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US12404584B2ActiveUtilityPatentIndex 41

Parallel atomic layer deposition of target element interiors

Assignee: APPLIED MATERIALS INCPriority: Jul 18, 2023Filed: Jul 18, 2023Granted: Sep 2, 2025
Est. expiryJul 18, 2043(~17 yrs left)· nominal 20-yr term from priority
Inventors:TOMAR YOGESHPATIL NIKSHEPNAINA KIRUBANANDAN SHANMUGAMPANAVALAPPIL KUMARANKUTTY HANISH KUMARNATU GAYATRIARCOT MAHESH CHELVARAJNATTAMAI SUBRAMANIAN SENTHIL KUMARRAJENDRAN HARI VENKATESHRICE MICHAELBEAUDRY CHRISTOPHER LAURENT
C23C 16/4408C23C 16/45553C23C 16/52C23C 16/45529C23C 16/45525C23C 16/45527C23C 16/45544C23C 16/45555C23C 16/403
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Claims

Abstract

A method includes performing an atomic layer deposition (ALD) process with respect to a plurality of target elements to coat interiors of the plurality of target elements with a protective coating. Performing the ALD process includes alternating delivery of a first precursor inside the plurality of target elements for a first duration to form an adsorption layer on the interiors of the plurality of target elements, alternating purging of the first precursor from the plurality of target elements for a second duration, and alternating delivery of a second precursor inside the plurality of target elements for a third duration to cause the second precursor to react with the adsorption layer and form a target layer on the interiors of the plurality of target elements.

Claims

exact text as granted — not AI-modified
What is claimed is: 
     
       1. A method comprising:
 performing an atomic layer deposition (ALD) process with respect to a plurality of components, each component comprising a target element, to coat interiors of the target elements of the plurality of components with a protective coating, wherein performing the ALD process comprises:
 alternating delivery of a first precursor inside each of the target elements for a first duration to form an adsorption layer on the interiors of the target elements; 
 alternating purging of the first precursor from the target elements for a second duration, wherein the purging is performed for a first interior of a first target element while delivery of the first precursor is performed for a second interior of a second target element; and 
 alternating delivery of a second precursor inside each of the target elements for a third duration to cause the second precursor to react with the adsorption layer and form a target layer on the interiors of the target elements, wherein the delivery of the second precursor is performed for the first interior of the first target element while purging is performed for the second interior of the second target element or a third interior of a third target element. 
 
 
     
     
       2. The method of  claim 1 , wherein alternating delivery of the first precursor comprises:
 pulsing the first precursor inside the first interior of the first target element at a first time; and 
 pulsing the first precursor inside the second interior of the second target element at a later second time, wherein a first difference between the first time and the second time comprises an offset delay. 
 
     
     
       3. The method of  claim 2 , wherein alternating delivery of the second precursor comprises:
 pulsing the second precursor inside the first interior of the first target element at a later third time; and 
 pulsing the second precursor inside the second interior of the second target element at a later fourth time, wherein a second difference between the third time and the fourth time comprises the offset delay. 
 
     
     
       4. The method of  claim 3 , wherein alternating purging of the first precursor comprises:
 flowing a purge gas inside the first interior of the first target element subsequent to the first time until the third time; and 
 flowing the purge gas inside the second interior of the second target element subsequent to the second time until the fourth time. 
 
     
     
       5. The method of  claim 2 , wherein the offset delay comprises a time delay between 100 milliseconds and 500 milliseconds. 
     
     
       6. The method of  claim 1 , wherein one or more of the first duration or the third duration comprises a length of time between 10 milliseconds and 50 milliseconds. 
     
     
       7. The method of  claim 1 , wherein the second duration comprises a length of time between 3 seconds and 9 seconds. 
     
     
       8. The method of  claim 1 , wherein:
 alternating delivery of the first precursor comprises opening one or more first valves for the first duration to cause the first precursor to flow to each of the target elements; 
 alternating delivery of the second precursor comprises opening one or more second valves for the third duration to cause the second precursor to flow to each of the target elements; and 
 alternating purging of the first precursor comprises opening one or more third valves for the second duration to cause purge gas to flow to each of the target elements. 
 
     
     
       9. The method of  claim 1 , wherein the interiors of the target elements are fluidly coupled in parallel with one another to receive the first precursor, a purge gas, and the second precursor from a common distribution system. 
     
     
       10. The method of  claim 1 , wherein the protective coating comprises an aluminum oxide coating on one or more interior surfaces of the target elements. 
     
     
       11. The method of  claim 1 , wherein the first precursor comprises one of trimethyl aluminum (TMA) or aluminum chloride, wherein the second precursor comprises one of water (H 2 O) or ozone (O 3 ). 
     
     
       12. The method of  claim 1 , wherein alternating purging of the first precursor comprises flowing a purge gas comprising nitrogen. 
     
     
       13. The method of  claim 1 , wherein a target element comprises a gas delivery tube configured to deliver a process gas to a process chamber. 
     
     
       14. The method of  claim 1 , wherein alternating delivery of the first precursor inside each of the interiors of the target elements comprises a first rastering of pulsing of the first precursor, and wherein alternating delivery of the second precursor comprises a second rastering of pulsing of the second precursor.

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