USRE44058EExpiredUtilityPatentIndex 48
Cleaning composition comprising a water-soluble or water-dispersible polymer
Est. expiryJul 15, 2019(expired)· nominal 20-yr term from priority
C11D 3/37C11D 3/3757C11D 3/3769
48
PatentIndex Score
1
Cited by
28
References
78
Claims
Abstract
This invention relates to a cleaning composition comprising at least one surfacatant or at least one cosmetic vehicle and a water-soluble or water-dispersible copolymer comprising, in the form of polymerized units: (a) at least one monomer compound of general formula I: (b) at least one hydrophilic monomer carrying a functional group with an acidic nature which is copolymerizable with (a) and which is capable of being ionized in the application medium; (c) optionally at least one hydrophilic monomer compound with ethylenic unsaturation with a neutral charge, carrying one or more hydrophilic groups, which is copolymerizable with (a) and (b).
Claims
exact text as granted — not AI-modified1. A process for the treatment of hard surfaces, comprising the step of treating said surfaces with an efficient cleaning or rinsing amount of a composition comprising at least one water-soluble or water dispersible copolymer comprising, in the form of polymerized units:
(a) at least one monomer compound of general formula I:
in which
R 1 is a hydrogen atom, a methyl or ethyl group;
R 2 , R 3 , R 4 , R 5 and R 6 , which are identical or different, are linear or branched C 1 -C 6 , alkyl, hydroxyalkyl or aminoalkyl groups;
m is an integer from 0 to 10;
n is an integer from 1 to 6;
Z represents a —C(O)O— or —C(O)NH— group or an oxygen atom;
A represents a (CH 2 ) p group, p being an integer from 1 to 6;
B represents a linear or branched C 2 -C 12 , polymethylene chain optionally interrupted by one or more heteroatoms or heterogroups, and optionally substituted by one or more hydroxyl or amino groups;
X, which are identical or different, represent counterions; and
(b) at least one hydrophilic monomer carrying a functional acidic group which is copolymerizable with (a) and which is capable of being ionized in the application medium.
2. The process according to claim 1 , wherein, in the general formula I:
Z represents C(O)O, C(O)NH or O; n is equal to 2 or 3; m ranges from 0 to 2; B represents
with q from 1 to 4; and
R 1 to R 6 , which are identical or different, represent a methyl or ethyl group.
3. The process according to claim 1 , in which the monomer (a) is represented by the following formula:
wherein p=2 to 4.
4. The process according to claim 1 , in which the monomer (a) is:
X − representing a chloride ion.
5. The process according to claim 1 , wherein said polymer further comprising:
(c) at least one monomer compound with ethylenic unsaturation with a neutral charge which is copolymerizable with (a) and (b).
6. The process according to claim 5 , wherein (c) is a hydrophilic monomer compound with ethylenic unsaturation with a neutral charge, carrying one or more hydrophilic groups, which is copolymerizable with (a) and (b).
7. The process according to claim 1 , wherein (b) is a C 3 -C 8 carboxylic, sulfonic, sulfuric, phosphonic or phosphoric acids with monoethylenic unsaturation.
8. The process according to claim 5 , wherein the monomer (b) is acrylic acid, methacrylic acid, α-ethacrylic acid, β,β-dimethylacrylic acid, methylenemalonic acid, vinylacetic acid, allylacetic acid, ethylidineacetic acid, propylidineacetic acid, crotonic acid, maleic acid, fumaric acid, itaconic acid, citraconic acid, mesaconic acid, N-(methacroyl)alanine, N-(acryloyl)hydroxyglycine, sulfopropyl acrylate, sulfoethyl acrylate, sulfoethyl methacrylate, styrenesulfonic acid, vinylsulfonic acid, vinylphosphonic acid, phosphoethyl acrylate, phophonoethyl acrylate, phosphopropyl acrylate, phophonopropyl acrylate, phosphoethyl methacrylate, phophonoethyl methacrylate, phosphopropyl methacrylate, or phophonopropyl methacrylate.
9. The process according to claim 5 , wherein the monomer (c) is acrylamide, vinyl alcohol, C 1 -C 4 alkyl ester of acrylic acid and of methacrylic acid, C 1 -C 4 hydroxyalkyl ester of acrylic acid and of methacrylic acid, polyalkoxylated ester of acrylic acid and of methacrylic acid, ester of acrylic acid, ester of methacrylic acid and of polyethylene glycol, polypropylene glycol C 1 -C 25 monoalkyl ether, vinyl acetate, vinylpyrrolidone or methyl vinyl ether.
10. The process according to claim 1 , wherein X is halogen, sulfonate, sulfate, hydrogensulfate, phosphate, phosphanate, citrate, formate or an acetate anion.
11. The process according to claim 5 , wherein the water-soluble or water-dispersible copolymer is obtained by copolymerization
of 3 to 80 mol %, of the monomer (a); of 10 to 95 mol %, of the monomer (b); of 0 to 50 mol %, of the monomer (c).
12. The process according to claim 1 , wherein the monomers (a) and the monomers (b) have a molar ratio by weight of the total of the monomers (a) to the total of the monomers (b) between 80/20 and 5/95.
13. The process according to claim 1 , wherein the copolymer has a molecular mass of at least 1000.
14. The process according to claim 1 , wherein the copolymer has the following formula:
wherein x having a mean value of 0 to 50%,
y having a mean value of 10 to 95%,
z having a mean value of 3 to 80%, and
with x+y+z=100%, x, y and z representing the mol % of units derived from acrylamide, acrylic acid (sodium salt) and from Diquat respectively;
wherein x having a mean value of 0 to 50%,
y having a mean value of 10 to 95%, and
z having a mean value of 3 to 80%,
wherein x having a mean value of 0 to 50%,
y having a mean value of 10 to 95%, and
z having a mean value of 3 to 80%,
wherein x having a mean value of 0 to 50%,
y having a mean value of 10 to 95%, and
z having a mean value of 3 to 80%,
wherein x having a mean value of 0 to 50%,
y having a mean value of 10 to 95%, and
z having a mean value of 3 to 80%,
wherein x having a mean value of 0 to 50%,
y having a mean value of 10 to 95%, and
z having a mean value of 3 to 80%, or
wherein x having a mean value of 0 to 50%,
y having a mean value of 10 to 95%, and
z having a mean value of 3 to 80%.
15. The process according to claim 1 , wherein the copolymer of formula I represents from 0.0005 to 10% by weight with respect to the total weight of said composition.
16. The process according to claim 1 , wherein said composition further comprises a surfactant, with a copolymer/surfactant ratio by weight of between 1/2 and 1/100.
17. A process for cleaning windows, comprising the step of treating said windows with a an efficient cleaning amount of a composition comprising:
from 0.001 to 10%, by weight of a water-soluble or water-dispersible copolymer comprising, in the form of polymerized units:
(a) at least one monomer compound of general formula I:
in which
R 1 is a hydrogen atom, a methyl or ethyl group;
R 2 , R 3 , R 4 , R 5 and R 6 , which are identical or different, are linear or branched C 1 -C 6 , alkyl, hydroxyalkyl or aminoalkyl groups;
m is an integer from 0 to 10;
n is an integer from 1 to 6;
Z represents a —C(O)O— or —C(O)NH— group or an oxygen atom;
A represents a (CH 2 ) p group, p being an integer from 1 to 6;
B represents a linear or branched C 2 -C 12 , polymethylene chain optionally interrupted by one or more heteroatoms or heterogroups, and optionally substituted by one or more hydroxyl or amino groups;
X, which are identical or different, represent counterions; and
(b) at least one hydrophilic monomer carrying a functional acidic group which is copolymerizable with (a) and which is capable of being ionized in the application medium;
from 0.005 to 20%, by weight of at least one nonionic and/or anionic surfactant;
the remainder being formed of water, or solvents.
18. The process according to claim 17 , wherein said composition further comprises an amine oxide as nonionic surfactant.
19. A process for washing dishes in an automatic dishwasher, comprising the step of treating said dishes with an efficient washing amount of a composition comprising:
from 0.001 to 10%, by weight of a water-soluble or water-dispersible copolymer comprising, in the form of polymerized units:
(a) at least one monomer compound of general formula I:
in which
R 1 is a hydrogen atom, a methyl or ethyl group;
R 2 , R 3 , R 4 , R 5 and R 6 , which are identical or different, are linear or branched C 1 -C 6 , alkyl, hydroxyalkyl or aminoalkyl groups;
m is an integer from 0 to 10;
n is an integer from 1 to 6;
Z represents a —C(O)O— or —C(O)NH— group or an oxygen atom;
A represents a (CH 2 ) p group, p being an integer from 1 to 6;
B represents a linear or branched C 2 -C 12 , polymethylene chain optionally interrupted by one or more heteroatoms or heterogroups, and optionally substituted by one or more hydroxyl or amino groups;
X, which are identical or different, represent counterions; and
(b) at least one hydrophilic monomer carrying a functional acidic group which is copolymerizable with (a) and which is capable of being ionized in the application medium;
from 0.2 to 10%, by weight with respect to the total weight of dry matter of a surfactant, and, optionally;
from 30 to 95% by weight with respect to the total weight of detergent composition, expressed as dry matter, of builders; and
from 3 to 25% by weight with respect to the total weight of the composition of an oxidizing system.
20. A process for rinsing dishes in an automatic dishwasher, comprising the step of treating said dishes with an efficient rinsing amount of a composition comprising:
from 0.02 to 10%, by weight of water-soluble or water-dispersible copolymer, with respect to the total weight of the composition, said copolymer comprising from 0.001 to 10%, by weight of a water-soluble or water-dispersible copolymer comprising, in the form of polymerized units:
(a) at least one monomer compound of general formula I:
in which
R 1 is a hydrogen atom, a methyl or ethyl group;
R 2 , R 3 , R 4 , R 5 and R 6 , which are identical or different, are linear or branched C 1 -C 6 , alkyl, hydroxyalkyl or aminoalkyl groups;
m is an integer from 0 to 10;
n is an integer from 1 to 6;
Z represents a —C(O)O— or —C(O)NH— group or an oxygen atom;
A represents a (CH 2 ) p group, p being an integer from 1 to 6;
B represents a linear or branched C 2 -C 12 , polymethylene chain optionally interrupted by one or more heteroatoms or heterogroups, and optionally substituted by one or more hydroxyl or amino groups;
X, which are identical or different, represent counterions; and
(b) at least one hydrophilic monomer carrying a functional acidic group which is copolymerizable with (a) and which is capable of being ionized in the application medium;
from 0.2 to 15%, by weight with respect to the total weight of said composition of a nonionic surfactant or a mixture of nonionic and anionic surfactants;
from 0 to 40%, by weight with respect to the total weight of dry matter of a calcium-sequestering organic acid; and
from 0 to 15%, by weight with respect to the total weight of said composition, expressed as dry matter, of an auxiliary agent of copolymer of acrylic acid and of maleic anhydride or acrylic acid homopolymers.
21. A process for washing dishes by hand comprising the step of treating said dishes with an efficient cleaning amount of a composition comprising:
from 0.1 to 5 parts by weight with respect to the total weight of said composition of water-soluble or water-dispersible copolymer comprising, in the form of polymerized units:
(a) at least one monomer compound of general formula I:
in which
R 1 is a hydrogen atom, a methyl or ethyl group;
R 2 , R 3 , R 4 , R 5 and R 6 , which are identical or different, are linear or branched C 1 -C 6 , alkyl, hydroxyalkyl or aminoalkyl groups;
m is an integer from 0 to 10;
n is an integer from 1 to 6;
Z represents a —C(O)— or —C(O)NH— group or an oxygen atom;
A represents a (CH 2 ) p group, p being an integer from 1 to 6;
B represents a linear or branched C 2 -C 12 , polymethylene chain optionally interrupted by one or more heteroatoms or heterogroups, and optionally substituted by one or more hydroxyl or amino groups;
X, which are identical or different, represent counterions; and
(b) at least one hydrophilic monomer carrying a functional acidic group which is copolymerizable with (a) and which is capable of being ionized in the application medium;
from 5 to 50, parts by weight of at least one surfactant;
at least one noncationic bactericide or disinfectant;
at least one synthetic cationic polymer agent;
a polymer for controling the viscosity of the mixture or the stability of the foams;
a hydrotropic agent;
a hydrating or moisturizing agent or an agent for protecting the skin; and
a dye or fragrance, and a preservative.
22. A process for the external cleaning of motor vehicles, comprising the step of cleaning said motor vehicles with an efficient cleaning amount of a composition comprising, in the form of polymerized units:
(a) at least one monomer compound of general formula I:
in which
R 1 is a hydrogen atom, a methyl or ethyl group;
R 2 , R 3 , R 4 , R 5 and R 6 , which are identical or different, are linear or branched C 1 -C 6 , alkyl, hydroxyalkyl or aminoalkyl groups;
m is an integer from 0 to 10;
n is an integer from 1 to 6;
Z represents a —C(O)O— or —C(O)NH— group or an oxygen atom;
A represents a (CH 2 ) p group, p being an integer from 1 to 6;
B represents a linear or branched C 2 -C 12 , polymethylene chain optionally interrupted by one or more heteroatoms or heterogroups, and optionally substituted by one or more hydroxyl or amino groups;
X, which are identical or different, represent counterions; and
(b) at least one hydrophilic monomer carrying a functional acidic group which is copolymerizable with (a) and which is capable of being ionized in the application medium;
from 0 to 30%, by weight of the formulation of at least one nonionic surfactant;
from 0 to 30%, by weight of the formulation of at least one anionic surfactant;
from 0 to 30%, by weight of an amphoteric and/or zwitterionic surfactant;
from 0 to 30%, by weight of a cationic surfactant; the minimum amount of surfactant being at least 1%;
an inorganic or organic builder; and
optionally, a hydrotropic agent, filler or pH modifier.
23. A process for cleaning ceramics, tilings, baths and sinks, comprising the step of cleaning said ceramics, tilings, baths and sinks with an efficient cleaning amount of a composition comprising:
from 0.02 to 5% by weight with respect to the total weight of said composition of water-soluble or water-dispersible copolymer comprising, in the form of polymerized units:
(a) at least one monomer compound of general formula I:
in which
R 1 is a hydrogen atom, a methyl or ethyl group;
R 2 , R 3 , R 4 , R 5 and R 6 , which are identical or different, are linear or branched C 1 -C 6 , alkyl, hydroxyalkyl or aminoalkyl groups;
m is an integer from 0 to 10;
n is an integer from 1 to 6;
Z represents a —C(O)O— or —C(O)NH— group or an oxygen atom;
A represents a (CH 2 ) p group, p being an integer from 1 to 6;
B represents a linear or branched C 2 -C 12 , polymethylene chain optionally interrupted by one or more heteroatoms or heterogroups, and optionally substituted by one or more hydroxyl or amino groups;
X, which are identical or different, represent counterions; and
(b) at least one hydrophilic monomer carrying a functional acidic group which is copolymerizable with (a) and which is capable of being ionized in the application medium;
from 0 to 30%, by weight of at least one nonionic surfactant;
from 0 to 30%, by weight of at least one anionic surfactant, the total amount of surfactants representing from 1.5 to 50%, by weight, with respect to the total weight of the composition;
from 0.1 to 25% by weight with respect to the total weight of the composition of at least one organic or inorganic builder; and
optionally a foam modifier,
said composition exhibiting a pH of between 3 and 1 and an a/b molar ratio of between 30/70 and 60/40.
24. A process for cleaning toilet bowls, comprising the step of cleaning said toilet bowls with a cleaning efficient amount of a composition comprising, in the form of polymerized units:
(a) at least one monomer compound of general formula I:
in which
R 1 is a hydrogen atom, a methyl or ethyl group;
R 2 , R 3 , R 4 , R 5 and R 6 , which are identical or different, are linear or branched C 1 -C 6 , alkyl, hydroxyalkyl or aminoalkyl groups;
m is an integer from 0 to 10;
n is an integer from 1 to 6;
Z represents a —C(O))O— or —C(O)NH— group or an oxygen atom;
A represents a (CH 2 ) p group, p being an integer from 1 to 6;
B represents a linear or branched C 2 -C 12 , polymethylene chain optionally interrupted by one or more heteroatoms or heterogroups, and optionally substituted by one or more hydroxyl or amino groups;
X, which are identical or different, represent counterions; and
(b) at least one hydrophilic monomer carrying a functional acidic group which is copolymerizable with (a) and which is capable of being ionized in the application medium;
from 0.1 to 40% by weight with respect to the total weight of the composition of an inorganic acid cleaning agent selected from the group consisting of phosphoric acid, sulfamic acid, hydrochloric acid, hydrofluoric acid, sulfuric acid, nitric acid, acetic acid, hydroxyacetic acid, adipic acid, citric acid, formic acid, fumaric acid, gluconic acid, glutaric acid, glycolic acid, malic acid, maleic acid, lactic acid, malonic acid, oxalic acid, succinic acid and sodium bisulfate;
from 0.5 to 10% by weight of a surfactant;
from 0.1 to 3% by weight of a thickener; and
a preservative intended to prevent the growth of microorganisms; said composition exhibiting a pH of between 0.5 and 4.
25. A process for rinsing shower walls, comprising the step of rinsing said shower walls with a rinsing efficient amount of a composition comprising:
from 0.02 to 5% by weight, of water-soluble or water-dispersible copolymer comprising, in the form of polymerized units:
(a) at least one monomer compound of general formula I:
in which
R 1 is a hydrogen atom, a methyl or ethyl group;
R 2 , R 3 , R 4 , R 5 and R 6 , which are identical or different, are linear or branched C 3 -C 6 , alkyl, hydroxyalkyl or aminoalkyl groups;
m is an integer from 0 to 10;
n is an integer from 1 to 6;
Z represents a —C(O)O— or —C(O)NH— group or an oxygen atom;
A represents a (CH 2 ) p group, p being an integer from 1 to 6;
B represents a linear or branched C 2 -C 12 , polymethylene chain optionally interrupted by one or more heteroatoms or heterogroups, and optionally substituted by one or more hydroxyl or amino groups;
X, which are identical or different, represent counterions; and
(b) at least one hydrophilic monomer carrying a functional acidic group which is copolymerizable with (a) and which is capable of being ionized in the application medium;
from 0.5 to 5% by weight of a nonionic surfactant; and
optionally from 0.01 to 5% by weight of a metal-chelating agent.
26. A process for cleaning a hard surface according to claim 1 , thereby conferring hydrophilization properties on said hard surface.
27. The process according to claim 26 , wherein the hydrophilization properties are “resistance to running”, “resistance to condensation”, “resistance to stains” or “resistance to marks”.
28. The process according to claim 1 , wherein from 0.0001 to 6 g/m 2 , of said water-soluble or water-dispersible copolymer are deposited on said surface.
29. The process according to claim 28 , wherein the surface is a glass, a ceramic, a tile, a sink, a toilet bowl, a window, a shower wall, or a motor vehicle.
30. A process for the treatment of hard surfaces, comprising the step of treating said surfaces with an efficient cleaning or rinsing amount of a composition comprising at least one water-soluble or water dispersible copolymer comprising, in the form of polymerized units:
(a) at least one monomer compound of general formula I:
in which
R 1 is a hydrogen atom, a methyl or ethyl group;
R 2 , R 3 , R 4 , R 5 and R 6 , which are identical or different, are linear or branched C 1 -C 6 , alkyl, hydroxyalkyl or aminoalkyl groups;
m is an integer from 0 to 10;
n is an integer from 1 to 6;
Z represents a —C(O)O— or —C(O)NH— group or an oxygen atom;
A represents a (CH 2 ) p group, p being an integer from 1 to 6;
B represents a linear or branched C 2 -C 12 , polymethylene chain optionally interrupted by one or more heteroatoms or heterogroups, and optionally substituted by one or more hydroxyl or amino groups;
X, which are identical or different, represent counterions; and
(b) at least one hydrophilic monomer carrying a functional acidic group which is copolymerizable with (a) and which is capable of being ionized in the application medium.
31. The process according to claim 30, wherein, in the general formula I:
Z represents C(O)O, C(O)NH or O; n is equal to 2 or 3; m ranges from 0 to 2; B represents
with q from 1 to 4; and
R 1 to R 6 , which are identical or different, represent a methyl or ethyl group.
32. The process according to claim 30, in which the monomer (a) is represented by the following formula:
wherein p=2 to 4.
33. The process according to claim 30, in which the monomer (a) is:
X − representing a chloride ion.
34. The process according to claim 30, wherein said polymer further comprising:
(c) at least one monomer compound with ethylenic unsaturation with a neutral charge which is copolymerizable with (a) and (b).
35. The process according to claim 34, wherein (c) is a hydrophilic monomer compound with ethylenic unsaturation with a neutral charge, carrying one or more hydrophilic groups, which is copolymerizable with (a) and (b).
36. The process according to claim 30, wherein (b) is a C 3 -C 8 carboxylic, sulfonic, sulfuric, phosphonic or phosphoric acids with monoethylenic unsaturation.
37. The process according to claim 34, wherein the monomer (b) is acrylic acid, methacrylic acid, α-ethacrylic acid, β,β-dimethylacrylic acid, methylenemalonic acid, vinylacetic acid, allylacetic acid, ethylidineacetic acid, propylidineacetic acid, crotonic acid, maleic acid, fumaric acid, itaconic acid, citraconic acid, mesaconic acid, N-(methacroyl)alanine, N-(acryloyl)hydroxyglycine, sulfopropyl acrylate, sulfoethyl acrylate, sulfoethyl methacrylate, styrenesulfonic acid, vinylsulfonic acid, vinylphosphonic acid, phosphoethyl acrylate, phophonoethyl acrylate, phosphopropyl acrylate, phophonopropyl acrylate, phosphoethyl methacrylate, phophonoethyl methacrylate, phosphopropyl methacrylate, or phophonopropyl methacrylate.
38. The process according to claim 34, wherein the monomer (c) is acrylamide, vinyl alcohol, C 1 -C 4 alkyl ester of acrylic acid and of methacrylic acid, C 1 -C 4 hydroxyalkyl ester of acrylic acid and of methacrylic acid, polyalkoxylated ester of acrylic acid and of methacrylic acid, ester of acrylic acid, ester of methacrylic acid and of polyethylene glycol, polypropylene glycol C 1 -C 25 monoalkyl ether, vinyl acetate, vinylpyrrolidone or methyl vinyl ether.
39. The process according to claim 30, wherein X is halogen, sulfonate, sulfate, hydrogensulfate, phosphate, phosphanate, citrate, formate or an acetate anion.
40. The process according to claim 34, wherein the water-soluble or water-dispersible copolymer is obtained by copolymerization
of 3 to 80 mol %, of the monomer (a); of 10 to 95 mol %, of the monomer (b); of 0 to 50 mol %, of the monomer (c).
41. The process according to claim 30, wherein the monomers (a) and the monomers (b) have a molar ratio by weight of the total of the monomers (a) to the total of the monomers (b) between 80/20 and 5/95.
42. The process according to claim 30, wherein the copolymer has a molecular mass of at least 1000.
43. The process according to claim 30, wherein the copolymer has the following formula:
wherein
x having a mean value of 0 to 50%,
y having a mean value of 10 to 95%,
z having a mean value of 3 to 80%, and
with x+y+z=100%, x, y and z representing the mol % of units derived from acrylamide, acrylic acid (sodium salt) and from Diquat respectively;
wherein
x having a mean value of 0 to 50%,
y having a mean value of 10 to 95%, and
z having a mean value of 3 to 80%,
wherein
x having a mean value of 0 to 50%,
y having a mean value of 10 to 95%, and
z having a mean value of 3 to 80%,
wherein
x having a mean value of 0 to 50%,
y having a mean value of 10 to 95%, and
z having a mean value of 3 to 80%,
wherein
x having a mean value of 0 to 50%,
y having a mean value of 10 to 95%, and
z having a mean value of 3 to 80%,
wherein
x having a mean value of 0 to 50%,
y having a mean value of 10 to 95%, and
z having a mean value of 3 to 80%, or
wherein
x having a mean value of 0 to 50%,
y having a mean value of 10 to 95%, and
z having a mean value of 3 to 80%.
44. The process according to claim 30, wherein the copolymer of formula I represents from 0.0005 to 10% by weight with respect to the total weight of said composition.
45. The process according to claim 30, wherein said composition further comprises a surfactant, with a copolymer/surfactant ratio by weight of between 1/2 and 1/100.
46. A process for cleaning windows, comprising the step of treating said windows with a an efficient cleaning amount of a composition comprising: from 0.001 to 10%, by weight of a water-soluble or water-dispersible copolymer comprising, in the form of polymerized units:
(a) at least one monomer compound of general formula I:
in which
R 1 is a hydrogen atom, a methyl or ethyl group;
R 2 , R 3 , R 4 , R 5 and R 6 , which are identical or different, are linear or branched C 1 -C 6 , alkyl, hydroxyalkyl or aminoalkyl groups;
m is an integer from 0 to 10;
n is an integer from 1 to 6;
Z represents a —C(O)O— or —C(O)NH— group or an oxygen atom;
A represents a (CH 2 ) p group, p being an integer from 1 to 6;
B represents a linear or branched C 2 -C 12 , polymethylene chain optionally interrupted by one or more heteroatoms or heterogroups, and optionally substituted by one or more hydroxyl or amino groups;
X, which are identical or different, represent counterions; and
(b) at least one hydrophilic monomer carrying a functional acidic group which is copolymerizable with (a) and which is capable of being ionized in the application medium;
from 0.005 to 20%, by weight of at least one nonionic and/or anionic surfactant;
the remainder being formed of water, or solvents.
47. The process according to claim 46, wherein said composition further comprises an amine oxide as nonionic surfactant.
48. A process for washing dishes in an automatic dishwasher, comprising the step of treating said dishes with an efficient washing amount of a composition comprising: from 0.001 to 10%, by weight of a water-soluble or water-dispersible copolymer comprising, in the form of polymerized units:
(a) at least one monomer compound of general formula I:
in which
R 1 is a hydrogen atom, a methyl or ethyl group;
R 2 , R 3 , R 4 , R 5 and R 6 , which are identical or different, are linear or branched C 1 -C 6 , alkyl, hydroxyalkyl or aminoalkyl groups;
m is an integer from 0 to 10;
n is an integer from 1 to 6;
Z represents a —C(O)O— or —C(O)NH— group or an oxygen atom;
A represents a (CH 2 ) p group, p being an integer from 1 to 6;
B represents a linear or branched C 2 -C 12 , polymethylene chain optionally interrupted by one or more heteroatoms or heterogroups, and optionally substituted by one or more hydroxyl or amino groups;
X, which are identical or different, represent counterions; and
(b) at least one hydrophilic monomer carrying a functional acidic group which is copolymerizable with (a) and which is capable of being ionized in the application medium;
from 0.2 to 10%, by weight with respect to the total weight of dry matter of a surfactant, and, optionally;
from 30 to 95% by weight with respect to the total weight of detergent composition, expressed as dry matter, of builders; and
from 3 to 25% by weight with respect to the total weight of the composition of an oxidizing system.
49. A process for rinsing dishes in an automatic dishwasher, comprising the step of treating said dishes with an efficient rinsing amount of a composition comprising:
from 0.02 to 10%, by weight of water-soluble or water-dispersible copolymer, with respect to the total weight of the composition, said copolymer comprising from 0.001 to 10%, by weight of a water-soluble or water-dispersible copolymer comprising, in the form of polymerized units: (a) at least one monomer compound of general formula I:
in which
R 1 is a hydrogen atom, a methyl or ethyl group;
R 2 , R 3 , R 4 , R 5 and R 6 , which are identical or different, are linear or branched C 1 -C 6 , alkyl, hydroxyalkyl or aminoalkyl groups;
m is an integer from 0 to 10;
n is an integer from 1 to 6;
Z represents a —C(O)O— or —C(O)NH— group or an oxygen atom;
A represents a (CH 2 ) p group, p being an integer from 1 to 6;
B represents a linear or branched C 2 -C 12 , polymethylene chain optionally interrupted by one or more heteroatoms or heterogroups, and optionally substituted by one or more hydroxyl or amino groups;
X, which are identical or different, represent counterions; and
(b) at least one hydrophilic monomer carrying a functional acidic group which is copolymerizable with (a) and which is capable of being ionized in the application medium;
from 0.2 to 15%, by weight with respect to the total weight of said composition of a nonionic surfactant or a mixture of nonionic and anionic surfactants;
from 0 to 40%, by weight with respect to the total weight of dry matter of a calcium-sequestering organic acid; and
from 0 to 15%, by weight with respect to the total weight of said composition, expressed as dry matter, of an auxiliary agent of copolymer of acrylic acid and of maleic anhydride or acrylic acid homopolymers.
50. A process for washing dishes by hand comprising the step of treating said dishes with an efficient cleaning amount of a composition comprising:
from 0.1 to 5 parts by weight with respect to the total weight of said composition of water-soluble or water-dispersible copolymer comprising, in the form of polymerized units: (a) at least one monomer compound of general formula I:
in which
R 1 is a hydrogen atom, a methyl or ethyl group;
R 2 , R 3 , R 4 , R 5 and R 6 , which are identical or different, are linear or branched C 1 -C 6 , alkyl, hydroxyalkyl or aminoalkyl groups;
m is an integer from 0 to 10;
n is an integer from 1 to 6;
Z represents a —C(O)O— or —C(O)NH— group or an oxygen atom;
A represents a (CH 2 ) p group, p being an integer from 1 to 6;
B represents a linear or branched C 2 -C 12 , polymethylene chain optionally interrupted by one or more heteroatoms or heterogroups, and optionally substituted by one or more hydroxyl or amino groups;
X, which are identical or different, represent counterions; and
(b) at least one hydrophilic monomer carrying a functional acidic group which is copolymerizable with (a) and which is capable of being ionized in the application medium;
from 5 to 50, parts by weight of at least one surfactant;
at least one noncationic bactericide or disinfectant;
at least one synthetic cationic polymer agent;
a polymer for controling the viscosity of the mixture or the stability of the foams;
a hydrotropic agent;
a hydrating or moisturizing agent or an agent for protecting the skin; and
a dye or fragrance, and a preservative.
51. A process for the external cleaning of motor vehicles, comprising the step of cleaning said motor vehicles with an efficient cleaning amount of a composition comprising, in the form of polymerized units:
(a) at least one monomer compound of general formula I:
in which
R 1 is a hydrogen atom, a methyl or ethyl group;
R 2 , R 3 , R 4 , R 5 and R 6 , which are identical or different, are linear or branched C 1 -C 6 , alkyl, hydroxyalkyl or aminoalkyl groups;
m is an integer from 0 to 10;
n is an integer from 1 to 6;
Z represents a —C(O)O— or —C(O)NH— group or an oxygen atom;
A represents a (CH 2 ) p group, p being an integer from 1 to 6;
B represents a linear or branched C 2 -C 12 , polymethylene chain optionally interrupted by one or more heteroatoms or heterogroups, and optionally substituted by one or more hydroxyl or amino groups;
X, which are identical or different, represent counterions; and
(b) at least one hydrophilic monomer carrying a functional acidic group which is copolymerizable with (a) and which is capable of being ionized in the application medium;
from 0 to 30%, by weight of the formulation of at least one nonionic surfactant;
from 0 to 30%, by weight of the formulation of at least one anionic surfactant;
from 0 to 30%, by weight of an amphoteric and/or zwitterionic surfactant;
from 0 to 30%, by weight of a cationic surfactant; the minimum amount of surfactant being at least 1%;
an inorganic or organic builder; and
optionally, a hydrotropic agent, filler or pH modifier.
52. A process for cleaning ceramics, tilings, baths and sinks, comprising the step of cleaning said ceramics, tilings, baths and sinks with an efficient cleaning amount of a composition comprising:
from 0.02 to 5% by weight with respect to the total weight of said composition of water-soluble or water-dispersible copolymer comprising, in the form of polymerized units:
(a) at least one monomer compound of general formula I:
in which
R 1 is a hydrogen atom, a methyl or ethyl group;
R 2 , R 3 , R 4 , R 5 and R 6 , which are identical or different, are linear or branched C 1 -C 6 , alkyl, hydroxyalkyl or aminoalkyl groups;
m is an integer from 0 to 10;
n is an integer from 1 to 6;
Z represents a —C(O)O— or —C(O)NH— group or an oxygen atom;
A represents a (CH 2 ) p group, p being an integer from 1 to 6;
B represents a linear or branched C 2 -C 12 , polymethylene chain optionally interrupted by one or more heteroatoms or heterogroups, and optionally substituted by one or more hydroxyl or amino groups;
X, which are identical or different, represent counterions; and
(b) at least one hydrophilic monomer carrying a functional acidic group which is copolymerizable with (a) and which is capable of being ionized in the application medium;
from 0 to 30%, by weight of at least one nonionic surfactant;
from 0 to 30%, by weight of at least one anionic surfactant, the total amount of surfactants representing
from 1.5 to 50%, by weight, with respect to the total weight of the composition;
from 0.1 to 25% by weight with respect to the total weight of the composition of at least one organic or inorganic builder; and
optionally a foam modifier,
said composition exhibiting a pH of between 3 and 1 and an a/b molar ratio of between 30/70 and 60/40.
53. A process for cleaning toilet bowls, comprising the step of cleaning said toilet bowls with a cleaning efficient amount of a composition comprising, in the form of polymerized units:
(a) at least one monomer compound of general formula I:
in which
R 1 is a hydrogen atom, a methyl or ethyl group;
R 2 , R 3 , R 4 , R 5 and R 6 , which are identical or different, are linear or branched C 1 -C 6 , alkyl, hydroxyalkyl or aminoalkyl groups;
m is an integer from 0 to 10;
n is an integer from 1 to 6;
Z represents a —C(O)O— or —C(O)NH— group or an oxygen atom;
A represents a (CH 2 ) p group, p being an integer from 1 to 6;
B represents a linear or branched C 2 -C 12 , polymethylene chain optionally interrupted by one or more heteroatoms or heterogroups, and optionally substituted by one or more hydroxyl or amino groups;
X, which are identical or different, represent counterions; and
(b) at least one hydrophilic monomer carrying a functional acidic group which is copolymerizable with (a) and which is capable of being ionized in the application medium;
from 0.1 to 40% by weight with respect to the total weight of the composition of an inorganic acid cleaning agent selected from the group consisting of phosphoric acid, sulfamic acid, hydrochloric acid, hydrofluoric acid, sulfuric acid, nitric acid, acetic acid, hydroxyacetic acid, adipic acid, citric acid, formic acid, fumaric acid, gluconic acid, glutaric acid, glycolic acid, malic acid, maleic acid, lactic acid, malonic acid, oxalic acid, succinic acid and sodium bisulfate;
from 0.5 to 10% by weight of a surfactant;
from 0.1 to 3% by weight of a thickener; and
a preservative intended to prevent the growth of microorganisms; said composition exhibiting a pH of between 0.5 and 4.
54. A process for rinsing shower walls, comprising the step of rinsing said shower walls with a rinsing efficient amount of a composition comprising:
from 0.02 to 5% by weight, of water-soluble or water-dispersible copolymer comprising, in the form of polymerized units:
(a) at least one monomer compound of general formula I:
in which
R 1 is a hydrogen atom, a methyl or ethyl group;
R 2 , R 3 , R 4 , R 5 and R 6 , which are identical or different, are linear or branched C 1 -C 6 , alkyl, hydroxyalkyl or aminoalkyl groups;
m is an integer from 0 to 10;
n is an integer from 1 to 6;
Z represents a —C(O)O— or —C(O)NH— group or an oxygen atom;
A represents a (CH 2 ) p group, p being an integer from 1 to 6;
B represents a linear or branched C 2 -C 12 , polymethylene chain optionally interrupted by one or more heteroatoms or heterogroups, and optionally substituted by one or more hydroxyl or amino groups;
X, which are identical or different, represent counterions; and
(b) at least one hydrophilic monomer carrying a functional acidic group which is copolymerizable with (a) and which is capable of being ionized in the application medium;
from 0.5 to 5% by weight of a nonionic surfactant; and
optionally from 0.01 to 5% by weight of a metal-chelating agent.
55. A process for cleaning a hard surface according to claim 30, thereby conferring hydrophilization properties on said hard surface.
56. The process according to claim 55, wherein the hydrophilization properties are “resistance to running”, “resistance to condensation”, “resistance to stains” or “resistance to marks”.
57. The process according to claim 30, wherein from 0.0001 to 6 g/m 2 , of said water-soluble or water-dispersible copolymer are deposited on said surface.
58. The process according to claim 57, wherein the surface is a glass, a ceramic, a tile, a sink, a toilet bowl, a window, a shower wall, or a motor vehicle.
59. A cleaning/rinsing composition, comprising at least one surfactant and/or at least one cleaning additive or vehicle and at least one water-soluble or water dispersible copolymer which comprises the copolymerizate of:
(a) at least one monomer compound of general formula I:
in which:
R 1 is a hydrogen atom, a methyl or ethyl group;
R 2 , R 3 , R 4 , R 5 and R 6 , which are identical or different, are linear or branched C 1 -C 6 , alkyl, hydroxyalkyl or aminoalkl groups;
m is an integer ranging from 0 to 10;
n is an integer ranging from 1 to 6;
Z is a —C(O)O— or —C(O)NH— group or an oxygen atom;
A is a (CH 2 ) p group, p being an integer ranging from 1 to 6;
B is a linear or branched C 2 -C 12 , polymethylene chain optionally interrupted by one or more heteroatoms or heterogroups, and optionally substituted by one or more hydroxyl or amino groups;
X, which are identical or different, represent counterions; and
(b) at least one hydrophilic monomer carrying a functional acidic group which is copolymerizable with (a) and which is capable of being ionized in a cleaning/rinsing medium; the at least one monomer (a) being effective to enable anchoring of said copolymer to a surface to be cleaned and the at least one monomer (b) being effective to confer hydrophilic characteristics thereon.
60. The cleaning/rinsing composition as defined by claim 59, wherein, in the general formula I:
Z is C(O)O, C(O)NH or O; n is equal to 2 or 3; m ranges from 0 to 2; B is
with q from 1 to 4; and
R 1 to R 6 , which are identical or different, represent a methyl or ethyl group.
61. The cleaning/rinsing composition as defined by claim 59, in which the monomer (a) is:
X − representing a chloride ion.
62. The cleaning/rinsing composition as defined by claim 59, said at least one water-soluble or water-dispersible copolymer further comprising:
(c) at least one monomer compound with ethylenic unsaturation with a neutral charge which is copolymerizable with (a) and (b).
63. The cleaning/rinsing composition as defined by claim 59, wherein (c) is a hydrophilic monomer compound with ethylenic unsaturation with a neutral charge, carrying one or more hydrophilic groups, which is copolymerizable with (a) and (b).
64. The cleaning/rinsing composition as defined by claim 59, wherein (b) is a C 3 -C 8 carboxylic, sulfonic, sulfuric, phosphonic or phosphoric acids with monoethylenic unsaturation.
65. The cleaning/rinsing composition as defined by claim 59, wherein the monomer (b) is acrylic acid, methacrylic acid, α-ethacrylic acid, β,β-dimethylacrylic acid, methylenemalonic acid, vinylacetic acid, allylacetic acid, ethylidineacetic acid, propylidineacetic acid, crotonic acid, maleic acid, fumaric acid, itaconic acid, citraconic acid, mesaconic acid, N-(methacroyl)alanine, N-(acryloyl)hydroxyglycine, sulfopropyl acrylate, sulfoethyl acrylate, sulfoethyl methacrylate, styrenesulfonic acid, vinylsulfonic acid, vinylphosphonic acid, phosphoethyl acrylate, phophonoethyl acrylate, phosphopropyl acrylate, phophonopropyl acrylate, phosphoethyl methacrylate, phophonoethyl methacrylate, phosphopropyl methacrylate, or phosphonopropyl methacrylate.
66. The cleaning/rinsing composition as defined by claim 62, wherein the monomer (c) is acrylamide, vinyl alcohol, C 1 -C 4 alkyl ester of acrylic acid and of methacrylic acid, C 1 -C 4 hydroxyalkyl ester of acrylic acid and of methacrylic acid, polyalkoxylated ester of acrylic acid and of methacrylic acid, ester of acrylic acid, ester of methacrylic acid and of polyethylene glycol, polypropylene glycol C 1 -C 25 monoalkyl ether, vinyl acetate, vinylpyrrolidone or methyl vinyl ether.
67. The cleaning/rinsing composition as defined by claim 59, wherein X is halogen, sulfonate, sulfate, hydrogensulfate, phosphate, phosphonate, citrate, formate or an acetate anion.
68. The cleaning/rinsing composition as defined by claim 59, comprising at least one water-soluble or water-dispersible copolymer having at least one of the following formulae:
wherein:
x having a mean value of 0 to 50%,
y having a mean value of 10 to 95%,
z having a mean value of 3 to 80%, and
with x+y+z=100%, x, y and z representing the mol % of units derived from acrylamide, acrylic acid (sodium salt) and from Diquat respectively;
wherein:
x having a mean value of 0 to 50%,
y having a mean value of 10 to 95%, and
z having a mean value of 3 to 80%;
wherein:
x having a mean value of 0 to 50%,
y having a mean value of 10 to 95%, and
z having a mean value of 3 to 80%;
wherein:
x having a mean value of 0 to 50%,
y having a mean value of 10 to 95%, and
z having a mean value of 3 to 80%;
wherein:
x having a mean value of 0 to 50%,
y having a mean value of 10 to 95%, and
z having a mean value of 3 to 80%;
wherein:
x having a mean value of 0 to 50%,
y having a mean value of 10 to 95%, and
z having a mean value of 3 to 80%; or
wherein:
x having a mean value of 0 to 50%,
y having a mean value of 10 to 95%, and
z having a mean value of 3 to 80%.
69. A water-soluble or water-dispersible copolymer which comprises the copolymerizate of:
(a) at least one monomer compound of general formula I:
in which:
R 1 is a hydrogen atom, a methyl or ethyl group;
R 2 , R 3 , R 4 , R 5 and R 6 which are identical or different, are linear or branched C1-C6 alkyl, hydroxyalkyl or aminoalkyl groups;
m is 0 or 2;
n is an integer ranging from 1 to 6;
Z is a —C(O)O— or —C(O)NH— group or an oxygen atom;
A is a (CH 2 ) p group, p being an integer ranging from 1 to 6;
B is a linear or branched C 1 -C 12 , polymethylene chain optionally interrupted by one or more heteroatoms or heterogroups, and optionally substituted by one or more hydroxyl or amino groups;
X, which are identical or different, represent counterions; and
(b) at least one hydrophilic monomer carrying a functional acidic group which is copolymerizable with (a) and which is capable of being ionized in a cleaning/rinsing medium.
70. The water-soluble or water-dispersible copolymer as defined by claim 69, wherein, in the general formula I:
Z represents C(O)O, C(O)NH or O; n is equal to 2 or 3; m ranges from 0 to 2; B is
with q from 1 to 4; and
R 1 to R 6 , which are identical or different, represent a methyl or ethyl group.
71. The water-soluble or water-dispersible copolymer as defined by claim 69, further comprising:
(c) at least one monomer compound with ethylenic unsaturation with a neutral charge which is copolymerizable with (a) and (b).
72. The water-soluble or water-dispersible copolymer as defined by claim 71, wherein (c) is a hydrophilic monomer compound with ethylenic unsaturation with a neutral charge, carrying one or more hydrophilic groups, which is copolymerizable with (a) and (b).
73. The water-soluble or water-dispersible copolymer as defined by claim 69, wherein (b) is a C 3 -C 8 carboxylic, sulfonic, sulfuric, phosphonic or phosphoric acids with monoethylenic unsaturation.
74. The water-soluble or water-dispersible copolymer as defined by claim 69, wherein the monomer (b) is acrylic acid, methacrylic acid, α-ethacrylic acid, β,β-dimethylacrylic acid, methylenemalonic acid, vinylacetic acid, allylacetic acid, ethylidineacetic acid, propylidineacetic acid, crotonic acid, maleic acid, fumaric acid, itaconic acid, citraconic acid, mesaconic acid, N-(methacroyl)alanine, N-(acryloyl)hydroxyglycine, sulfopropyl acrylate, sulfoethyl acrylate, sulfoethyl methacrylate, styrenesulfonic acid, vinylsulfonic acid, vinylphosphonic acid, phosphoethyl acrylate, phophonoethyl acrylate, phosphopropyl acrylate, phophonopropyl acrylate, phosphoethyl methacrylate, phophonoethyl methacrylate, phosphopropyl methacrylate, or phophonopropyl methacrylate.
75. The water-soluble or water-dispersible copolymer as defined by claim 71, wherein the monomer (c) is acrylamide, vinyl alcohol, C 1 -C 4 alkyl ester of acrylic acid and of methacrylic acid, C 1 -C 4 hydroxyalkyl ester of acrylic acid and of methacrylic acid, polyalkoxylated ester of acrylic acid and of methacrylic acid, ester of acrylic acid, ester of methacrylic acid and of polyethylene glycol, polypropylene glycol C 1 -C 25 monoalkyl ether, vinyl acetate, vinylpyrrolidone or methyl vinyl ether.
76. The water-soluble or water-dispersible copolymer as defined by claim 69, said water-soluble or water-dispersible copolymer having one of the following formulae:
wherein:
x having a mean value of 0 to 50%,
y having a mean value of 10 to 95%,
z having a mean value of 3 to 80%, and
with x+y+z=100%, x, y and z representing the mol % of units derived from acrylamide, acrylic acid (sodium salt) and from Diquat respectively;
wherein:
x having a mean value of 0 to 50%,
y having a mean value of 10 to 95%, and
z having a mean value of 3 to 80%;
wherein:
x having a mean value of 0 to 50%,
y having a mean value of 10 to 95%, and
z having a mean value of 3 to 80%;
wherein:
x having a mean value of 0 to 50%,
y having a mean value of 10 to 95%, and
z having a mean value of 3 to 80%;
wherein:
x having a mean value of 0 to 50%,
y having a mean value of 10 to 95%, and
z having a mean value of 3 to 80%;
wherein:
x having a mean value of 0 to 50%,
y having a mean value of 10 to 95%, and
z having a mean value of 3 to 80%; or
wherein:
x having a mean value of 0 to 50%,
y having a mean value of 10 to 95%, and
z having a mean value of 3 to 80%.
77. A hydrophilized hard surface having at least one water-soluble or water-dispersible copolymer as defined by claim 69 deposited thereon and anchored thereto.
78. The cleaning/rinsing composition as defined by claim 59, wherein m is 0 or 2.Cited by (0)
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