Volatile organic compound sensor system

Abstract

Generally, this invention relates to the development of field monitoring methodology for new substances and sensing chemical warfare agents (CWAs) and terrorist substances. It also relates to a portable test kit which may be utilized to measure concentrations of halogenated volatile organic compounds (VOCs) in the field. Specifically it relates to systems for reliably field sensing the potential presence of such items while also distinguishing them from other elements potentially present. It also relates to overall systems and processes for sensing, reacting, and responding to an indicated presence of such substance, including modifications of existing halogenated sensors and arrayed sensing systems and methods.

1. A method of sensing an environmentally situated, non-refrigerant halogenated volatile compound comprising the steps of:
 obtaining a refrigerant leak detector from which anutilizing corona discharge and/or heated diode sensor technology to contact a sample suspected of containing said environmentally situated, non- refrigerant halogenated volatile compound and obtain an  electrical output can be obtained ; and  
 establishingutilizing a numerical output provision element responsive to said electrical output forto quantitatively displayingdisplay a value of a concentration of said environmentally situated, non-refrigerant halogenated volatile compound,  
 wherein said sample suspected of containing said environmentally situated, non-refrigerant halogenated volatile compound is in an environmental area of interest.  
 
     
     
       2. A method of sensing an environmentally situated, non-refrigerant halogenated volatile compound as described in  claim 1 , wherein said step of establishing a numerical output provision element responsive to said electrical output for quantitatively displaying a value of a concentration of an  environmentally situated, non-refrigerant halogenated volatile compound comprises the step of establishing a numerical output provision element responsive to said electrical output and that quantitatively displays a value of a concentration of  a halogenated soil contaminant. 
     
     
       3. A method of sensing an environmentally situated, non-refrigerant halogenated volatile compound as describe in  claim 1 , wherein said step of establishing a numerical output provision element responsive to said electrical output for quantitatively displaying a value of a concentration of an  environmentally situated, non-refrigerant halogenated volatile compound comprises the step of establishing a numerical output provision element that quantitatively displays a value of a concentration of  an environmentally situated, non-refrigerant halogenated volatile compound in the presence of non-halogenated volatile compounds. 
     
     
       4. A method of sensing environmentally situated, non-refrigerant halogenated volatile compound as described in  claim 1 , wherein said step of establishing a numerical output provision element responsive to said electrical output and that quantitatively displays a value of a concentration of an  environmentally situated, non-refrigerant halogenated volatile compound comprises the step of establishing a numeric output provision element responsive to said electrical output and that quantitatively displays a value of a concentration of  a DNAPL that contaminate  contaminates oil or water. 
     
     
       5. A method of sensing an environmentally situated, non-refrigerant halogenated volatile compound and described in  claim 1 , wherein said step of establishing a numerical output provision element responsive to said electrical output and that quantitatively displays a value of a concentration of an  environmentally situated, non-refrigerant halogenated volatile compound comprises the step of establishing a numeric output provision element responsive to said electrical output and that quantitatively displays a value of a concentration of  a halogenated volatile compound chemical warfare agent. 
     
     
       6. A method of sensing an environmently situated, non-refrigerant halogenated volatile compound as described  claim 1 , wherein said step of establishing a numerical output provision element responsive to said electrical output for quantitatively displaying a value a concentration of an environmentally situated, non-refrigerant halogenated volatile compound comprises the step of establishing a numeric output provision element responsive to said electrical output and that quantitatively displays a value of a concentration of said environmentally situated, non-refrigerant halogenated volatile compound. 
     
     
       7. A method of environmental monitoring for environmentally situated, halogenated volatile compounds comprising the steps of:
 obtaining a refrigerant leak detector adapted to provide a value of a concentration of an environmentally situated, halogenated volatile compound; 
 establishing said refrigerant leak detectorpositioning corona discharge and/or heated diode sensor technology in an environmental area of interest to contact a sample suspected of containing said environmentally situated, non- refrigerant halogenated volatile compound; and    
 sensing said environmentally situated, halogenated volatile compound in said environmental area of interest by operating said refrigerant leak detector  corona discharge and/or heated diode sensor technology to provide a value of a concentration of said environmentally situated, halogenated volatile compound; and  
 quantitatively displaying said value of a  said concentration of said environmentally situated, halogenated volatile compound.  
 
     
     
       8. A method of environmental monitoring for environmentally situated, halogenated volatile compounds as described in  claim 7 , wherein said step of sensing an  environmentally situated, halogenated volatile compound comprises the step of sensing  halogenated contaminants. 
     
     
       9. A method of environmental monitoring for environmentally situated, halogenated volatile compounds as described in  claim 7 , wherein said step of obtaining a refrigerant leak detector  corona discharge and/or heated diode sensor technology comprises the step of obtaining  a commercially available refrigerant leak detector. 
     
     
       10. A method of environmental monitoring for environmentally situated, halogenated volatile compounds as described in  claim 7  or  9  wherein said step of obtaining a refrigerant leak detector  corona discharge and/or heated diode sensor technology comprises the step of obtaining  a heated diode refrigerant leak detector. 
     
     
       11. A method of environmental monitoring for environmentally situated, halogenated volatile compounds as described in  claim 7  or  9  wherein said step of obtaining a refrigerant leak detector  corona discharge and/or heated diode sensor technology comprises the step of obtaining  a corona discharge refrigerant leak detector. 
     
     
       12. A method of environmental monitoring for environmentally situated, halogenated volatile compounds as described in  claim 7 , wherein said step of obtaining a refrigerant leak detector  operating said corona discharge and/or heated diode sensor technology to provide a value of a concentration of said environmentally situated, halogenated volatile compound comprises the step of obtaining a refrigerant leak detector from which  an electrical output can be obtained  from said corona discharge and/or heated diode sensor technology and further comprising the step of establishing  utilizing a numerical output provision element responsive to said electrical output to provide said value of the concentration of said environmentally situated, halogenated volatile compound. 
     
     
       13. A method of environmental monitoring for environmentally situated, halogenated volatile compounds as described in  claim 12 , wherein said step of establishing a  numerical output provision element responsive to said electrical output comprises the step of connecting  a voltmeter connected to said corona discharge and/or heated diode sensor technology in order to provide said numerical output. 
     
     
       14. A method of environmental monitoring for environmentally situated, halogenated volatile compounds as
 described in  claim 12 , wherein said step of establishing a  numerical output provision element responsive to said electrical output comprises the step of connecting  a frequency meter connected to said corona discharge and/or heated diode sensor technology in order to provide said numerical output.  
 
     
     
       15. A method of environmental monitoring for environmentally situated, halogenated volatile compounds as described in  claim 7 , wherein said step of establishing said refrigerant leak detector in an  environmental area of interest comprises the step of establishing said refrigerant leak detector in  soil or in  a headspace above said soil. 
     
     
       16. A method of environmental monitoring for environmentally situated, halogenated volatile compounds as described in  claim 7 , wherein said step of sensing a  halogenated volatile compound in said environmental area of interest by operating said refrigerant leak detector  comprises the step of sensing  a halogenated volatile chemical war agent selected from the group of a halogenated volatile chemical war agents  consisting of: sarin, soman, cyanogen chloride, chlorine, phosgene, sulfur mustard, nitrogen mustard and lewisite. 
     
     
       17. A method of environmental monitoring for environmentally situated, halogenated volatile compounds as described in  claim 7 , further comprising the step of establishing  utilizing an alert system responsive to said step of sensing a halogenated volatile compound in said environmental area of interest by operating said refrigerant leak detector  corona discharge and/or heated diode sensor technology to provide a value of a concentration of said environmentally situated, halogenated volatile compound. 
     
     
       18. A method of environmental monitoring for environmentally situated, halogenated volatile compounds as described in  claim 7 , wherein said step of sensing comprises in-field sensing of a halogenated volatile compound in soil, water or air. 
     
     
       19. A method of environmental monitoring for environmentally situated, halogenated volatile compounds as described in  claim 7 , wherein said step of establishing said refrigerant leak detector in an  environmental area of interest comprises the step of establishing said refrigerant leak detector in  a headspace above soil. 
     
     
       20. A method environmental  of environmental monitoring for environmentally situated, halogenated volatile compounds as described in  claim 7 , wherein said step of establishing said refrigerant leak detector in an  environmental area of interest comprises step of establishing said refrigerant leak detector in  a headspace above water. 
     
     
       21. A method of environmental monitoring for environmentally situated, halogenated volatile compounds as described in  claim 7 , wherein said step of establishing said refrigerant leak detector in an  environmental area of interest comprises the , step of establishing said refrigerant leak detector in  air. 
     
     
       22. A method of environmental monitoring for environmentally situated, halogenated volatile compounds as described in  claim 7 , wherein said step of sensing said  environmentally situated, halogenated volatile compound in said environmental at of interest by operating said refrigerant leak detector  comprises the step sensing  an environmentally situated, non-refrigerant halogenated volatile compound. 
     
     
       23. A method of sensing an environmentally situated, non- refrigerant halogenated volatile compound as described in    claim 1   , wherein said corona discharge and/or heated diode sensor technology comprises a refrigerant leak detector.   
     
     
       24. A method of sensing an environmentally situated, non- refrigerant halogenated volatile compound as described in    claim 23   , wherein said refrigerant leak detector comprises a commercially available refrigerant leak detector.   
     
     
       25. A method of sensing an environmentally situated, non- refrigerant halogenated volatile compound as described in    claim 4   , further comprising the step of utilizing an alert system responsive to said step electrical output of said corona discharge and/or heated diode sensor technology.   
     
     
       26. A method of an sensing environmentally situated, non- refrigerant halogenated volatile compound as described in    claim 1   , wherein said numerical output provision element responsive to said electrical output for quantitatively displaying a value of a concentration of an environmentally situated, non - refrigerant halogenated volatile compound comprises a voltmeter or a frequency meter connected to said corona discharge and/or heated diode sensor technology.   
     
     
       27. A method of environmental monitoring for environmentally situated, halogenated volatile compounds as described in  claim 7 , wherein said corona discharge and/or heated diode sensor technology is commercially available. 
     
     
       28. A method of environmental monitoring for environmentally situated, halogenated volatile compounds as described in  claim 7 , wherein said corona discharge and/or heated diode sensor technology provides a numerical value of said concentration of an environmentally situated halogenated volatile compound. 
     
     
       29. A method of environmental monitoring for environmentally situated, halogenated volatile compounds as described in  claim 7 , wherein said environmentally situated halogenated volatile compound comprises an environmentally situated, halogenated volatile organic compound.