US2009120237A1PendingUtilityA1
Enhanced formulation of cobalt alloy matrix compositions
Est. expiryApr 18, 2025(expired)· nominal 20-yr term from priority
Inventors:Abdelouahab Ziani
C22C 32/0026B22F 2999/00B22F 2998/10C23C 14/3414C22F 1/10C22C 1/0433C22C 19/07
60
PatentIndex Score
0
Cited by
0
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0
Claims
Abstract
A method for manufacturing a single-element matrix cobalt-based granular media alloy composition formulated as Co f 1 -(M u O v ) f 2 , M representing a base metal selected from the group consisting of magnesium (Mg), titanium (Ti), vanadium (V), chromium (Cr), manganese (Mn), iron (Fe), nickel (Ni), copper (Cu), zinc (Zn), aluminum (Al), silicon (Si), yttrium (Y), zirconium (Zr), niobium (Nb), molybdenum (Mo), ruthenium (Ru), indium (In), lanthanum (La), hafnium (Hf), tantalum (Ta), and tungsten (W), u and v representing the number of atoms of base metal M and oxygen (O) per oxide formula, respectively, and f 1 and f 2 being mole fractions represented by the equation f 1 +(u+v)f 2 =1. The method includes the steps of blending a Co-M master alloy powder and a Co u′ O v′ powder into a corresponding (Co a M 1−a ) f 1 ′-(Co u′ O v′ ) f 2 ′ formula, and densifying the blended powders.
Claims
exact text as granted — not AI-modified1 . A method for manufacturing a single-element matrix cobalt-based granular media alloy composition formulated as Co f 1 -(M u O v ) f 2 , M representing a base metal selected from the group consisting of magnesium (Mg), titanium (Ti), vanadium (V), chromium (Cr), manganese (Mn), iron (Fe), nickel (Ni), copper (Cu), zinc (Zn), aluminum (Al), silicon (Si), yttrium (Y), zirconium (Zr), niobium (Nb), molybdenum (Mo), ruthenium (Ru), indium (In), lanthanum (La), hafnium (Hf), tantalum (Ta), and tungsten (W), u and v representing the number of atoms of base metal M and oxygen (O) per oxide formula, respectively, and f 1 and f 2 being mole fractions represented by the equation f 1 +(u+v)f 2 =1, the method comprising the steps of:
blending a Co-M master alloy powder and a Co u′ O v′ powder into a corresponding (Co a M 1−a ) f 1 ′ -(Co u′ O v′ ) f 2 ′ formula, wherein f 2 ′ is represented by the formula:
f
2
′
=
v
v
′
·
f
2
,
wherein f 1 ′ is represented by the formula
f
1
′
=
1
-
v
v
′
(
u
′
+
v
′
)
f
2
,
and
wherein a is represented by the formula
a
=
1
-
(
u
+
v
)
f
2
-
u
′
·
v
v
′
·
f
2
1
-
v
v
′
(
u
′
+
v
′
)
f
2
=
1
-
v
v
′
(
u
′
+
v
′
)
f
2
-
u
·
f
2
1
-
v
v
′
(
u
′
+
v
′
)
f
2
;
and
densifying the blended powders.
2 . The method according to claim 1 , further comprising the step of ball milling the blended powder.
3 . The method according to claim 1 , where the densifying step further includes the steps of:
encapsulating the blended powders in a can; evacuating gasses from the can; and subjecting the can to high temperature and pressure.
4 . A method for manufacturing a binary matrix cobalt-based granular media alloy composition formulated as (Co a Pt 1−a ) f 1 -(M u O v ) f 2 , M representing a base metal selected from the group consisting of magnesium (Mg), titanium (Ti), vanadium (V), chromium (Cr), manganese (Mn), iron (Fe), nickel (Ni), copper (Cu), zinc (Zn), aluminum (Al), silicon (Si), yttrium (Y), zirconium (Zr), niobium (Nb), molybdenum (Mo), ruthenium (Ru), indium (In), lanthanum (La), hafnium (Hf), tantalum (Ta), and tungsten (W), u and v representing the number of atoms of base metal M and oxygen (O) per oxide formula, respectively, a representing an atom fraction, f 1 and f 2 representing mole fractions expressed by the equation f 1 +(u+v)f 2 =1, the method comprising the steps of:
blending a Co a′ Mp b′ Pt 1−a′−b′ master alloy powder and a Co u′ O v′ powder into a corresponding (Co a′ M b′ Pt 1−a′−b′ ) f 1 ′ -(Co u′ O v′ ) f 2 ′ formula, wherein f 2 ′ is represented by the formula:
f
2
′
=
v
v
′
·
f
2
,
wherein f 1 ′ is represented by the formula
f
1
′
=
1
-
v
v
′
(
u
′
+
v
′
)
f
2
,
and
wherein a′ and b′ are represented by the formulas
a
′
=
f
1
·
a
-
u
′
·
v
v
′
·
f
2
1
-
v
v
′
(
u
′
+
v
′
)
f
2
;
and
b
′
=
f
2
·
u
1
-
v
v
′
(
u
′
+
v
′
)
f
2
densifying the blended powders.
5 . A method for manufacturing a ternary matrix cobalt-based granular media alloy composition formulated as (Co a Cr b Pt 1−a−b ) f 1 -(M u O v ) f 2 , M representing a base metal selected from the group consisting of magnesium (Mg), titanium (Ti), vanadium (V), manganese (Mn), iron (Fe), nickel (Ni), copper (Cu), zinc (Zn), aluminum (Al), silicon (Si), yttrium (Y), zirconium (Zr), niobium (Nb), molybdenum (Mo), ruthenium (Ru), indium (In), lanthanum (La), hafnium (Hf), tantalum (Ta), and tungsten (W), u and v representing the number of atoms of base metal M and oxygen (O) per oxide formula, respectively, a and b representing atom fractions, f 1 and f 2 representing mole fractions expressed by the equation f 1 +(u+v)f 2 =1, the method comprising the steps of:
blending a Co a′ Cr b′ Pt c′ M d′ master alloy powder and a Co u′ O v′ powder into a corresponding (Co a′ Cr b′ Pt c′ M d′ ) f 1 ′ -(Co u′ O v′ ) f 2 ′ formula, wherein f 2 ′ is represented by the formula:
f
2
′
=
v
v
′
·
f
2
,
wherein f 1 ′ is represented by the formula
f
1
′
=
1
-
v
v
′
(
u
′
+
v
′
)
f
2
,
and
wherein a′, b′, c′ and d′ are represented by the formulas
a
′
=
f
1
·
a
-
u
′
·
v
v
′
·
f
2
1
-
v
v
′
(
u
′
+
v
′
)
f
2
b
′
=
f
1
·
b
1
-
v
v
′
(
u
′
+
v
′
)
f
2
c
′
=
f
1
·
c
1
-
v
v
′
(
u
′
+
v
′
)
f
2
d
′
=
f
2
·
u
1
-
v
v
′
(
u
′
+
v
′
)
f
2
;
and
densifying the blended powders.
6 . A method for manufacturing a ternary matrix cobalt-based granular media alloy composition formulated as (Co a Cr b Pt 1−a−b ) f 1 -(M m O v ) f 2 , M representing a base metal selected from the group consisting of magnesium (Mg), titanium (Ti), vanadium (V), manganese (Mn), iron (Fe), nickel (Ni), copper (Cu), zinc (Zn), aluminum (Al), silicon (Si), yttrium (Y), zirconium (Zr), niobium (Nb), molybdenum (Mo), ruthenium (Ru), indium (In), lanthanum (La), hafnium (Hf), tantalum (Ta), and tungsten (W), u and v representing the number of atoms of base metal M and oxygen (O) per oxide formula, respectively, a and b representing atom fractions, f 1 and f 2 representing mole fractions expressed by the equation f 1 +(u+v)f 2 =1, the method comprising the steps of:
blending a Co a″ Cr b″ Pt ″ M d″ master alloy powder and a Cr u″ O v″ powder into a corresponding (Co a″ Cr b″ Pt c″ M d″ ) f 1 ″ -(Cr u″ O v″ ) f 2″ formula,
wherein
f
1
·
b
-
v
v
″
·
u
″
·
f
2
≥
0
,
wherein f 2 ″ is represented by the formula:
f
2
″
=
v
v
″
·
f
2
,
wherein f 1 ″ is represented by the formula
f
1
″
=
1
-
v
v
″
(
u
″
+
v
″
)
f
2
,
and
wherein a″, b″, c″ and d″ are represented by the formulas
a
″
=
f
1
·
a
1
-
v
v
″
(
u
″
+
v
″
)
f
2
b
″
=
f
1
·
b
-
v
v
″
·
u
″
·
f
2
1
-
v
v
″
(
u
″
+
v
″
)
f
2
c
″
=
f
1
·
c
1
-
v
v
″
(
u
″
+
v
″
)
f
2
d
″
=
f
2
·
u
1
-
v
v
″
(
u
″
+
v
″
)
f
2
;
and
densifying the blended powders.
7 . A single-element matrix cobalt-based granular media alloy composition formulated as Co f 1 -(M u O v ) f 2 , M representing a base metal selected from the group consisting of magnesium (Mg), titanium (Ti), vanadium (V), chromium (Cr), manganese (Mn), iron (Fe), nickel (Ni), copper (Cu), zinc (Zn), aluminum (Al), silicon (Si), yttrium (Y), zirconium (Zr), niobium (Nb), molybdenum (Mo), ruthenium (Ru), indium (In), lanthanum (La), hafnium (Hf), tantalum (Ta), and tungsten (W), u and v representing the number of atoms of base metal M and oxygen (O) per oxide formula, respectively, and f 1 and f 2 being mole fractions represented by the equation f 1 +(u+v)f 2 =1, the composition produced using the steps of:
blending a Co-M master alloy powder and a Co u′ O v′ powder into a corresponding (Co a M 1−a ) f 1 ′ -(Co u′ O v′ ) f 2 ′ formula, wherein f 2 ′ is represented by the formula:
f
2
′
=
v
v
′
·
f
2
,
wherein f 1 ′ is represented by the formula
f
1
′
=
1
-
v
v
′
(
u
′
+
v
′
)
f
2
,
and
wherein a is represented by the formula
a
=
1
-
(
u
+
v
)
f
2
-
u
′
·
v
v
′
·
f
2
1
-
v
v
′
(
u
′
+
v
′
)
f
2
=
1
-
v
v
′
(
u
′
+
v
′
)
f
2
-
u
·
f
2
1
-
v
v
′
(
u
′
+
v
′
)
f
2
;
and
densifying the blended powders.
8 . A binary matrix cobalt-based granular media alloy composition formulated as (Co a Pt 1−a ) f 1 -(M u O v ) f 2 , M representing a base metal selected from the group consisting of magnesium (Mg), titanium (Ti), vanadium (V), chromium (Cr), manganese (Mn), iron (Fe), nickel (Ni), copper (Cu), zinc (Zn), aluminum (Al), silicon (Si), yttrium (Y), zirconium (Zr), niobium (Nb), molybdenum (Mo), ruthenium (Ru), indium (In), lanthanum (La), hafnium (Hf), tantalum (Ta), and tungsten (W), u and v representing the number of atoms of base metal M and oxygen (O) per oxide formula, respectively, a representing an atom fraction, f 1 and f 2 representing mole fractions expressed by the equation f 1 +(u+v)f 2 =1, the composition produced using the steps of:
blending a Co a′ M b′ Pt 1−a′−b′ master alloy powder and a Co u′ O v′ powder into a corresponding (Co a′ M b′ Pt 1−a′−b′ ) f 1 ′ -(Co u′ O v′ ) f 2 ′ formula, wherein f 2 ′ is represented by the formula:
f
2
′
=
v
v
′
·
f
2
,
wherein f 1 ′ is represented by the formula
f
1
′
=
1
-
v
v
′
(
u
′
+
v
′
)
f
2
,
and
wherein a′ and b′ are represented by the formulas
a
′
=
f
1
·
a
-
u
′
·
v
v
′
·
f
2
1
-
v
v
′
(
u
′
+
v
′
)
f
2
b
′
=
f
2
·
u
1
-
v
v
′
(
u
′
+
v
′
)
f
2
;
and
densifying the blended powders.
9 . A ternary matrix cobalt-based granular media alloy composition formulated as (Co a Cr b Pt 1−a−b ) f 1 -(M u O v ) f 2 , M representing a base metal selected from the group consisting of magnesium (Mg), titanium (Ti), vanadium (V), manganese (Mn), iron (Fe), nickel (Ni), copper (Cu), zinc (Zn), aluminum (Al), silicon (Si), yttrium (Y), zirconium (Zr), niobium (Nb), molybdenum (Mo), ruthenium (Ru), indium (In), lanthanum (La), hafnium (Hf), tantalum (Ta), and tungsten (W), u and v representing the number of atoms of base metal M and oxygen (O) per oxide formula, respectively, a and b representing atom fractions, f 1 and f 2 representing mole fractions expressed by the equation f 1 +(u+v)f 2 =1, the composition produced using the steps of:
blending a Co a′ Cr b′ Pt c′ M d′ master alloy powder and a Co u′ O v′ powder into a corresponding (Co a′ Cr b′ Pt c′ M d′ ) f 1 ′ -(Co u′ O v′ ) f 2 ′ formula, wherein f 2 ′ is represented by the formula:
f
2
′
=
v
v
′
·
f
2
,
wherein f 1 ′ is represented by the formula
f
1
′
=
-
v
v
′
(
u
′
+
v
′
)
f
2
,
and
wherein a′, b′, c′ and d′ are represented by the formulas
a
′
=
f
1
·
a
-
u
′
·
v
v
′
·
f
2
1
-
v
v
′
(
u
′
+
v
′
)
f
2
b
′
=
f
1
·
b
1
-
v
v
′
(
u
′
+
v
′
)
f
2
c
′
=
f
1
·
c
1
-
v
v
′
(
u
′
+
v
′
)
f
2
d
′
=
f
2
·
u
1
-
v
v
′
(
u
′
+
v
′
)
f
2
;
and
densifying the blended powders.
10 . A ternary matrix cobalt-based granular media alloy composition formulated as (Co a Cr b Pt 1−a−b ) f 1 -(M u O v ) f 2 , M representing a base metal selected from the group consisting of magnesium (Mg), titanium (Ti), vanadium (V), manganese (Mn), iron (Fe), nickel (Ni), copper (Cu), zinc (Zn), aluminum (Al), silicon (Si), yttrium (Y), zirconium (Zr), niobium (Nb), molybdenum (Mo), ruthenium (Ru), indium (In), lanthanum (La), hafnium (Hf), tantalum (Ta), and tungsten (W), u and v representing the number of atoms of base metal M and oxygen (O) per oxide formula, respectively, a and b representing atom fractions, f 1 and f 2 representing mole fractions expressed by the equation f 1 +(u+v)f 2 =1, the composition produced using the steps of:
blending a Co a″ Cr b″ Pt c″ M d″ master alloy powder and a Cr u″ O v″ powder into a corresponding (Co a″ Cr b″ Pt c″ M d″ ) f 1 ″ -(Cr u″ O v″ ) f 2 ″ formula,
wherein
f
1
·
b
-
v
v
″
·
u
″
·
f
2
≥
0
,
wherein f 2 ″ is represented by the formula:
f
2
″
=
v
v
″
·
f
2
,
wherein f 1 ″ is represented by the formula
f
1
″
=
1
-
v
v
″
(
u
″
+
v
″
)
f
2
,
and
wherein a″, b″, c″ and d″ are represented by the formulas
a
″
=
f
1
·
a
1
-
v
v
″
(
u
″
+
v
″
)
f
2
b
″
=
f
1
·
b
-
v
v
″
·
u
″
·
f
2
1
-
v
v
″
(
u
″
+
v
″
)
f
2
c
″
=
f
1
·
c
1
-
v
v
″
(
u
″
+
v
″
)
f
2
d
″
=
f
2
·
u
1
-
v
v
″
(
u
″
+
v
″
)
f
2
;
and
densifying the blended powders.
11 . A quaternary matrix cobalt-based granular media alloy composition formulated as (Co a Cr b Pt c M′ d ) f 1 -(M u O v ) f 2 , M′ representing an element selected from the group consisting of boron (B), tantalum (Ta), niobium (Nb), zirconium (Zr), copper (Cu), silver (Ag), gold (Au), and ruthenium (Ru), M representing a base metal different from M′ and selected from the group consisting of magnesium (Mg), titanium (Ti), vanadium (V), manganese (Mn), iron (Fe), nickel (Ni), copper (Cu), zinc (Zn), aluminum (Al), silicon (Si), yttrium (Y), zirconium (Zr), niobium (Nb), molybdenum (Mo), ruthenium (Ru), indium (In), lanthanum (La), hafnium (Hf), tantalum (Ta), and tungsten (W), u and v representing the number of atoms of base metal M and oxygen (O) per oxide formula, respectively, a and b representing atom fractions, f 1 and f 2 representing mole fractions expressed by the equation f 1 +(u+v)f 2 =1, and d being represented by the equation d=1−a−b−c, the composition produced using the steps of:
blending a Co a′ Cr b′ Pt c′ M′ d′ M e′ master alloy powder and a Co u′ O v′ powder into a corresponding (Co a′ Cr b′ Pt c′ M′ d′ M e′ ) f 1 ′ -(Co u′ O v′ ) f 2 ′ formula, wherein f 2 ′ is represented by the formula:
f
2
′
=
v
v
′
·
f
2
,
wherein f 1 ′ is represented by the formula
f
1
′
=
1
-
v
v
′
(
u
′
+
v
′
)
f
2
,
and
wherein a′, b′, c′, d′ and e′ are represented by the formulas
a
′
=
f
1
·
a
-
u
′
·
v
v
′
·
f
2
1
-
v
v
′
(
u
′
+
v
′
)
f
2
b
′
=
f
1
·
b
1
-
v
v
′
(
u
′
+
v
′
)
f
2
c
′
=
f
1
·
c
1
-
v
v
′
(
u
′
+
v
′
)
f
2
d
′
=
f
1
·
d
1
-
v
v
′
(
u
′
+
v
′
)
f
2
e
′
=
f
2
·
u
1
-
v
v
′
(
u
′
+
v
′
)
f
2
;
and
densifying the blended powders.
12 . A quaternary matrix cobalt-based granular media alloy composition formulated as (Co a Cr b Pt c M′ d ) f 1 -(M u O v ) f 2 , M′ representing an element selected from the group consisting of boron (B), tantalum (Ta), niobium (Nb), zirconium (Zr), copper (Cu), silver (Ag), gold (Au), and ruthenium (Ru), M representing a base metal different from M′ and selected from the group consisting of magnesium (Mg), titanium (Ti), vanadium (V), manganese (Mn), iron (Fe), nickel (Ni), copper (Cu), zinc (Zn), aluminum (Al), silicon (Si), yttrium (Y), zirconium (Zr), niobium (Nb), molybdenum (Mo), ruthenium (Ru), indium (In), lanthanum (La), hafnium (Hf), tantalum (Ta), and tungsten (W), u and v representing the number of atoms of base metal M and oxygen (O) per oxide formula, respectively, a and b representing atom fractions, f 1 and f 2 representing mole fractions expressed by the equation f 1 +(u+v)f 2 =1, and d being represented by the equation d=1−a−b−c, the composition produced using the steps of:
blending a Co a″ Cr b″ Pt c″ M′ d″ M e″ master alloy powder and a Cr u″ O v″ powder into a corresponding (Co a″ Cr b″ Pt c″ M′ d″ M e″ ) f 1 ″ -(Cr u″ O v″ ) f 2 ″ formula,
wherein
f
1
·
b
-
v
v
″
·
u
″
·
f
2
≥
0
,
wherein f 2 ″ is represented by the formula:
f
2
″
=
v
v
″
·
f
2
,
wherein f 1 ″ is represented by the formula
f
1
″
=
1
-
v
v
″
(
u
″
+
v
″
)
f
2
,
and
wherein a″, b″, c″, d″ and e″ are represented by the formulas
a
″
=
f
1
·
a
1
-
v
v
″
(
u
″
+
v
″
)
f
2
b
″
=
f
1
·
b
-
v
v
″
·
u
″
·
f
2
1
-
v
v
″
(
u
″
+
v
″
)
f
2
c
″
=
f
1
·
c
1
-
v
v
″
(
u
″
+
v
″
)
f
2
d
″
=
f
1
·
d
1
-
v
v
″
(
u
″
+
v
″
)
f
2
e
″
=
f
2
·
u
1
-
v
v
″
(
u
″
+
v
″
)
f
2
;
and
densifying the blended powders.Cited by (0)
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