Thermosetting resin composition for semiconductor package and prepreg using the same

Abstract

A thermosetting resin composition having improved flowability and stiffness, and a prepreg using the same. Specifically, three kinds of fillers having different average particle diameters are combined with a binder resin system including an epoxy resin, a bismaleimide resin, a diaminodiphenylsulfone resin, and a benzoxazine resin.

The invention claimed is: 
     
       1. A thermosetting resin composition, including:
 100 parts by weight of a binder resin including an epoxy resin, a bismaleimide resin, a diaminodiphenylsulfone resin, and a benzoxazine resin; and 
 350 parts by weight or more of a filler composed of at least three kinds of fillers having different average particle diameters, 
 wherein the filler comprises a first filler having an average particle diameter of 0.7 μm to 1 μm, a second filler having an average particle diameter of 90 nm to 0.3 μm, and a third filler having an average particle diameter of 10 nm to 50 nm, and 
 wherein the first filler is present in an amount of 250 parts by weight or more, relative to 100 parts by weight of the hinder resin in the thermosetting resin composition. 
 
     
     
       2. The thermosetting resin composition according to  claim 1 , wherein the binder comprises 5 to 20% by weight diaminodiphenylsulfone resin, based on the total weight of the binder. 
     
     
       3. The thermosetting resin composition according to  claim 1 , wherein the three kinds of fillers include 350 to 550 parts by weight, relative to 100 parts by weight of the binder resin on the thermosetting resin composition. 
     
     
       4. The thermosetting resin composition according to  claim 1 , wherein the three kinds of fillers include, relative to 100 parts by weight of the binder resin in the thermosetting resin composition,
 250 to 400 parts by weight of the first filler having an average particle diameter of 0.7 μm to 1 μm, 
 30 to 90 parts by weight of the second filler having an average particle diameter of 90 nm to 0.3 μm, and 
 35 to 60 parts by weight of the third filler having an average particle diameter of 10 nm to 50 nm. 
 
     
     
       5. The thermosetting resin composition according to  claim 1 , wherein the diaminodiphenylsulfone resin has a weight average molecular weight of 100 to 400. 
     
     
       6. The thermosetting resin composition for according to  claim 1 , wherein the content of the benzoxazine resin is 2 to 10% by weight based on the total weight of the binder resin. 
     
     
       7. The thermosetting resin composition for a semiconductor package according to  claim 1 , wherein the three kinds of fillers independently include at least one selected from the group consisting of silica aluminum trihydroxide, magnesium hydroxide, molybdenum oxide, zinc molybdate, zinc borate, zinc stannate, alumina, clay, kaolin, talc, calcined kaolin, calcined talc, mica, glass staple fiber, glass fine powder, and hollow glass. 
     
     
       8. The thermosetting resin composition according to  claim 1 , wherein the epoxy resin is at least one selected from the group consisting of a bisphenol A type of epoxy resin, a phenol novolac epoxy resin, a tetraphenyl ethane epoxy resin, a naphthalene-based epoxy resin, a biphenyl-based epoxy resin, a dicyclopentadiene epoxy resin, and a mixture of a dicyclopentadiene-based epoxy resin and a naphthalene-based epoxy resin. 
     
     
       9. The thermosetting resin composition according to  claim 1 , wherein the bismaleimide resin is at least one selected from the group consisting of compounds represented by the following Chemical Formula 2: 
       
         
           
           
               
               
           
         
         (wherein n is an integer of 0 or 1 to 50). 
       
     
     
       10. The thermosetting resin composition according to  claim 1 ,
 further comprising one or more additives selected from the group consisting of a solvent, a curing accelerator, a flame retardant, a lubricant, a dispersant, a plasticizer, and a silane coupling agent. 
 
     
     
       11. A prepreg obtained by impregnating a fiber substrate with the thermosetting resin composition according to  claim 1 . 
     
     
       12. A metal clad laminate comprising the prepreg according to  claim 11 , and
 a metal foil integrated with the prepreg by heating and pressurizing.