Cyclodextrin compositions, articles, and methods

Abstract

Cyclodextrin compositions including one or more radiation polymerizable monomers and a cyclodextrin inclusion complex, the cyclodextrin inclusion complex including a cyclodextrin compound and an olefinic inhibitor of an ethylene generation in produce, are coated onto packaging materials and cured. Treated containers and treated package inserts having the cured cyclodextrin compositions are useful in packaging of respiring plant materials.

What is claimed is: 
     
       1. A method of treating one or more items of produce, the method comprising
 a. forming a cyclodextrin composition comprising one or more radiation polymerizable monomers and a cyclodextrin inclusion complex, the cyclodextrin inclusion complex comprising α-cyclodextrin and 1-methylcyclopropene; 
 b. disposing the cyclodextrin composition onto at least a portion of one surface of a packaging material or onto produce; 
 c. irradiating the disposed cyclodextrin composition to form a treated packaging material, the treated packaging material comprising a cured cyclodextrin composition; 
 d. placing the treated packaging material proximal to one or more items of produce; and 
 e.d. exposing the treated packaging materialcured cyclodextrin composition to an activating amount of water. 
 
     
     
       2. The method of  claim 1  wherein the forming comprises combining the one or more radiation polymerizable monomers with between 0.01 wt % and 10 wt % of the cyclodextrin inclusion complex based on the weight of the cyclodextrin composition. 
     
     
       3. The method of  claim 1  wherein the disposing is die coating, curtain coating, flood coating, gap coating, notch bar coating, wrapped wire bar drawdown coating, dip coating, brush coating, spray coating, rotogravure coating, flexographic printing, inkjet printing, lithographic printing, or letterset printing. 
     
     
       4. The method of  claim 1  wherein the disposing comprises coating a thickness of about 0.01 micron to 1 millimeter. 
     
     
       5. The method of  claim 1  wherein the disposing comprises selecting an amount of cyclodextrin composition to provide a concentration of 1-methylcyclopropene of about 2.5 ppb to 10 ppm within an enclosed volume surrounding the one or more items of produce. 
     
     
       6. The method of  claim 1  wherein the irradiating comprises irradiating with electron beam radiation or UV radiation. 
     
     
       7. The method of  claim 1  wherein the placing proximal to one or more items of produce is, wherein the cyclodextrin composition is disposed onto the at least the portion of the one surface of the packaging material and the irradiating forms a treated packaging material comprising the cured cyclodextrin composition, and the method comprises contacting the treated packaging material with a container, wherein the container encloses the one or more items of produce. 
     
     
       8. The method of  claim 7  wherein the container comprises a bag; a box; a carton; a pallet; a punnet; or a bag enclosing a pallet of boxes or punnets. 
     
     
       9. The method of  claim 7  further comprising forming a treated package insert comprising the treated packaging material, wherein the placing proximal to one or more items of produce is disposing the package insert in the container. 
     
     
       10. The method of  claim 7  wherein the placing proximal to one or more items of produce is, wherein the cyclodextrin composition is disposed onto the at least the portion of the one surface of the packaging material and the irradiating forms a treated packaging material comprising the cured cyclodextrin composition, and the method comprises contacting the exterior of the container with the treated packaging material, further wherein the container is permeable to water vapor, 1-methylcyclopropene, or both. 
     
     
       11. The method of  claim 7  further comprising storing the container at a temperature of about 0° C. to 20° C. 
     
     
       12. The method of  claim 7  wherein the container is a bag; a box; a carton; a pallet; a punnet; a bag enclosing a pallet of boxes or punnets; or a truck, a boat, or plane having a sealed or controlled environment for transport of produce. 
     
     
       13. The method of  claim 7  wherein the container further comprises a modified atmosphere, an equilibrium modified atmosphere, or a controlled atmosphere. 
     
     
       14. The method of  claim 1  further comprising, wherein the cyclodextrin composition is disposed onto the at least the portion of the one surface of the packaging material and the irradiating forms a treated packaging material comprising the cured cyclodextrin composition, and the method comprises forming a container from the treated packaging material, wherein the placing proximal to one or more items of produce is and enclosing the one or more items of produce in the container. 
     
     
       15. The method of  claim 1  wherein an activating amount of water is released by respiration of the one or more items of produce. 
     
     
       16. The method of  claim 1 , wherein the cyclodextrin composition is disposed onto the at least the portion of the one surface of the packaging material and the irradiating forms a treated packaging material comprising the cured cyclodextrin composition, wherein the packaging material is a first packaging material, and the method further comprising comprises laminating the cyclodextrin composition or the cured cyclodextrin composition with a second packaging material. 
     
     
       17. The method of  claim 1  wherein ripening or maturation of the one or more items of produce is inhibited by the exposing. 
     
     
       18. The method of claim 1, wherein the cyclodextrin composition is disposed onto at least a portion of one surface of a composite material or a selectively permeable membrane.  
     
     
       19. The method of claim 1, wherein the cyclodextrin composition is disposed onto the at least the portion of the one surface of the item of the produce.  
     
     
       20. The method of claim 1, wherein the cyclodextrin composition is disposed onto the at least a portion of the one surface of the packaging material,
 wherein the irradiating the disposed cyclodextrin composition forms a treated packaging material comprising the cured cyclodextrin composition,   wherein the treated packaging material is placed proximal to one or more items of produce, and   wherein the treated packaging material comprising the cured cyclodextrin composition is exposed to the activating amount of water.    
     
     
       21. A method of treating one or more items of produce, the method comprising:
 a. forming a cyclodextrin composition comprising one or more radiation polymerizable monomers and a cyclodextrin inclusion complex, the cyclodextrin inclusion complex comprising α-cyclodextrin and 1-methylcyclopropene;   b. disposing the cyclodextrin composition onto at least a portion of one surface of a packaging material;   c. irradiating the disposed cyclodextrin composition to form a treated packaging material, the treated packaging material comprising a cured cyclodextrin composition; and   d. exposing the treated packaging material to an activating amount of water.