Method for enhancing the solderability of a surface

Abstract

A method for enhancing the solderability of a metallic surface is disclosed where the metallic surface is plated with an immersion silver plate prior to soldering, which immersion silver plate is treated with an additive selected from the group consisting of fatty amines, fatty amides, quaternary salts, amphateric salts, resinous amines, resinous amides, fatty acids, resinous acids, ethoxylated derivatives of any of the foregoing, and mixtures of any of the foregoing. The immersion silver deposits created are resistant to electromigration.

We claim:  
     
       1. A process for improving the solderability of a metal surface, said process comprising treating the metal surface with an immersion silver plating solution, said solution comprising
 a). a soluble source of silver ions;   b). an acid;   c). from about 0.1 g/l to about 15 g/l of an additive selected from the group consisting of fatty amines, fatty amides, quaternary salts, amphoteric salts, resinous amines, resinous amides, fatty acids, resinous acids, ethoxylated versions of any of the foregoing, propoxylated versions of any of the foregoing and mixtures of any of the foregoing.   
     
     
       2. A process according to  claim 1  wherein the silver plating solution also comprises material selected from the group consisting of imidazoles, benzimidazoles, imidazole derivatives and benzimidazole derivatives. 
     
     
       3. A process according to  claim 1  wherein the silver plating solution also comprises an oxidant. 
     
     
       4. A process according to  claim 1  wherein the metal surface comprises copper. 
     
     
       5. A process according to  claim 1  wherein the additive is selected from the group consisting of ethoxylated tallowamine, ethoxylated cocoamine, tallow amine, cocoamine, amines derived from tall oil acids, ethoxylated amines derived from tall oil acids, stearic acid, oleic acid, palmitic acid, acids derived from the distillation of tall oil, (stearamidopropyl) dimethyl hydroxyethylammonium dihydrogen phosphate, alkyliminodipropionic acid monosodium salts, and mixtures of the foregoing. 
     
     
       6. A process according to  claim 4  wherein the silver plating solution also comprises a material selected from the group consisting of imidazoles, benzimidazoles, imidazole derivatives, and benzimidazole derivatives. 
     
     
       7. A process according to  claim 6  wherein the silver plating solution also comprises an oxidant. 
     
     
       8. A process according to  claim 7  wherein the additive is selected from the group consisting of ethoxylated tallowamine, ethoxylated cocoamine, tallow amine, cocoamine, amines derived from tall oil acids, ethoxylated amines derived from tall oil acids, stearic acid, oleic acid, palmitic acid, acids derived from the distillation of tall oil, (stearamidopropyl) dimethyl hydroxyethylaminium dihydrogen phosphate, alkyliminadipropionic acid monosodium salts, and mixtures of the foregoing. 
     
     
       9. An immersion silver plating solution comprising an additive selected from the group consisting of ethoxylared tallowamine, ethoxylated cocoamine, amines derived from tall oil acids, ethoxylated amines derived from tall oil acids, stearic acid, oleic acid, palmitic acid, acids derived from the distillation of tall oil, (stearamidopropyl)dimethyl hydroxyethylaminium dihydrogen phosphate, alkyliminadipropionic acid monosodium salts, and mixtures of the foregoing. 
     
     
       10. An immersion plating solution according to  claim 9  also comprising a material selected from the group consisting of imidazoles, benzimidazoles, imidazole derivatives, and benzimidazole derivatives. 
     
     
       11. An immersion plating solution according to  claim 9  also comprising an oxidant. 
     
     
       12. A process for improving the solderability of a metal surface, said process comprising treating the metal surface with an immersion silver plating solution, said solution comprising
 a) a soluble source of silver ions;   b) an acid;   c) from about 0.1 g/l to about 15 g/l of an additive selected from the group consisting of resinous amines, resinous amides, fatty acids, resinous acids, ethoxylated versions of any of the foregoing, propoxylated versions of any of the foregoing and mixtures of any of the foregoing.   
     
     
       13. A process according to claim 12 wherein the silver plating solution also comprises material selected from the group consisting of imidazoles, benzimidazoles, imidazole derivatives and benzimidazole derivatives. 
     
     
       14. A process according to claim 12 wherein the silver plating solution also comprises an oxidant. 
     
     
       15. A process according to claim 12 wherein the metal surface comprises copper. 
     
     
       16. A process according to claim 12 wherein the additive is selected from the group consisting of amines derived from tall oil acids, ethoxylated amines derived from tall oil acids, stearic acid, oleic acid, palmitic acid, acids derived from the distillation of tall oil, alkyliminodipropionic acid monosodium salts, and mixtures of the foregoing. 
     
     
       17. A process according to claim 15 wherein the silver plating solution also comprises a material selected from the group consisting of imidazoles, benzimidazoles, imidazole derivatives, and benzimidazole derivatives. 
     
     
       18. A process according to claim 17 wherein the silver plating solution also comprises an oxidant. 
     
     
       19. A process according to claim 18 wherein the additive is selected from the group consisting of amines derived from tall oil acids, ethoxylated amines derived from tall oil acids, stearic acid, oleic acid, palmitic acid, acids derived from the distillation of tall oil, alkyliminodipropionic acid monosodium salts, and mixtures of the foregoing. 
     
     
       20. An immersion silver plating solution comprising a soluble source of silver ions, an acid, and from about 0.1 g/l to about 15 g/l of an additive selected from the group consisting of amines derived from tall oil acids, ethoxylated amines derived from tall oil acids, stearic acid, oleic acid, palmitic acid, acids derived from the distillation of tall oil, alkyliminodipropionic acid monosodium salts, and mixtures of the foregoing. 
     
     
       21. An immersion plating solution according to claim 20 also comprising a material selected from the group consisting of imidazoles, benzimidazoles, imidazole derivatives, and benzimidazole derivatives. 
     
     
       22. An immersion plating solution according to claim 20 also comprising an oxidant.