US10516037B2ActiveUtilityA1

Method of forming shaped source/drain epitaxial layers of a semiconductor device

82
Assignee: TAIWAN SEMICONDUCTOR MFG CO LTDPriority: Jun 30, 2017Filed: Nov 1, 2017Granted: Dec 24, 2019
Est. expiryJun 30, 2037(~11 yrs left)· nominal 20-yr term from priority
H10P 50/242H10P 14/3466H10P 14/3442H10P 14/2905H10P 14/271H10P 14/24H01L 29/045H01L 29/785H01L 21/02609H01L 29/66795H01L 27/0924H01L 21/823814H01L 21/02381H01L 21/02576H01L 29/0847H01L 21/02639H01L 21/823821H01L 21/0262H01L 21/3065H10D 30/62H10D 64/513H10D 30/024H10D 84/853H10D 84/0193H10D 84/038H10D 84/017H10D 62/405H10D 62/151H10D 84/0165H10B 10/00
82
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Cited by
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References
20
Claims

Abstract

In a method for manufacturing a semiconductor device, an isolation insulating layer is formed over a fin structure. A first portion of the fin structure is exposed from and a second portion of the fin structure is embedded in the isolation insulating layer. A dielectric layer is formed over sidewalls of the first portion of the fin structure. The first portion of the fin structure and a part of the second portion of the fin structure in a source/drain region are removed, thereby forming a trench. A source/drain epitaxial structure is formed in the trench using one of a first process or a second process. The first process comprises an enhanced epitaxial growth process having an enhanced growth rate for a preferred crystallographic facet, and the second process comprises using a modified etch process to reduce a width of the source/drain epitaxial structure.

Claims

exact text as granted — not AI-modified
What is claimed is: 
     
       1. A method for manufacturing a semiconductor device, comprising:
 forming an isolation insulating layer over a fin structure, wherein a first portion of the fin structure is exposed from the isolation insulating layer and a second portion of the fin structure is embedded in the isolation insulating layer; 
 forming a gate structure over a part of the first portion of the fin structure; 
 forming a dielectric layer over sidewalls of the first portion of the fin structure in a source/drain region not covered by the gate structure; 
 removing the first portion of the fin structure and a part of the second portion of the fin structure between portions of the dielectric layer in the source/drain region, thereby forming a trench over a remaining part of the second portion of the fin structure and between the portions of the dielectric layer that extend along an entire length of the trench; and 
 forming a source/drain (SD) epitaxial structure in the trench using one of a first process or a second process, 
 wherein a top surface of the remaining part of the second portion of the fin structure in the trench provides a preferred crystallographic facet, and the first process comprises an enhanced epitaxial growth process having an enhanced growth rate for the preferred crystallographic facet, 
 the second process comprises disposing an SD epitaxial structure in the trench and on top of the trench and using a modified etch process to reduce a width of the SD epitaxial structure on top of the trench, and 
 after either of the first process or the second process a lateral extent of the SD epitaxial structure on top of the trench is limited to about sidewalls of the portions of the dielectric layer that are further away from the trench. 
 
     
     
       2. The method of  claim 1 , wherein the preferred crystallographic facet comprise a (100) facet, and wherein an epitaxial deposition is performed with an enhanced growth ratio on facet (100) over facet (111) and on facet (100) over facet (110), wherein the enhanced growth ratio is between 3 to 5 times. 
     
     
       3. The method of  claim 1 , wherein the semiconductor device comprises an NMOS device, and wherein the first process is performed using a chemical vapor deposition (CVD) process. 
     
     
       4. The method of  claim 3 , wherein the CVD process is performed at a high temperature within a range of about 650-700° C. and a pressure within a range of about 200-350 Torr. 
     
     
       5. The method of  claim 1 , wherein the semiconductor device comprises a PMOS device, and wherein the first process is performed using a CVD process at a high temperature within a range of about 600-650° C. and a pressure within a range of about 5-50 Torr. 
     
     
       6. The method of  claim 1 , wherein the semiconductor device comprises an NMOS device, and wherein the modified etch process comprises a CVD etch operation. 
     
     
       7. The method of  claim 6 , wherein the CVD etch operation is performed using a mixture of germanium tetrahydride (GeH 4 ) and hydrochloric acid (HCl) with a GeH 4  to HCl mixture ratio within a range of about 0.5-1.2 and at a high temperature within a range of about 650-750° C. and a pressure within a range of about 5-100 Torr. 
     
     
       8. The method of  claim 6 , wherein the CVD etch operation is performed using a mixture of silicon tetrahydride (SiH 4 ) and HCl with a SiH 4  to HCl mixture ratio within a range of about 0.2-0.25 and at a high temperature within a range of about 650-750° C. and a pressure within a range of about 5-100 Torr. 
     
     
       9. The method of  claim 1 , wherein the semiconductor device comprises a PMOS device, and wherein the modified etch process comprises a CVD etch operation using HCl at a flow rate within a range of about 50-120 sccm, a temperature within a range of about 600-650° C., and a pressure within a range of about 5-50 Torr. 
     
     
       10. The method of  claim 1 , wherein the isolation insulating layer comprises a shallow trench isolation (STI) material, and wherein the dielectric layer comprises silicon nitride (Si 3 N 4 ), silicon oxide (SiO 2 ), or silicon oxynitride (SiO x N y ), and wherein the dielectric layer over the sidewalls of the first portion of the fin structure is asymmetric and results in an asymmetry of the SD epitaxial structure formed by the enhanced epitaxial growth process. 
     
     
       11. A method for manufacturing a semiconductor device, comprising:
 forming a first structure extending in a first direction, the first structure including a fin made of a first material and having a first portion exposed and a second portion embedded; 
 forming a gate structure over a part of the first portion of the fin; 
 forming a dielectric layer over sidewalls of the first portion of the fin in a source/drain region not covered by the gate structure; 
 removing the first material from the first portion and a part of the second portion of the fin between portions of the dielectric layer in the source/drain region, thereby forming a trench over a remaining part of the second portion of the fin and between the portions of the dielectric layer that extend along an entire length of the trench; 
 forming in and above the trench a source/drain (SD) epitaxial structure; and 
 performing an modified etch process to partially remove portions of a top part of the SD epitaxial structure grown in a second direction perpendicular to the first direction, thereby producing flat sides on the top part of the epitaxial structure, 
 wherein after the modified etch process an extent of the top part of the SD epitaxial structure in the second direction is limited to about sidewalls of the portions of the dielectric layer that are further away from the trench. 
 
     
     
       12. The method of  claim 11 , wherein the first structure includes an isolation insulating layer deposited on the second portion of the fin, and wherein the first material comprises a substrate material. 
     
     
       13. The method of  claim 11 , wherein the semiconductor device comprises an NMOS device, and wherein the modified etch process comprises a CVD etch operation. 
     
     
       14. The method of  claim 13 , wherein performing the CVD etch operation comprises using a mixture of GeH 4  and HCl with a GeH 4  to HCl mixture ratio within a range of about 0.5-1.2. 
     
     
       15. The method of  claim 14 , wherein the CVD etch operation is performed at a temperature within a range of about 650-750° C. and a pressure within a range of about 5-100 Torr. 
     
     
       16. The method of  claim 13 , wherein performing the CVD etch operation comprises using a mixture of silicon tetrahydride (SiH 4 ) and HCl with a SiH 4  to HCl mixture ratio within a range of about 0.2-0.25. 
     
     
       17. The method of  claim 16 , wherein the CVD etch operation is performed at a temperature within a range of about 650-750° C. and a pressure within a range of about 5-100 Torr. 
     
     
       18. The method of  claim 11 , wherein the semiconductor device comprises a PMOS device, and wherein the modified etch process comprises a CVD etch operation using HCl at a flow rate within a range of about 50-120 sccm. 
     
     
       19. The method of  claim 18 , wherein the CVD etch operation is performed at a temperature within a range of about 600-650° C. and a pressure within a range of about 5-50 Torr. 
     
     
       20. A method for manufacturing a semiconductor device, comprising:
 forming a first structure extending in a first direction, the first structure including a fin made of a first material and having a first portion exposed and a second portion embedded; 
 forming a gate structure over a part of the first portion of the fin; 
 forming a dielectric layer over sidewalls of the first portion of the fin in a source/drain region not covered by the gate structure; 
 removing the first material from the first portion and a part of the second portion of the fin between portions of the dielectric layer in the source/drain region, thereby forming a trench over a remaining part of the second portion of the fin and between the portions of the dielectric layer that extend along an entire length of the trench; 
 forming in and above the trench a source/drain (SD) epitaxial structure; and 
 performing a modified etch process to partially remove portions of a top part of the epitaxial structure grown in a second direction perpendicular to the first direction, thereby producing a diamond-shape top for the SD epitaxial structure with flat side surfaces parallel to the first direction, 
 wherein after the modified etch process an extent of the top part of the SD epitaxial structure in the second direction is limited to about sidewalls of the portions of the dielectric layer that are further away from the trench.

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