Process for producing hydrogen absorbing alloy powder and hydrogen absorbing alloy electrode

Abstract

Provided is an inexpensive process for producing hydrogen absorbing alloy powder suitable for a nickel-metal hydride storage battery having a high rate discharge property, a high capacity and a long cycle life for repetition of charge and discharge. The process comprises a step of an addition of a rare earth metal oxide and/or hydroxide to a hydrogen absorbing alloy powder, a wet or dry mixing step and a thermal treatment step in an inert atmosphere or in a vacuum.

1 . Process for producing a hydrogen absorbing alloy powder comprising an addition step of a rare earth metal oxide and/or hydroxide to a hydrogen absorbing alloy powder, a wet or dry mixing step, and a thermal treatment step at 100 to 800° C. in an inert atmosphere or in a vacuum.  
     
     
         2 . Process for producing a hydrogen absorbing alloy powder according to    claim 1    wherein said hydrogen absorbing powder before the addition of the rare earth metal oxide and/or hydroxide is obtained starting from an ingot of hydrogen absorption alloy through steps comprising a thermal treatment at 800 to 1100° C. in an inert atmosphere or in a vacuum, a cooling step, and then a milling step.  
     
     
         3 . Process for producing a hydrogen absorbing alloy is powder according to    claim 1    wherein said hydrogen absorbing powder before the addition of the rare earth metal oxide and/or hydroxide is represented by a general formula (R) n (Ni) 5-x-y-z- (Mn) x (Al) y (Co) z  wherein R is La alone or a mixture of La and one or more rare earth elements other than La, and n, x, y and z are each a positive number, denotes a atomic ratio satisfying 0.93≦n≦1.06, 0<x≦0.6, 0<y≦0.6 and 0<z≦1.0.  
     
     
         4 . Process for producing a hydrogen absorbing alloy powder according to    claim 1    wherein said rare earth metal oxide and/or hydroxide is added in an amount of 0.1 to 20% by weight toward the hydrogen absorbing alloy.  
     
     
         5 . Process for producing a hydrogen absorbing alloy powder according to    claim 1    wherein said rare earth metal oxide and/or hydroxide is oxide and/or hydroxide of at least one selected from the group consisting of Gd, Ho, Er, Yb and Y, or compound oxide and/or compound hydroxide of at least two selected from said group.  
     
     
         6 . A hydrogen absorbing alloy electrode for a nickel-metal hydride storage battery formed of the hydrogen absorbing alloy powder produced according to    claim 1   .  
     
     
         7 . A hydrogen absorbing alloy electrode for a nickel-metal hydride storage battery formed of the hydrogen absorbing alloy powder produced according to    claim 2   .  
     
     
         8 . A hydrogen absorbing alloy electrode for a nickel-metal hydride storage battery formed of the hydrogen absorbing alloy powder produced according to    claim 3   .  
     
     
         9 . A hydrogen absorbing alloy electrode for a nickel-metal hydride storage battery formed of the hydrogen absorbing alloy powder produced according to    claim 4   .  
     
     
         10 . A hydrogen absorbing alloy electrode for a nickel-metal hydride storage battery formed of the hydrogen absorbing alloy powder produced according to    claim 5   .