Curable composition

Abstract

An object of the present invention is to provide a curable composition that can be used as sealing materials, adhesives, and the like, has excellent curing properties, and gives a cured product excellent in elongation properties. The object can be attained by means of a curable composition comprising: a reactive silyl group-containing polyether polymer (A) that contains a reactive silyl group with high activity (e.g., (ClCH 2 )(CH 3 O) 2 Si—, (CH 3 OCH 2 )(CH 3 O) 2 Si—, or CH 3 (CH 3 O) 2 Si—CH 2 —NH—C(═O)—); and a reactive silyl group-containing polyether polymer (B) that contains a reactive silyl group (e.g., CH 3 (CH 3 O) 2 Si— or (CH 3 O) 3 Si—) different from that mentioned above and/or a (meth)acrylic polymer (C) containing a reactive silyl group that is not particularly limited.

The invention claimed is: 
     
       1. A curable composition, comprising: a polyether polymer (A) containing a reactive silyl group represented by the following formula (1); and at least one of a polyether polymer (B) containing a reactive silyl group represented by the following formula (2) and a (meth)acrylic polymer (C) containing a reactive silyl group represented by the following formula (3):
   —W—CH 2 —SiR 1   a R 2   b X c    (1)
 
 
       wherein R 1  is a methoxymethyl group; R 2  represents a C1 to C20 hydrocarbon group, a C6 to C20 aryl group, a C7 to C20 aralkyl group, or a triorganosiloxy group represented by R 0   3 SiO— wherein each of three R 0 s is a C1 to C20 hydrocarbon group and they may be the same as or different from each other; X represents a hydroxy or hydrolyzable group; W represents a linking group selected from —O—R 8 —, —O—CO—N(R 9 )—, —N(R 9 )—CO—O—, —N(R 9 )—CO—N(R 9 )—, —S—CO—NH—, —NH—CO—S—, and —S— wherein R 8  represents a divalent C1 to C8 hydrocarbon group, and R 9  represents hydrogen or a C1 to C18 hydrocarbon group optionally substituted with halogen; in the case that W is —O—R 8 —, a is 1 or 2, b is 0 or 1, and c is 1 or 2, provided that a+b+c =3 is satisfied; in the case that W is a group other than —O—R 8 -, a is 0, 1, or 2, b is 0, 1, or 2, and c is 1, 2, or 3, provided that a+b+c=3 is satisfied; and in the case that a plurality of R 1 s, R 2 s, or Xs exist, they may be the same as or different from each other,
   —V—SiR 2   d X 3-d    (2)
 
 
       wherein R 2  and X are defined as mentioned in formula (1); V represents a divalent C2 to C8 hydrocarbon group; d represents any of 0, 1, and 2; and in the case that a plurality of R 2 s or Xs exist, they may be the same as or different from each other, and
   —Z—(CH 2 ) n —SiR 1   a R 2   b X c    (3)
 
 
       wherein R 1 , of Formula (3) is a C1 to C20 hydrocarbon group wherein at least one hydrogen atom on carbon atoms at positions 1 to 3 is replaced with halogen, —OR 3 , —NR 4 R 5 , —N═R 6 , —SR 7  (in which each of R 3 , R 4 , R 5 , and R 7  is a hydrogen atom or a C1 to C20 substituted or unsubstituted hydrocarbon group, and R 6  is a divalent C1 to C20 substituted or unsubstituted hydrocarbon group), a C1 to C20 perfluoroalkyl group, or a cyano group; R 2 , and X are defined as mentioned in formula (1); Z represents a linking group selected from —CO—O—, —O—CO—N(R 9 )—, —N(R 9 )—CO—O—, —N(R 9 )—CO—N(R 9 )—, —S—CO—NH—, —NH—CO—S—, and —S— wherein R 9  is defined as mentioned in formula (1); n represents a number of 1 to 8; a is 0,1, or 2, b is 0, 1, or 2, and c is 1, 2, or 3, provided that the condition: a+b+c =3 is satisfied; and in the case that a plurality of R 1 s, R 2 s, or Xs exist, they may be the same as or different from each other. 
     
     
       2. The curable composition according to  claim 1 , wherein W in formula (1) is —O—R 8 — wherein R 8  is a divalent C1 to C8 hydrocarbon group. 
     
     
       3. The curable composition according to  claim 1 , wherein the polyether polymer (A) is a polyoxypropylene polymer. 
     
     
       4. The curable composition according to  claim 1 , wherein the polyether polymer (A) is a linear polymer having no branch. 
     
     
       5. The curable composition according to  claim 1 , wherein a backbone structure of the polyether polymer (B) is a polyoxypropylene polymer. 
     
     
       6. The curable composition according to  claim 1 , wherein the reactive silyl group of formula (2) is a dimethoxymethylsilyl group. 
     
     
       7. The curable composition according to  claim 1 , wherein the (meth)acrylic polymer (C) is at least one of a reactive silyl group-containing alkyl (meth)acrylate polymer and copolymer. 
     
     
       8. A curable composition, which comprises a polyether polymer (A) containing a reactive silyl group represented by the following formula (1); a polyether polymer (B) containing a reactive silyl group represented by the following formula (2); and a (meth)acrylic polymer (C) containing a reactive silyl group represented by the following formula (3):
   —W—CH 2 —SiR 1   a R 2   b X c    (1)
 
 
       wherein R 1  is a C1 to C20 hydrocarbon group wherein at least one hydrogen atom on carbon atoms at positions 1 to 3 is replaced with halogen, —OR 3 , —NR 4 R 5 , —N═R 6 , —SR 7  (in which each of R 3 , R 4 , R 5 , and R 7  is a hydrogen atom or a C1 to C20 substituted or unsubstituted hydrocarbon group, and R 6  is a divalent C1 to C20 substituted or unsubstituted hydrocarbon group), a C1 to C20 perfluoroalkyl group, or a cyano group; R 2  represents a C1 to C20 hydrocarbon group, a C6 to C20 aryl group, a C7 to C20 aralkyl group, or a triorganosiloxy group represented by R 0   3 SiO— wherein each of three R 0 s is a C1 to C20 hydrocarbon group and they may be the same as or different from each other; X represents a hydroxy or hydrolyzable group; W represents a linking group selected from —O—R 8 —, —O—CO—N(R 9 )—, —N(R 9 )—CO—O—, —N(R 9 )—CO—N(R 9 )—, —S—CO—NH—, —NH—CO—S—, and —S— wherein R 8  represents a divalent C1 to C8 hydrocarbon group, and R 9  represents hydrogen or a C1 to C18 hydrocarbon group optionally substituted with halogen; in the case that W is —O—R 8 —, a is 1 or 2, b is 0 or 1, and c is 1 or 2, provided that a+b+c =3 is satisfied; in the case that W is a group other than —O—R 8 —, a is 0, 1, or 2, b is 0, 1, or 2, and c is 1, 2, or 3, provided that a+b+c =3 is satisfied; and in the case that a plurality of R 1 s, R 2 s, or Xs exist, they may be the same as or different from each other,
   —V—SiR 2   d X 3-d    (2)
 
 
       wherein R 2  and X are defined as mentioned in formula (1); V represents a divalent C2 to C8 hydrocarbon group; d represents any of 0, 1, and 2; and in the case that a plurality of R 2 s or Xs exist, they may be the same as or different from each other, and
   —Z—(CH 2 ) n —SiR 1   a R 2   b X c    (3)
 
 
       wherein R 1 , R 2 , and X are defined as mentioned in formula (1); Z represents a linking group selected from —CO—O—, —O—CO—N(R 9 )—, —N(R 9 )—CO—O—, —N(R 9 )—CO—N(R 9 )—, —S—CO—NH—, —NH—CO—S—, and —S— wherein R 9  is defined as mentioned in formula (1); n represents a number of 1 to 8; a is 0, 1, or 2, b is 0, 1, or 2, and c is 1, 2, or 3, provided that the condition: a+b+c =3 is satisfied; and in the case that a plurality of R 1 s, R 2 s, or Xs exist, they may be the same as or different from each other. 
     
     
       9. The curable composition according to  claim 8 , wherein the polyether polymer (A) has a number average molecular weight of 22,000 or higher. 
     
     
       10. The curable composition according to  claim 8 , wherein the polyether polymer (A) and the polyether polymer (B) are contained at a ratio of (A):(B)=50:50 to 5:95 (parts by weight). 
     
     
       11. The curable composition according to  claim 8 , further comprising: at least one of an amine compound (d1) and an organic dialkyltin compound (d2) as a condensation catalyst (D). 
     
     
       12. A sealing material, comprising the curable composition according to  claim 8  as a component. 
     
     
       13. An adhesive, comprising the curable composition according to  claim 8  as a component. 
     
     
       14. A contact adhesive, comprising the curable composition according to  claim 8  as a component. 
     
     
       15. The contact adhesive according to  claim 8 , comprising the polyether polymer (A) and the polyether polymer (B). 
     
     
       16. A cured product, obtained by curing the curable composition according to  claim 8 . 
     
     
       17. A contact adhesive, comprising the curable composition according to  claim 1  as a component. 
     
     
       18. The contact adhesive according to claim 17, comprising the polyether polymer (A) and the polyether polymer (B).