cationic surfactant in the composition, said additive agent being operable to improve bonding of the cationic surfactant to the substrate; and    mixing the additive agent with the cationic surfactant to form the composition.    
     
     
       30. A combination for sanitizing a surface, said combination comprising:
 a liquid sanitizing solution that includes a sanitizer comprising positively charged ions at an effective concentration level;    a substrate that absorbs and holds the sanitizing solution, said substrate having a structure that enables a user to wipe the surface with the substrate, thereby applying the sanitizing solution to the surface; and    an adhesive binder that binds together the structure of the substrate, said binder including positively or neutrally charged ions that provide the substrate with a predominantly positive or neutral charge that prevents the substrate from neutralizing the positively charged ions in the sanitizer when the sanitizer is subsequently applied to the substrate, thereby maintaining the concentration level of the sanitizer at the effective level.    
     
     
       31. The combination of  claim 30  wherein the sanitizer in the sanitizing solution is a quaternary ammonium compound (QAC)-based sanitizer. 
     
     
       32. A combination for sanitizing a surface, said combination comprising:
 a liquid sanitizing solution that includes a sanitizer comprising positively charged ions at an effective concentration level; and    a cationic or nonionic substrate that absorbs and holds the sanitizing solution, said substrate having a structure that enables a user to wipe the surface with the substrate, thereby applying the sanitizing solution to the surface, said substrate having a cationic surfactant bonded to the surface of the substrate during manufacturing to provide the substrate with a predominantly positive or neutral charge, thereby preventing the substrate from neutralizing the positively charged ions in the sanitizer when the sanitizer is subsequently applied to the substrate.    
     
     
       33. A method of manufacturing an article for sanitizing surfaces, said article being utilized with a sanitizing solution that includes a sanitizer comprising positively charged ions, said method comprising the steps of:
 selecting a substrate for the article having a structure suitable for absorbing and holding the sanitizing solution during use;    selecting a cationic surfactant comprising predominantly positively charged ions; and    bonding the cationic surfactant to the surface of the substrate to provide the substrate with a predominantly positive or neutral charge;    whereby, when the article is subsequently utilized with the sanitizing solution, the positively or neutrally charged substrate prevents the article from neutralizing the positively charged ions in the sanitizer.