Litho strip and method for its manufacture

Abstract

A litho strip for use as an offset printing plate is described which has a composition of 0.05-0.25% Si, 0.30-0.40% Fe, 0.10-0.30% Mg, max. 0.05% Mn, and max. 0.04% Cu. The strip is produced from a continuous cast ingot of the above composition which is hot rolled to a thickness of up to 2-7 mm. The residual resistance ratio of the hot rolled strip is RR=10-20. The cold rolling is carried out with or without intermediate annealing, wherein the degree of rolling reduction after intermediate annealing is >60%. The further processing up to the EC roughening takes place with the microstructure adjusted in the rolling process at <100° C. The litho strip is characterized by a high thermal stability, a good roughening behavior in the EC processes, and a high reverse bending fatigue strength perpendicular to the rolling direction.

1. A litho strip for electrochemical roughening comprising a rolled aluminum alloy, said aluminum alloy comprising in addition to impurities resulting from manufacture:
 aluminium;    0.30-0.40% iron;    0.10-0.30% magnesium;    0.05-0.25% silicon;    not more than 0.05% manganese; and    not more than 0.04% copper; wherein: 
 said litho strip has a rolling direction;  
 said litho strip has a reversed bending fatigue strength perpendicular to said rolling direction, said reversed bending fatigue strength having a value greater than 1,250 cycles in a reversed bending test; and  
 said litho strip has a surface, globulitic recrystallized grains, and a residual resistance ratio RR, said grains being disposed in said surface and having an average diameter of less than 50 microns, and said residual resistance ratio having a value in the range 10-20; and  
 said litho strip, after test annealing at 240° C. for 10 minutes, has a tensile strength, Rm, greater than 145 N/mm 2 .  
   
     
     
       2. The litho strip according to  claim 1 , wherein:
 if said alloy comprises any impurities, said any impurities individually amount to less than 0.03% of said alloy; and    all of said impurities, in sum, amount to less than 0.10% of said alloy.    
     
     
       3. The litho strip of  claim 2  wherein:
 said litho strip is produced from a hot rolled strip that is continuously recrystallized to more than 75%.    
     
     
       4. The litho strip of  claim 1  wherein:
 said litho strip is produced from a hot rolled strip that is continuously recrystallized to more than 75%.    
     
     
       5. A method for manufacturing a printing plate support from a litho strip defined by  claim 1   comprising:
 electrochemically roughening said litho strip by placing said litho strip in an acid bath, said acid selected from the group consisting of HCl and HNO 3 ;  
 providing an alternating current in said acid bath; and  
 subsequently anodizing said litho strip;  
   the litho strip comprising a rolled aluminum alloy, said aluminum alloy comprising in addition to impurities resulting from manufacture;    
   aluminum;    
     0 . 30 - 0 . 40   %  iron;    
     0 . 10 - 0 . 30   %  magnesium;    
     0 . 05 - 0 . 25   %  silicon;    
   not more than  0 . 05   %  manganese; and    
   not more than  0 . 04   %  copper; wherein:    
   said litho strip has a rolling direction;    
   said litho strip has a reversed bending fatigue strength perpendicular to said rolling direction, said reversed bending fatigue strength having a value greater than  1 , 250  cycles in a reversed bending test; and    
   said litho strip is produced from a hot rolled strip, the hot rolled strip having a surface, globulitic recrystallized grains, and a residual resistance ratio RR, said grains being disposed in said surface and having an average diameter of less than  50  microns, and said residual resistance ratio having a value in the range  10 - 20 ; and    
   said litho strip, after test annealing at  240 ° C. for  10  minutes, has a tensile strength, Rm, greater than  145  N/mm   2 .  
 
     
     
       6. A method for manufacturing a printing plate for rotary offset printing from a printing plate support comprising:
 manufacturing said printing plate support according to the method of  claim 5 ; and  
 providing said printing plate with a photo-sensitive hydrophobic layer.  
 
     
     
       7. A litho strip for electrochemical roughening comprising a rolled aluminum alloy, said aluminum alloy comprising, in addition to any impurities from manufacture:
 aluminum;  
 0.30-0.40% iron;  
 0.15-0.30% magnesium;  
 0.05-0.15% silicon;  
 not more than 0.01% manganese;  
 not more than 0.005% copper;  
 not more than 0.01% chromium;  
 not more than 0.02% zinc;  
 not more than 0.01% titanium;  
 not more than 50 ppm boron; and,  
 if said alloy comprises any impurities resulting from manufacture, said impurities, in sum, amount to less than 0.05% of said alloy, wherein: 
 said litho strip has a rolling direction;  
 said litho strip has a reversed bending fatigue strength perpendicular to said rolling direction, said reversed bending fatigue strength having a value greater than 1,250 cycles in a reversed bending test; and  
 said litho strip, after test annealing at 240° C. for 10 minutes, has a tensile strength, Rm, greater than 145 N/mm 2 .  
 
 
     
     
       8. The litho strip of  claim 7  wherein:
 said litho strip is produced from a hot rolled strip that is , the hot rolled strip being continuously recrystallized to more than 75%; and  
 said litho strip hashaving a surface layer comprising globulitic grains, said globulitic grains having an average grain diameter of less than 50 microns.  
 
     
     
       9. A method for producing a litho strip comprising:
 producing a rolling ingot of a thickness greater than 500 millimeters from an aluminum alloy, said aluminum alloy comprising in addition to impurities resulting from manufacture:  
 aluminum;  
 0.30-0.40% iron;  
 0.10-0.30% magnesium;  
 0.05-0.25% silicon;  
 not more than 0.05% manganese; and  
 not more than 0.04% copper, wherein: 
 said producing comprises: 
 continuous casting; and  
 homogenizing at a temperature in the range 480-620 degrees centigrade for no less than two hours;  
 
 
 hot rolling said rolling ingot into a hot rolled strip wherein: 
 said hot rolling comprises a last hot rolling pass, said last hot rolling pass reducing the thickness of said hot rolled strip by 15 to 75%;  
 said hot rolling has a hot rolling end temperature of greater than 250 degrees centigrade; and  
 said hot rolling causes said hot rolled strip to have a thickness of 2-7 millimeters;  
 
 cooling said hot rolled strip to room temperature to produce a cooled hot rolled strip, said cooled hot rolled strip having a surface, globulitic recrystallized grains, and a residual resistance ratio RR, said grains being disposed in said surface and having an average diameter of less than 50 microns, and said residual resistance ratio having a value in the range 10-20;  
 cold rolling said cooled hot rolled strip to form a cold rolled strip; and  
 further processing said cold rolled strip prior to electrochemical roughening, said cold rolled strip having a microstructure formed during said hot and cold rolling and a temperature less than 100 degrees centigrade, while maintaining said microstructure and said temperature, wherein said further processing is selected from the group consisting of: 
 a. stretching;  
 b. degreasing;  
 c. cutting;  
 d. pickling; and  
 a combination of any of (a)-(d).  
 
 
     
     
       10. The method of  claim 9  further comprising allowing intermediate annealing, wherein, after intermediate annealing, said cold rolling comprises achieving a rolling reduction of greater than 60%. 
     
     
       11. The method according to  claim 10 , wherein said hot rolled strip has a metal temperature and said intermediate annealing comprises:
 annealing at a slow heating rate, said slow heating rate in the range 10 to 75 centigrade degrees per hour;  
 maintaining said metal temperature in the range 300 to 500 degrees centigrade; and  
 allowing said intermediate annealing to occur for an annealing time, said annealing time greater than 1 hour.  
 
     
     
       12. The method according to  claim 10 , wherein said hot rolled strip has a metal temperature and said intermediate annealing comprises:
 annealing at a fast heating rate, said fast heating rate in the range 5 to 40 centigrade degrees per second;  
 maintaining said metal temperature in the range 400 to 500 degrees centigrade; and  
 allowing said intermediate annealing to occur for an annealing time, said annealing time in the range 2 seconds to 2 minutes.