Tank-mix formulations

Abstract

The invention relates to the use of additives in the preparation of crop protection composition spray mixtures, in particular as additives for tank mixtures of specific pesticides according to formula (I), pesticide mixtures and crop protection compositions comprising these pesticides.

The invention claimed is: 
     
       1. A pesticidal composition comprising a tetramic acid compound of the formula (I) 
       
         
           
           
               
               
           
         
       
       wherein
 X, Y and Z independently of each other are C 1-4 alkyl, C 3-6 cycloalkyl, C 1-4 haloalkyl, C 1-4 alkoxy, halogen, phenyl or phenyl substituted by C 1-4 alkyl, C 1-4 haloalkyl, halogen or cyano; 
 m and n, independently of each other, are 0, 1, 2 or 3 and m+n is 0, 1, 2 or 3; 
 G is hydrogen, a metal, ammonium, sulfonium or a latentiating group selected from the groups C 1 -C 8 alkyl, C 2 -C 8 haloalkyl, phenyl 1 -C 8 alkyl (wherein the phenyl may optionally be substituted by C 1 -C 3 alkyl, C 1 -C 3 haloalkyl, C 1 -C 3 alkoxy, C 1 -C 3 haloalkoxy, C 1 -C 3 alkylthio, C 1 -C 3 alkylsulfinyl, C 1 -C 3 alkylsulfonyl, halogen, cyano or by nitro), heteroarylC 1 -C 8 alkyl (wherein the heteroaryl may optionally be substituted by C 1 -C 3 alkyl, C 1 -C 3 haloalkyl, C 1 -C 3 alkoxy, C 1 -C 3 haloalkoxy, C 1 -C 3 alkylthio, C 1 -C 3 alkylsulfinyl, C 1 -C 3  alkylsulfonyl, halogen, cyano or by nitro), C 3 -C 8 alkenyl, C 3 -C 8 haloalkenyl, C 3 -C 8 alkynyl, C(X a )—R a , C(X b )—X c —R b , C(X d )—N(R c )—R d , —SO 2 —R e , P(X e )(R f )—R g  or CH 2 —X f —R h  wherein X a , X b , X c , X d , X e  and X f  are independently of each other oxygen or sulfur; 
 R a  is H, C 1 -C 18 alkyl, C 2 -C 18 alkenyl, C 2 -C 18 alkynyl, C 1 -C 10 haloalkyl, C 1 -C 10 cyanoalkyl, C 1 -C 10 nitroalkyl, C 1 -C 10 aminoalkyl , C 1 -C 5 alkylaminoC 1 -C 5 alkyl, C 2 -C 8 dialkylaminoC 1 -C 5 alkyl, C 3 -C 7 cycloalkylC 1 -C 5 alkyl, C 1 -C 5 alkoxyC 1 -C 5 alkyl, C 3 -C 5 alkenyloxyC 1 -C 5 alkyl, C 3 -C 5 alkynylC 1 -C 5 oxyalkyl, C 1 -C 5 alkylthioC 1 -C 5 alkyl, C 1 -C 5 alkylsulfinylC 1 -C 5 alkyl, C 1 -C 5 alkylsulfonylC 1 -C 5 alkyl, C 2 -C 8 alkylideneaminoxyC 1 -C 5 alkyl, C 1 -C 5 alkylcarbonylC 1 -C 5 alkyl, C 1 -C 5 alkoxycarbonylC 1 -C 5 alkyl, aminocarbonylC 1 -C 5 alkyl, C 1 -C 5 alkylaminocarbonylC 1 -C 5 alkyl, C 2 -C 8 dialkylaminocarbonylC 1 -C 5 alkyl, C 1 -C 5 alkylcarbonylaminoC 1 -C 5 alkyl, N—C 1 C 5 alkylcarbonyl-N—C 1 C 5 alkylaminoC 1 -C 5 alkyl, C 3 -C 6 trialkylsilylC 1 -C 5 alkyl, phenylC 1 -C 5 alkyl (wherein the phenyl may optionally be substituted by C 1 -C 3 alkyl, C 1 -C 3 haloalkyl, C 1 -C 3 alkoxy, C 1 -C 3 haloalkoxy, C 1 -C 3 alkylthio, C 1 -C 3 alkylsulfinyl, C 1 -C 3 alkylsulfonyl, halogen, cyano, or by nitro), heteroarylC 1 -C 5 alkyl, (wherein the heteroaryl may optionally be substituted by C 1 -C 3 alkyl, C 1 -C 3 haloalkyl, C 1 -C 3 alkoxy, C 1 -C 3 haloalkoxy, C 1 -C 3 alkylthio, C 1 -C 3 ,alkylsulfinyl, C 1 -C 3 alkylsulfonyl, halogen, cyano, or by nitro), C 2 -C 5 haloalkenyl, C 3 -C 8 cycloalkyl, phenyl or phenyl substituted by C 1 -C 3 alkyl, C 1 -C 3 haloalkyl, C 1 -C 3 alkoxy, C 1 -C 3 haloalkoxy, halogen, cyano or nitro, heteroaryl or heteroaryl substituted by C 1 -C 3  alkyl, C 1 -C 3 haloalkyl, C 1 -C 3 alkoxy, C 1 -C 3 haloalkoxy, halogen, cyano or nitro, 
 R b  is C 1 -C 18 alkyl, C 3 -C 18 alkenyl, C 3 -C 18 alkynyl, C 2  -C 10 haloalkyl, C 1 -C 5 cyanoalkyl, C 1 -C 10 nitroalkyl, C 2  -C 10 aminoalkyl , C 1 -C 5 alkylaminoC 1 -C 5 alkyl, C 2 -C 8 dialkylaminoC 1 -C 5 alkyl, C 3 -C 7 cycloalkylC 1 -C 5 alkyl, C 1 -C 5 alkoxyC 1 -C 5 alkyl, C 3 -C 5 alkenyloxyC 1 -C 5 alkyl, C 3 -C 5 alkynyloxyC 1 -C 5 alkyl, C 1 -C 5 alkylthioC 1 -C 5 alkyl, C 1 -C 5 alkylsulfinylC 1 -C 5 alkyl, C 1 -C 5 alkylsulfonylC 1 -C 5 alkyl, C 2 -C 8 alkylideneaminoxyC 1 -C 5 alkyl, C 1 -C 5 alkylcarbonylC 1 -C 5 alkyl, C 1 -C 5 alkoxycarbonylC 1 -C 5 alkyl, aminocarbonylC 1 -C 5 alkyl, C 1 -C 5 alkylaminocarbonylC 1 -C 5 alkyl, C 2 -C 8 dialkylaminocarbonylC 1 -C 5 alkyl, C 1 -C 5 alkylcarbonylaminoC 1 -C 5 alkyl, N—C 1 -C 5 alkylcarbonyl-N—C 1 -C 5 alkylaminoC 1 -C 5 alkyl, C 3 -C 6 trialkylsilylC 1 -C 5 alkyl, phenylC 1 -C 5 alkyl (wherein the phenyl may optionally be substituted by C 1 -C 3 alkyl, C 1 -C 3 haloalkyl, C 1 -C 3 alkoxy, C 1 -C 3 haloalkoxy, C 1 -C 3 alkylthio, C 1 -C 3 alkylsulfinyl, C 1 -C 3 alkylsulfonyl, halogen, cyano, or by nitro), heteroarylC 1 -C 5 alkyl, (wherein the heteroaryl may optionally be substituted by C 1 -C 3 alkyl, C 1 -C 3 haloalkyl, C 1 -C 3 alkoxy, C 1 -C 3 haloalkoxy, C 1 -C 3 alkyl-thio, C 1 -C 3 alkylsulfinyl, C 1 -C 3 alkylsulfonyl, halogen, cyano, or by nitro), C 3 -C 5 haloalkenyl, C 3 -C 8 cycloalkyl, phenyl or phenyl substituted by C 1 -C 3 alkyl, C 1 -C 3 haloalkyl, C 1 -C 3 alkoxy, C 1 -C 3 haloalkoxy, halogen, cyano or nitro, heteroaryl or heteroaryl substituted by C 1 -C 3  alkyl, C 1 - 3 haloalkyl, C 1 -C 3 alkoxy, C 1 -C 3 haloalkoxy, halogen, cyano or nitro, 
 R c  and R d  are each independently of each other hydrogen, C 1 -C 10 alkyl, C 3 -C 10 alkenyl, C 3 -C 10 alkynyl, C 2 -C 10 haloalkyl, C 1 -C 10 cyanoalkyl, C 1 -C 10 nitroalkyl, C 1 -C 10 aminoalkyl, C 1 -C 5 alkylaminoC 1 C 5 alkyl, C 2 -C 8 dialkylaminoC 1 -C 5 alkyl, C 3 -C 7 cycloalkylC 1 -C 5 alkyl, C 1 -C 5 alkoxyC 1 -C 5 alkyl, C 3 -C 5 alkenyloxyC 1 -C 5 alkyl, C 3 -C 5 alkynyloxyC 1 -C 5 alkyl, C 1 -C 5 alkylthioC 1 -C 5 alkyl, C 1 -C 5 alkylsulfinylC 1 -C 5 alkyl, C 1 -C 5 alkylsulfonylC 1 -C 5 alkyl, C 2 -C 8 alkylideneaminoxyC 1 -C 5 alkyl, C 1 -C 5 alkylcarbonylC 1 -C 5 alkyl, C 1 -C 5 alkoxycarbonylC 1 -C 5 alkyl, aminocarbonylC 1 -C 5 alkyl, C 1 -C 5 alkylaminocarbonylC 1 -C 5 alkyl, C 2 -C 8 dialkylaminocarbonylC 1 -C 5 alkyl, C 1 -C 5 alkylcarbonylaminoC 1 -C 5 alkyl, N—C 1 -C 5 alkylcarbonyl-N—C 2 -C 5 alkylaminoalkyl, C 3 -C 6 trialkylsilylC 1 -C 5 alkyl, phenylC 1 -C 5 alkyl (wherein the phenyl may optionally be substituted by C 1 -C 3 alkyl, C 1 -C 3 haloalkyl, C 1 -C 3 alkoxy, C 1 -C 3 haloalkoxy, C 1 -C 3 alkylthio, C 1 -C 3 alkylsulfinyl, C 1 -C 3 alkylsulfonyl, halogen, cyano, or by nitro), heteroarylC 1 -C 5 alkyl, (wherein the heteroaryl may optionally be substituted by C 1 -C 3 alkyl, C 1 -C 3 haloalkyl, C 1 -C 3 alkoxy, C 1 -C 3 haloalkoxy, C 1 -C 3 alkylthio, C 1 -C 3 alkylsulfinyl, C 1 -C 3 alkylsulfonyl, halogen, cyano, or by nitro), C 2 -C 5 haloalkenyl, C 3 -C 8 cycloalkyl, phenyl or phenyl substituted by C 1 -C 3 alkyl, C 1 -C 3 haloalkyl, C 1 -C 3 alkoxy, C 1 -C 3 haloalkoxy, halogen, cyano or nitro, heteroaryl or heteroaryl substituted by C 1 -C 3 alkyl, C 1 -C 3 haloalkyl, C 1 -C 3 alkoxy, C 1 -C 3 haloalkoxy, halogen, cyano or nitro, heteroarylamino or heteroarylamino substituted by C 1 -C 3 alkyl, C 1 -C 3 haloalkyl, C 1 -C 3 alkoxy, C 1 -C 3 haloalkoxy, halogen, cyano or nitro, diheteroarylamino or diheteroarylamino substituted by C 1 -C 3 alkyl, C 1 -C 3 haloalkyl, C 1 -C 3 alkoxy, C 1 -C 3 haloalkoxy, halogen, cyano or nitro, phenylamino or phenylamino substituted by C 1 -C 3 alkyl, C 1 -C 3 haloalkyl, C 1 -C 3 alkoxy, C 1 -C 3 haloalkoxy, halogen, cyano or by nitro, diphenylamino or diphenylamino substituted by C 1 -C 3 alkyl, C 1 -C 3 haloalkyl, C 1 -C 3 alkoxy, C 1 -C 3 haloalkoxy, halogen, cyano or by nitro or C 3 -C 7 cycloalkylamino, di-C 3 -C 7 cycloalkylamino or C 3 -C 7 cycloalkoxy or R c  and R d  may join together to form a 3-7 membered ring, optionally containing one heteroatom selected from O or S, 
 R e  is C 1 -C 10 alkyl, C 2 -C 10 alkenyl, C 2 -C 10 alkynyl, C 1 -C 10 haloalkyl, C 1 -C 10 cyanoalkyl, C 1 -C 10 nitroalkyl, C 1 -C 10 aminoalkyl, C 1 -C 5 alkylaminoC 1 -C 5 alkyl, C 2 -C 8 dialkylaminoC 1 -C 5 alkyl, C 3 -C 7 cycloalkylC 1 -C 5 alkyl, C 1 -C 5 alkoxyC 1 -C 5 alkyl, C 3 -C 5 alkenyloxyC 1 -C 5 alkyl, C 3 -C 5 alkynyloxyC 1 -C 5 alkyl, C 1 -C 5 alkylthioC 1 -C 5 alkyl, C 1 -C 5 alkylsulfinylC 1 -C 5 alkyl, C 1 -C 5 alkylsulfonylC 1 -C 5 alkyl, C 2 -C 8 alkylideneaminoxyC 1 -C 5 alkyl, C 1 -C 5 alkylcarbonylC 1 -C 5 alkyl, C 1 -C 5 alkoxycarbonylC 1 -C 5 alkyl, aminocarbonylC 1 -C 5 alkyl, C 1 -C 5 alkylaminocarbonylC 1 -C 5 alkyl, C 2 -C 8 dialkylaminocarbonylC 1 -C 5 alkyl, C 1 -C 5 alkylcarbonylaminoC 1 -C 5 alkyl, N—C 1 -C 5 alkylcarbonyl-N—C 1 -C 5 alkylaminoC 1 -C 5 alkyl, C 3 -C 6 trialkylsilylC 1 -C 5 alkyl, phenylC 1 -C 5 alkyl (wherein the phenyl may optionally be substituted by C 1 -C 3 alkyl, C 1 -C 3 haloalkyl, C 1 -C 3 alkoxy, C 1 -C 3 haloalkoxy, C 1 - 3 alkylthio, C 1 -C 3 alkylsulfinyl, C 1 -C 3 alkylsulfonyl, halogen, cyano, or by nitro), heteroarylC 1 -C 5 alkyl (wherein the heteroaryl may optionally be substituted by C 1 -C 3 alkyl, C 1 -C 3 haloalkyl, C 1 -C 3 alkoxy, C 1 -C 3 haloalkoxy, C 1 -C 3 alkylthio, C 1 -C 3 alkylsulfinyl, C 1 -C 3 alkylsulfonyl, halogen, cyano, or by nitro), C 2 -C 5 haloalkenyl, C 3 -C 8 cycloalkyl, phenyl or phenyl substituted by C 1 -C 3 alkyl, C 1 -C 3 haloalkyl, C 1 -C 3 alkoxy, C 1 -C 3 haloalkoxy, halogen, cyano or nitro, heteroaryl or heteroaryl substituted by C 1 -C 3  alkyl, C 1 -C 3 haloalkyl, C 1 -C 3 alkoxy, C 1 -C 3 haloalkoxy, halogen, cyano or by nitro, heteroarylamino or heteroarylamino substituted by C 1 -C 3  alkyl, C 1 -C 3 haloalkyl, C 1 -C 3 alkoxy, C 1 -C 3 haloalkoxy, halogen, cyano or by nitro, diheteroarylamino or diheteroarylamino substituted by C 1 -C 3  alkyl, C 1 -C 3 haloalkyl, C 1 -C 3 alkoxy, C 1 -C 3 haloalkoxy, halogen, cyano or nitro, phenylamino or phenylamino substituted by C 1 -C 3 alkyl, C 1 -C 3 haloalkyl, C 1 -C 3 alkoxy, C 1 -C 3 haloalkoxy, halogen, cyano or nitro, diphenylamino, or diphenylamino substituted by C 1 -C 3 alkyl, C 1 -C 3 haloalkyl, C 1 -C 3 alkoxy, C 1 -C 3 haloalkoxy, halogen, cyano or nitro, or C 3 -C 7 cycloalkylamino, diC 3 -C 7 cycloalkylamino or C 3 -C 7 cycloalkoxy, C 1 -C 10 alkoxy, C 1 -C 10 haloalkoxy, C 1 -C 5 alkylamino or C 2 -C 8 dialkylamino 
 R f  and R g  are are each independently of each other C 1 -C 10 alkyl, C 2 -C 10 alkenyl, C 2 -C 10 alkynyl, C 1 -C 10 alkoxy, C 1 -C 10 haloalkyl, C 1 -C 10 cyanoalkyl, C 1 -C 10 nitroalkyl, C 1 -C 10 aminoalkyl , C 1 -C 5 alkylaminoC 1 -C 5 alkyl, C 2 -C 8 dialkylaminoC 1 -C 5 alkyl, C 3 -C 7 cycloalkylC 1 -C 5 alkyl, C 1 -C 5 alkoxy, C 1 -C 5 alkyl, C 3 -C 5 alkenyloxyC 1 -C 5 alkyl, C 3 -C 5 alkynyloxyC 1 -C 5 alkyl, C 1 -C 5 alkylthioC 1 -C 5 alkyl, C 1 -C 5 alkylsulfinylC 1 -C 5 alkyl, C 1 -C 5 alkylsulfonylC 1 -C 5 alkyl, C 2 -C 8 alkylideneaminoxyC 1 -C 5 alkyl, C 1 -C 5 alkylcarbonylC 1 -C 5 alkyl, C 1 -C 5 alkoxycarbonylC 1 -C 5 alkyl, aminocarbonylC 1 -C 5 alkyl, C 1 -C 5 alkylaminocarbonylC 1 -C 5 alkyl, C 2 -C 8 dialkylaminocarbonylC 1 -C 5 alkyl, C 1 -C 5 alkylcarbonylaminoC 1 -C 5 alkyl, N—C 1 -C 5 alkylcarbonyl-N—C 2 -C 5 alkylaminoalkyl, C 3 -C 6 trialkylsilylC 1 -C 5 alkyl, phenylC 1 -C 5 alkyl (wherein the phenyl may optionally be substituted by C 1 -C 3 alkyl, C 1 -C 3 haloalkyl, C 1 -C 3 alkoxy, C 1 -C 3 haloalkoxy, C 1 -C 3 alkylthio, C 1 -C 3 alkylsulfinyl, C 1 -C 3 alkylsulfonyl, halogen, cyano, or by nitro), heteroarylC 1 -C 5 alkyl (wherein the heteroaryl may optionally be substituted by C 1 -C 3 alkyl, C 1 -C 3 haloalkyl, C 1 -C 3 alkoxy, C 1 -C 3 haloalkoxy, C 1 -C 3 alkylthio, C 1 -C 3 alkylsulfinyl, C 1 -C 3 alkylsulfonyl, halogen, cyano, or by nitro), C 2 -C 5 haloalkenyl, C 3 -C 8 cycloalkyl, phenyl or phenyl substituted by C 1 -C 3 alkyl, C 1 -C 3 haloalkyl, C 1 -C 3 alkoxy, C 1 -C 3 haloalkoxy, halogen, cyano or nitro, heteroaryl or heteroaryl substituted by C 1 -C 3  alkyl, C 1 -C 3 haloalkyl, C 1 -C 3 alkoxy, C 1 -C 3 haloalkoxy, halogen, cyano or by nitro, heteroarylamino or heteroarylamino substituted by C 1 -C 3 alkyl, C 1 -C 3 haloalkyl, C 1 -C 3 alkoxy, C 1 -C 3 haloalkoxy, halogen, cyano or by nitro, diheteroarylamino or diheteroarylamino substituted by C 1 -C 3  alkyl, C 1 -C 3 haloalkyl, C 1 -C 3 alkoxy, C 1 -C 3 haloalkoxy, halogen, cyano or nitro, phenylamino or phenylamino substituted by C 1 -C 3 alkyl, C 1 -C 3 haloalkyl, C 1 -C 3 alkoxy, C 1 -C 3 haloalkoxy, halogen, cyano or nitro, diphenylamino, or diphenylamino substituted by C 1 -C 3 alkyl, C 1 -C 3 haloalkyl, C 1 -C 3 alkoxy, C 1 -C 3 haloalkoxy, halogen, cyano or nitro, or C 3 -C 7 cycloalkylamino, diC 3 -C 7 cycloalkylamino or C 3 -C 7 cycloalkoxy, C 1 -C 10 haloalkoxy, C 1 -C 5 alkylamino or C 2 -C 8 dialkylamino, benzyloxy or phenoxy, wherein the benzyl and phenyl groups may in turn be substituted by C 1 -C 3 alkyl, C 1 -C 3 haloalkyl, C 1 -C 3 alkoxy, C 1 -C 3 haloalkoxy, halogen, cyano or nitro, and 
 R h  is C 1 -C 10 alkyl, C 3 -C 10 alkenyl, C 3 -C 10 alkynyl, C 1 -C 10 haloalkyl, C 1 -C 10 cyanoalkyl, C 1 -C 10 nitroalkyl , C 2 -C 10 aminoalkyl, C 1 -C 5 alkylaminoC 1 -C 5 alkyl, C 2 -C 8 dialkylaminoC 1 -C 5 alkyl, C 3 -C 7 cycloalkylC 1 -C 5 alkyl, C 1 -C 5 alkoxyC 1 -C 5 alkyl, C 3 -C 5 alkenyloxyC 1 -C 5 alkyl, C 3 -C 5 alkynyloxyC 1 -C 5 alkyl, C 1 -C 5 alkylthioC 1 -C 5 alkyl, C 1 -C 5 alkylsulfinylC 1 -C 5 alkyl, C 1 -C 5 alkylsulfonylC 1 -C 5 alkyl, C 2 -C 8 alkylideneaminoxyC 1 -C 5 alkyl, C 1 -C 5 alkylcarbonylC 1 -C 5 alkyl, C 1 -C 5 alkoxycarbonylC 1 -C 5 alkyl, aminocarbonylC 1 -C 5 alkyl, C 1 -C 5 alkylaminocarbonylC 1 -C 5 alkyl, C 2 -C 8 dialkylaminocarbonylC 1 -C 5 alkyl, C 1 -C 5 alkylcarbonylaminoC 1 -C 5 alkyl, N—C 1 -C 5 alkylcarbonyl-N—C 1 -C 5 alkylaminoC 1 -C 5 alkyl, C 3 -C 6 trialkylsilylC 1 -C 5 alkyl, phenylC 1 -C 5 alkyl (wherein wherein the phenyl may optionally be substituted by C 1 -C 3 alkyl, C 1 -C 3 haloalkyl, C 1 -C 3 alkoxy, C 1 -C 3 haloalkoxy, C 1 -C 3 alkylthio , C 1 -C 3 alkylsulfinyl, C 1 -C 3  alkylsulfonyl, halogen, cyano or by nitro), heteroarylC 1 -C 5 alkyl (wherein the heteroaryl may optionally be substituted by C 1 -C 3 alkyl, C 1 -C 3 haloalkyl, C 1 -C 3 alkoxy, C 1 -C 3 haloalkoxy, C 1  -C, alkylthio , C 1 -C 3 alkylsulfinyl, C 1 -C 3  alkylsulfonyl, halogen, cyano or by nitro), phenoxyC l -C 5 alkyl (wherein wherein the phenyl may optionally be substituted by C 1 -C 3 alkyl, C 1 -C 3 haloalkyl, C 1 -C 3 alkoxy, C 1 -C 3 haloalkoxy, C 1 -C 3 alkylthio, C 1 -C 3 alkylsulfinyl, C 1 -C 3  alkylsulfonyl, halogen, cyano or by nitro), heteroaryloxyC 1 -C 5 alkyl (wherein the heteroaryl may optionally be substituted by C 1 -C 3 alkyl, C 1 -C 3 haloalkyl, C 1 -C 3 alkoxy, C 1 -C 3 haloalkoxy, C 1 -C 3 alkylthio, C 1 -C 3 akylsulfinyl, C 1 -C 3  alkylsulfonyl, halogen, cyano or by nitro), C 3 -C 5 -haloalkenyl, C 1 -C 8 cycloalkyl, phenyl or phenyl substituted by C 1 -C 3 alkyl, C 1 -C 3 haloalkyl, C 1 -C 3 alkoxy, C 1 -C 3 haloalkoxy, halogen or by nitro, or heteroaryl, or heteroaryl substituted by C 1 -C 3 alkyl, C 1 -C 3 haloalkyl, C 1 -C 3 alkoxy, C 1 -C 3 haloalkoxy, halogen, cyano or by nitro. 
 R is hydrogen, C 1-6 alkyl, C 1-6 haloalkyl, C 1-6 cyanoalkyl, benzyl, C 1-4 alkoxy(C 1-4 )alkyl, C 1-4 alkoxy(C 1-4 )alkoxy (C 1-4 )alkyl or a group selected from G; and 
 A is hydrogen, C 1-6 alkyl, C 1-6 haloalkyl, C 3-6 cycloalkyl, C 3-6 cycloalkyl(C 1-4 )alkyl, or C 3-6 cycloalkyl(C 1-4 )alkyl where in the cycloalkyl moiety a methylene group is replaced by O, S or NR 0 , where R 0  is C 1-6 alkyl or C 1-6 alkoxy, or A is C 2-6 alkenyl,C 2-6 haloalkenyl, C 3-6 alkynyl, C 1-4 cyanoalkyl, benzyl, C 1-4 alkoxy(C 1-4 ) alkyl, C 1-4 alkoxy (C 1-4 )alkoxy(C 1-4 )alkyl, oxetanyl, tetrahydrofuranyl, tetrahydropyranyl, C 1-6 alkylcarbonyl, C 1-6 alkoxycarbonyl, C 3-6 cycloalkylcarbonyl, N-di (C 1-6 alkyl)carbamoyl, benzoyl, C 1-6 alkylsulfonyl, phenylsulfonyl, C 1-4 alkylthio(C 1-4 )alkyl, C 1-4 alkylsulfinyl (C 1-4 )alkyl or C 1-4 alkylsulfonyl (C 1-4 )alkyl; 
 or A is O-A 1  wherein A 1  is selected from one of A, as defined above, or furanyl -(C 1-4 )alkyl, tetrahydro-thiofuranyl, tetrahydro-thiopyranyl or 1-(C 1-4 )alkoxy-piperidin-4-yl, 
 or an agrochemically acceptable salt or an N-oxide of formula (I); 
 and a tank-mix adjuvant selected from the group consisting of polysiloxane(s), sodium dioctylsulphosuccinate, isodecyl alcohol ethoxylate, and mixtures thereof. 
 
     
     
       2. The composition according to  claim 1  wherein the compound of formula (I) is selected from compounds wherein R is methyl, X is methyl or methoxy, Y and Z, independently of each other, are methyl, ethyl, methoxy, chloro or bromo, G is hydrogen, methoxycarbonyl or propenyloxycarbonyl or —(C═O)OCH 2 CH 3 , and A is hydrogen, methyl, ethyl, methoxy, ethoxy, methoxymethyl, tetrahydrofuran-2-yl or tetrahydrofuran-3-yl. 
     
     
       3. The composition according to  claim 1  wherein the compound of formula (I) is selected from compounds wherein m is 1 and n is 1 and Y is in the ortho position and Z is in the para position. 
     
     
       4. The composition according to  claim 1  wherein the compound of formula (I) is selected from one or more of 
       
         
           
           
               
               
           
         
         
           
           
               
               
           
         
         
           
           
               
               
           
         
         wherein G is 
       
       
         
           
           
               
               
           
         
         or H. 
       
     
     
       5. The composition according to  claim 1  wherein the compound according to formula (I) is formulated as a suspension concentrate, emulsion concentrate, wettable powder, water dispersible granule, soluble liquid, emulsion in water, oil dispersion, soluble granule or soluble powder. 
     
     
       6. The composition according to  claim 1  wherein the adjuvant is a polysiloxane selected according to formula (II) 
       
         
           
           
               
               
           
         
         wherein 
         z is 0 or 1 
         x is a number from 0 to 100 
         y is 0 or greater 
         R′ is R or an alkyl radical having 1 to 8 carbon atoms or a hydrogen atom 
         R is C n H 2n O(C e H 2e O) p K or Si n R1 2n O(Si e R1 2e O) p K 
         R1 are independently alkyl, alkenyl or alkynyl radicals having 1 to 4 carbon atoms or aryl radicals 
         n is 1, 2, 3, 4 or greater 
         e is 1, 2, 3, 4 or greater 
         p is 0 or greater 
         K is H, an alkyl radical having at most 4 carbon atoms or SiR1 2 R2, wherein R2 is hydrogen or an alkyl radical having at most 4 carbon atoms. 
       
     
     
       7. The composition according to  claim 1  wherein the adjuvant is a polysiloxane selected according to formula (II′) 
       
         
           
           
               
               
           
         
         wherein 
         z is 0 or 1 
         x is a number from 0 to 100 
         y is 0 or greater 
         R′ is R or an alkyl radical having 1 to 8 carbon atoms or a hydrogen atom 
         R is C n H 2n O(C e H 2e O) p K 
         n is 3 or 4 
         e is 2, 3 or 4 
         p is 3 or greater 
         K is H or an alkyl radical having at most 4 carbon atoms. 
       
     
     
       8. A combination pack comprising a combination of a compound according to formula (I) as defined in  claim 1  and an adjuvant selected from the group consisting of polysiloxane(s), sodium dioctylsulphosuccinate, isodecyl alcohol ethoxylate, and mixtures thereof, wherein a first container contains the compound according to formula (I) and a second container contains the said adjuvant. 
     
     
       9. The combination pack according to  claim 8  wherein the adjuvant is a polysiloxane selected according to formula (II) 
       
         
           
           
               
               
           
         
         wherein 
         z is 0 or 1 
         x is a number from 0 to 100 
         y is 0 or greater 
         R′ is R or an alkyl radical having 1 to 8 carbon atoms or a hydrogen atom 
         R is C n H 2n O(C e H 2e O) p K or Si n R1 2n O(Si e R1 2e O) p K 
         R1 are independently alkyl, alkenyl or alkynyl radicals having 1 to 4 carbon atoms or aryl radicals 
         n is 1, 2, 3, 4 or greater 
         e is 1, 2, 3, 4 or greater 
         p is 0 or gr 
         K is H, an alkyl radical having at most 4 carbon atoms or SiR1 2 R2, wherein R2 is hydrogen or an alkyl radical having at most 4 carbon atoms. 
       
     
     
       10. The combination pack according to  claim 9  wherein the adjuvant is a polysiloxane is selected according to formula (II′) 
       
         
           
           
               
               
           
         
         wherein 
         z is 0 or 1 
         x is a number from 0 to 100 
         y is 0 or greater 
         R′ is R or an alkyl radical having 1 to 8 carbon atoms or a hydrogen atom 
         R is C n H 2n O(C e H 2e O) p K 
         n is 3 or 4 
         e is 2, 3 or 4 
         p is 3 or greater 
         K is H or an alkyl radical having at most 4 carbon atoms. 
       
     
     
       11. A pesticidal composition comprising a tetramic acid compound of the formula (I): 
       
         
           
           
               
               
           
         
         wherein G is 
       
       
         
           
           
               
               
           
         
         or H; 
         or an agrochemically acceptable salt or an N-oxide of formula (I); 
         and a tank-mix adjuvant selected from one or more of: polysiloxane(s), sodium dioctylsulphosuccinate, and isodecyl alcohol ethoxylate.  
       
     
     
       12. The composition according to claim 11, wherein G is 
       
         
           
           
               
               
           
         
        
       
     
     
       13. The composition according to claim 11, wherein the compound according to formula (I) is formulated as a suspension concentrate, emulsion concentrate, wettable powder, water dispersible granule, soluble liquid, emulsion in water, oil dispersion, soluble granule or soluble powder.  
     
     
       14. The composition according to claim 11, wherein the adjuvant is a polysiloxane selected according to formula (II) 
       
         
           
           
               
               
           
         
         wherein 
         z is 0 or 1; 
         x is a number from 0 to 100; 
         y is 0 or greater; 
         R′ is R or an alkyl radical having 1 to 8 carbon atoms or a hydrogen atom; 
         R is C n H 2n O(C e H 2e O) p K or Si e R1 2n O(Si e R1 2n O) p K; 
         R1 are independently alkyl, alkenyl or alkynyl radicals having 1 to 4 carbon atoms or aryl radicals; 
         n is 1, 2, 3, 4 or greater; 
         e is 1, 2, 3, 4 or greater; 
         p is 0 or greater; 
         K is H, an alkyl radical having at most 4 carbon atoms or SiR1 2 R2, wherein R2 is hydrogen or an alkyl radical having at most 4 carbon atoms.  
       
     
     
       15. A combination pack comprising a combination of a compound according to formula (I) as defined in claim 11 and an adjuvant selected from one or more polysiloxane(s), sodium dioctylsulphosuccinate, and isodecyl alcohol ethoxylate;
 wherein a first container contains the compound according to formula (I) and a second container contains said adjuvant.    
     
     
       16. The combination pack according to claim 15, wherein the adjuvant is a polysiloxane according to formula (II) 
       
         
           
           
               
               
           
         
         wherein 
         z is 0 or 1; 
         x is a number from 0 to 100; 
         y is 0 or greater; 
         R′ is R or an alkyl radical having 1 to 8 carbon atoms or a hydrogen atom; 
         R is C n H 2n O(C e H 2e O) p K or Si n R1 2n O(Si e R1 2e O) p K; 
         R1 are independently alkyl, alkenyl or alkynyl radicals having 1 to 4 carbon atoms or aryl radicals; 
         n is 1, 2, 3, 4 or greater; 
         e is 1, 2, 3, 4 or greater; 
         p is 0 or greater; and 
         K is H, an alkyl radical having at most 4 carbon atoms or SiR1 2 R2, wherein R2 is hydrogen or an alkyl radical having at most 4 carbon atoms.