US2013168833A1PendingUtilityA1
METHOD FOR ENHANCING GROWTH OF SEMIPOLAR (Al,In,Ga,B)N VIA METALORGANIC CHEMICAL VAPOR DEPOSITION
Est. expiryJan 20, 2026(expired)· nominal 20-yr term from priority
Inventors:Hitoshi SatoJohn F. KaedingMichael IzaBenjamin A. HaskellTroy J. BakerSteven P. DenbaarsShuji Nakamura
H10P 14/3416H10P 14/3258H10P 14/3248H10P 14/3216H10P 14/2926H10P 14/2921H10P 14/24H10P 14/20H10D 62/405C30B 25/02C30B 29/403C30B 29/406H01L 29/045H01L 21/02365
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Abstract
A method for enhancing growth of device-quality planar semipolar nitride semiconductor thin films via metalorganic chemical vapor deposition (MOCVD) by using an (Al,In,Ga)N nucleation layer containing at least some indium. Specifically, the method comprises loading a substrate into a reactor, heating the substrate under a flow of nitrogen and/or hydrogen and/or ammonia, depositing an In x Ga 1-x N nucleation layer on the heated substrate, depositing a semipolar nitride semiconductor thin film on the In x Ga 1-x N nucleation layer, and cooling the substrate under a nitrogen overpressure.
Claims
exact text as granted — not AI-modifiedWhat is claimed is:
1 . A device structure, comprising:
a III-nitride nucleation or buffer layer on, above, or overlying a substrate or template; and a semi-polar III-nitride film on, above, or overlying the III-nitride nucleation or buffer layer, wherein: the semi-polar III-nitride film is characterized by a rocking curve having a full width at half maximum (FWHM) of less than 0.5 degrees as measured by X-ray Diffraction.
2 . The device structure of claim 1 , wherein:
the III-nitride nucleation or buffer layer is deposited on or above a major surface of a substrate; and the semipolar III-nitride film has a planar surface area greater than 10 microns wide.
3 . The device structure of claim 1 , wherein a top surface of the semipolar III-nitride film is substantially parallel to the substrate's major surface.
4 . The device structure of claim 1 , wherein the III-nitride nucleation or buffer layer includes at least some indium.
5 . The device structure of claim 1 , wherein the III-nitride nucleation or buffer layer comprises InGaN.
6 . The device structure of claim 1 , wherein the semi-polar III-nitride film has a lower surface roughness and a reduced number of crystallographic defects as compared to a semi-polar III-nitride semiconductor film grown without the III-nitride nucleation or buffer layer.
7 . The device structure of claim 1 , wherein the substrate is sapphire.
8 . The device structure of claim 1 , wherein the nucleation or buffer layer is grown on Gallium Nitride.
9 . The device structure of claim 1 , wherein the semi-polar III-nitride film is Gallium Nitride.
10 . The device structure of claim 1 , wherein the semi-polar III-nitride film has a comprises a {11 2 2} semipolar III-nitride film.
11 . A method of fabricating a device structure, comprising:
growing a III-nitride nucleation or buffer layer on, above, or overlying a substrate or template; and growing a semi-polar III-nitride film on, above, or overlying the III-nitride nucleation or buffer layer, wherein: growth conditions and characteristics for the nucleation or buffer layer and the semi-polar III-nitride film are such that the semi-polar III-nitride film is characterized by a rocking curve having a full width at half maximum (FWHM) of less than 0.5 degrees as measured by X-ray Diffraction.Cited by (0)
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