Non-petrochemically derived cationic emulsifiers that are neutralized amino acid esters and related compositions and methods

Abstract

The invention includes a method of increasing the substantivity of a personal care composition to hair, skin or nails by preparing a composition of an aqueous phase, a non-aqueous phase and a neutralized amino acid ester that is a reaction product of a neutral amino acid having a non-polar side chain with a long chain fatty alcohol and is represented by formula (I):wherein R1 is an alkyl group; R2 is a linear or branched carbon chain; and the amine group of the amino acid is neutralized with an acid. The composition is substantially free of petrochemicals and/or derivatives of petrochemical materials. The aqueous phase and the non-aqueous phase are emulsified by the neutralized amino acid ester. Other methods and an emulsifiers that is the neutralized amino acid ester are included. Because the neutralized amino acid ester and the compositions do not contain petrochemical-derived ingredient, the products are natural.

I claim: 
     
       1. A method of increasing the substantivity of a personal care composition to hair, skin or nails comprising:
 preparing a composition that comprises an aqueous phase, a non-aqueous phase and a neutralized amino acid ester that is a reaction product of a neutral amino acid having a non-polar side chain with a long chain fatty alcohol and is represented by formula (I): 
 
       
         
           
           
               
               
           
         
         wherein R 1  is a linear or branched alkyl group; 
         R 2  is a linear or branched carbon chain; and 
         the amine group of the amino acid is neutralized with an acid, and wherein the composition is substantially free of petrochemicals and/or derivatives of petrochemical materials, and the aqueous phase and the non-aqueous phase are emulsified by the neutralized amino acid ester; and
 applying the personal care composition to a surface of hair, skin or nails. 
 
       
     
     
       2. The method of  claim 1 , wherein R 1  of formula (I) is chosen from a branched alkyl and a linear alkyl group. 
     
     
       3. The method of  claim 1 , wherein R 1  of formula (I) is has 1 to 10 carbon atoms. 
     
     
       4. The method of  claim 1 , wherein the carbon chain of R 2  in formula (I) comprises at least one unsaturated carbon atom. 
     
     
       5. The method of  claim 1 , wherein R 2  of formula (I) is has 10 to 50 carbon atoms. 
     
     
       6. The method of  claim 1 , wherein the neutral amino acid is chosen from L-alanine, L-valine, L-leucine, and L-isoleucine. 
     
     
       7. The method of  claim 1 , wherein the neutral amino acid is L-isoleucine. 
     
     
       8. The method of  claim 1 , wherein the neutral amino acid is obtained from vegetable matter. 
     
     
       9. The method of  claim 1 , wherein the long chain fatty alcohol is chosen from the coconut fatty alcohol, capric alcohol, lauryl alcohol, myristyl alcohol, cetyl alcohol, stearyl alcohol, arachidyl alcohol, behenyl alcohol, lignoceryl alcohol, isostearyl alcohol, and/or mixtures thereof. 
     
     
       10. The method of  claim 1 , wherein the amine group of the amino acid is neutralized by an ethanesulfonic acid that is derived from an ethanol that is derived from fermentation of vegetable matter. 
     
     
       11. The method of  claim 1 , wherein the amine group of the amino acid is neutralized by an acid chosen from hydrochloric acid, phosphoric acid, sulfuric acid, boric acid, and nitric acid. 
     
     
       12. The method of  claim 1 , wherein the personal care composition further comprise at least one of a surfactant, a colorant, a pearlizing agent, an acrylate polymer, an antioxidant, an opacifying agent, mica, an oil, a lipid, a protein, a pH modifier, a vitamin, a fatty acid, a fatty alcohol, a humectant, and a conditioning agent. 
     
     
       13. The method of  claim 1 , wherein the composition is chosen from a hair detergent, shampoo, rinse, hair cream conditioner, conditioning shampoo, hair lotions, hair treatment, hair cream, hair spray, hair liquid, hair wax, hair-styling preparation, permanent wave liquids, hair colorant, acidic hair colorant, hair manicure, glaze, skin lotion, milky lotion, face wash, makeup remover, cleansing lotion, emollient lotion, nourishing cream, emollient cream, massage cream, cleansing cream, body shampoo, hand soap, bar soap, shaving creams, sunscreen, sunburn treatment, deodorants, makeup removing gel, moisture gel, moisture essence, UV exposure-preventing essence, shaving foam, face powder, foundation, lipstick, blush, eyeliner, wrinkle and anti-aging cream, eye shadow, eyebrow pencils, mascara, mouthwash, toothpaste, an oral care composition, a skin cleansing composition, a textile cleansing compositions, a dish cleaning composition, a hair or fur cleansing composition, a deodorant or antiperspirant, a cosmetic, a hair styling composition, a skin moisturizer, a skin conditioner, a hair conditioner and a nail conditioner. 
     
     
       14. A method of increasing the substantivity of a personal care composition to hair, skin or nails comprising: preparing a composition that comprises an aqueous phase, a non-aqueous phase and a neutralized amino acid ester that is a reaction product of one or more of L-alanine, L-valine, L-leucine, and L-isoleucine with a long chain fatty alcohol and is represented by formula (1): 
       
         
           
           
               
               
           
         
       
       wherein R 1  is a linear or branched alkyl group; R 2  is a linear or branched carbon chain; and the amine group of the amino acid is neutralized with an acid, and wherein the composition is substantially free of petrochemicals and/or derivatives of petrochemical materials, and the aqueous phase and the non-aqueous phase are emulsified by the neutralized amino acid ester; and applying the personal care composition to a surface of hair, skin or nails. 
     
     
       15. The method of claim 14, wherein the neutral amino acid is obtained from vegetable matter. 
     
     
       16. The method of claim 14, wherein the long chain fatty alcohol is chosen from Brassica alcohol, coconut fatty alcohol, capric alcohol, lauryl alcohol, myristyl alcohol, cetyl alcohol, stearyl alcohol, arachidyl alcohol, behenyl alcohol, lignoceryl alcohol, isostearyl alcohol, and/or mixtures thereof. 
     
     
       17. The method of claim 14, wherein the amine group of the amino acid is neutralized by an ethanesulfonic acid that is derived from an ethanol that is derived from fermentation of vegetable matter. 
     
     
       18. The method of claim 14, wherein the amine group of the amino acid is neutralized by an acid chosen from hydrochloric acid, phosphoric acid, sulfuric acid, boric acid, and nitric. 
     
     
       19. A method of preparing a personal care composition comprising preparing a composition that comprises an aqueous phase, a non-aqueous phase and a neutralized amino acid ester that is a reaction product of one or more of L-alanine, L-valine, L-leucine, and L-isoleucine with a long chain fatty alcohol and is represented by formula (I): 
       
         
           
           
               
               
           
         
       
       wherein R 1  is a linear or branched alkyl group; R 2  is a linear or branched carbon chain, wherein an amine group of the amino acid is neutralized with an acid, wherein the composition is substantially free of petrochemicals and/or derivatives of petrochemical materials, emulsifying the aqueous phase and the non-aqueous phase with the neutralized amino acid ester, and applying the personal care composition to a surface of hair, skin or nails. 
     
     
       20. The method of claim 19, wherein the neutral amino acid is obtained from vegetable matter. 
     
     
       21. The method of claim 19, wherein the long chain fatty alcohol is chosen from Brassica alcohol, coconut fatty alcohol, capric alcohol, lauryl alcohol, myristyl alcohol, cetyl alcohol, stearyl alcohol, arachidyl alcohol, behenyl alcohol, lignoceryl alcohol, isostearyl alcohol, and/or mixtures thereof. 
     
     
       22. The method of claim 19, wherein the amine group of the amino acid is neutralized by an ethanesulfonic acid that is derived from an ethanol that is derived from fermentation of vegetable matter. 
     
     
       23. The method of claim 19, wherein the amine group of the amino acid is neutralized by an acid chosen from hydrochloric acid, phosphoric acid, sulfuric acid, boric acid, and nitric.