Amphiphilic block polymer ultralow-permeability agent and intelligent temporary plugging type water-based drilling fluid

Abstract

An ultralow-permeability agent contains a structural unit provided by styryl hydrophobic monomer, maleic anhydride and acrylamide; the drilling fluid contains two or more of water, sodium bentonite, Pac-Lv, the ultralow-permeability agent, calcium carbonate, one-way plugging agent, white asphalt and barite which are stored in a mixed manner or independently stored. When the amphiphilic block polymer provided by the invention is used as the ultralow-permeability agent of the intelligent temporary plugging type water-based drilling fluid, the self-adaptive characteristic is realized; according to the amphiphilic block polymer, temporary plugging layer gaps formed in pore and throats by plugging materials in drilling fluid can be fully filled under the condition that the sizes and the distribution of the pore and throats of reservoirs are not required to be clear, so that the permeability of temporary plugging layer is greatly reduced, ultralow-permeability is realized.

1 . An amphiphilic block polymer ultralow-permeability agent, comprising structural unit A, structural unit B and structural unit C, wherein the structural unit A is provided by styryl hydrophobic monomer, the structural unit B is provided by maleic anhydride, and the structural unit C is provided by acrylamide;
 the content of the structural unit A is 32 wt % to 44 wt % based on the total weight of the ultralow-permeability agent; the content of the structural unit B is 22 wt % to 28 wt %; the content of the structural unit C is 33 wt % to 40 wt %.   
     
     
         2 . The ultralow-permeability agent according to  claim 1 , wherein the styryl hydrophobic monomer is selected from at least one of styrene, α-methyl styrene, 2-methyl styrene, 3-methyl styrene and 4-methyl styrene. 
     
     
         3 . The ultralow-permeability agent according to  claim 1 , wherein the ultralow-permeability agent is the permeability agent prepared by a method comprising the steps of:
 in the presence of protective gas,   (1) the weight ratio of the dosage is 1:0.02-0.04:0.004-0.008 of the styryl hydrophobic monomer I, the chain transfer agent contact with the initiator to carry out the first reaction to obtain the first intermediate;   (2) in the presence of a solvent, contacting the first intermediate with the styryl hydrophobic monomer II, maleic anhydride, acrylamide and the initiator to perform the second reaction to obtain the second intermediate, wherein the first intermediate, the styryl hydrophobic monomer II, the maleic anhydride and the acrylamide are used in the weight ratio of 1:2.9-3.5:2.5-3.0:4.0-4.9;   (3) contacting the second intermediate with the precipitant to effect precipitation;   the styryl hydrophobic monomer I and the styryl hydrophobic monomer II provide the structural unit A of the amphiphilic block polymer ultralow-permeability agent as described in  claim 1 ;   the weight ratio of the second intermediate to the precipitant is 1:0.83-1.2.   
     
     
         4 . The ultralow-permeability agent according to  claim 3 , wherein the chain transfer agent is selected from at least one of 4-cyano-(thiobenzoic) pentanoic acid, 4-cyano-4-(thiobenzoyl) pentanoic acid, 4-cyanopentanoic acid dithiobenzoate;
 the initiator is selected from at least one of azobisisobutyronitrile and azobisisoheptonitrile;   the solvent is selected from at least one of tetrahydrofuran and dimethylformamide;   the precipitant is selected from at least one of petroleum ether and n-hexane.   
     
     
         5 . The ultralow-permeability agent according to  claim 3 , wherein in step (1), the conditions of the first reaction at least satisfy: the temperature is 40-80° C., and the time is 16-24 h;
 in step (2), the conditions of the second reaction at least satisfy: the temperature is 40-80° C., and the time is 16-24 h. 
 
     
     
         6 . The ultralow-permeability agent according to  claim 4 , wherein in step (1), the conditions of the first reaction at least satisfy: the temperature is 40-80° C., and the time is 16-24 h;
 in step (2), the conditions of the second reaction at least satisfy: the temperature is 40-80° C., and the time is 16-24 h. 
 
     
     
         7 . The ultralow-permeability agent according to  claim 2 , wherein the ultralow-permeability agent is the permeability agent prepared by a method comprising the steps of:
 in the presence of protective gas,   (1) the weight ratio of the dosage is 1:0.02-0.04:0.004-0.008 of the styryl hydrophobic monomer I, the chain transfer agent contact with the initiator to carry out the first reaction to obtain the first intermediate;   (2) in the presence of a solvent, contacting the first intermediate with the styryl hydrophobic monomer II, maleic anhydride, acrylamide and the initiator to perform the second reaction to obtain the second intermediate, wherein the first intermediate, the styryl hydrophobic monomer II, the maleic anhydride and the acrylamide are used in the weight ratio of 1:2.9-3.5:2.5-3.0: 4.0-4.9;   (3) contacting the second intermediate with the precipitant to effect precipitation;   the styryl hydrophobic monomer I and the styryl hydrophobic monomer II provide the structural unit A of the amphiphilic block polymer ultralow-permeability agent as described in  claim 1 ;   the weight ratio of the second intermediate to the precipitant is 1:0.83-1.2.   
     
     
         8 . The ultralow-permeability agent according to  claim 7 , wherein the chain transfer agent is selected from at least one of 4-cyano-(thiobenzoic) pentanoic acid, 4-cyano-4-(thiobenzoyl) pentanoic acid, 4-cyanopentanoic acid dithiobenzoate;
 the initiator is selected from at least one of azobisisobutyronitrile and azobisisoheptonitrile;   the solvent is selected from at least one of tetrahydrofuran and dimethylformamide;   the precipitant is selected from at least one of petroleum ether and n-hexane.   
     
     
         9 . The ultralow-permeability agent according to  claim 7 , wherein in step (1), the conditions of the first reaction at least satisfy: the temperature is 40-80° C., and the time is 16-24 h;
 in step (2), the conditions of the second reaction at least satisfy: the temperature is 40-80° C., and the time is 16-24 h. 
 
     
     
         10 . The ultralow-permeability agent according to  claim 8 , wherein in step (1), the conditions of the first reaction at least satisfy: the temperature is 40-80° C., and the time is 16-24 h;
 in step (2), the conditions of the second reaction at least satisfy: the temperature is 40-80° C., and the time is 16-24 h. 
 
     
     
         11 . An intelligent temporary plugging type water-based drilling fluid, wherein the drilling fluid contains two or more of the following components stored in a mixed manner or independently:
 water, sodium bentonite, Pac-Lv, the ultralow-permeability agent, calcium carbonate, one-way plugging agent, white asphalt and barite;   the ultralow-permeability agent is the amphiphilic block polymer ultralow-permeability agent according to  claim 1 .   
     
     
         12 . The drilling fluid according to  claim 11 , wherein the content of the sodium bentonite is 0.5 parts to 3 parts by weight relative to 100 parts by weight of water; the content of the ultralow-permeability agent is 0.5 parts to 3 parts by weight; the content of the calcium carbonate is 2 parts to 8 parts by weight; the content of the one-way plugging agent is 1 part to 5 parts by weight; the content of the white asphalt is 1 part to 5 parts by weight; the content of the barite is 60 parts to 120 parts by weight. 
     
     
         13 . The drilling fluid according to  claim 12 , wherein the content of the sodium bentonite is 1 part to 2 parts by weight relative to 100 parts by weight of water; the content of the ultralow-permeability agent is 1 part to 2 parts by weight; the content of the calcium carbonate is 4 parts to 6 parts by weight; the content of the one-way plugging agent is 2 parts to 3 parts by weight; the content of the white asphalt is 2 parts to 3 parts by weight; the content of the barite is 80 parts to 100 parts by weight. 
     
     
         14 . The drilling fluid according to  claim 11 , wherein the content of Pac-Lv is 1 wt % to 3 wt % based on the total weight of the drilling fluid. 
     
     
         15 . The drilling fluid according to  claim 14 , wherein the content of Pac-Lv is 1 wt % to 2 wt % based on the total weight of the drilling fluid. 
     
     
         16 . An intelligent temporary plugging type water-based drilling fluid, wherein the drilling fluid contains two or more of the following components stored in a mixed manner or independently:
 water, sodium bentonite, Pac-Lv, the ultralow-permeability agent, calcium carbonate, one-way plugging agent, white asphalt and barite;   the ultralow-permeability agent is the amphiphilic block polymer ultralow-permeability agent according to  claim 10 .   
     
     
         17 . The drilling fluid according to  claim 16 , wherein the content of the sodium bentonite is 0.5 parts to 3 parts by weight relative to 100 parts by weight of water; the content of the ultralow-permeability agent is 0.5 parts to 3 parts by weight; the content of the calcium carbonate is 2 parts to 8 parts by weight; the content of the one-way plugging agent is 1 part to 5 parts by weight; the content of the white asphalt is 1 part to 5 parts by weight; the content of the barite is 60 parts to 120 parts by weight. 
     
     
         18 . The drilling fluid according to  claim 17 , wherein the content of the sodium bentonite is 1 part to 2 parts by weight relative to 100 parts by weight of water; the content of the ultralow-permeability agent is 1 part to 2 parts by weight; the content of the calcium carbonate is 4 parts to 6 parts by weight; the content of the one-way plugging agent is 2 parts to 3 parts by weight; the content of the white asphalt is 2 parts to 3 parts by weight; the content of the barite is 80 parts to 100 parts by weight. 
     
     
         19 . The drilling fluid according to  claim 16 , wherein the content of Pac-Lv is 1 wt % to 3 wt % based on the total weight of the drilling fluid. 
     
     
         20 . The drilling fluid according to  claim 19 , wherein the content of Pac-Lv is 1 wt % to 2 wt % based on the total weight of the drilling fluid.